Diffusion of Ar in muscovite

Hydrothermal treatment of closely sized muscovite aggregates in a piston-cylinder apparatus induced ⁴⁰Ar^∗ loss that is revealed in ⁴⁰Ar/³⁹Ar step heating spectra. Age spectra and Arrhenius data, however, differ from that expected from a single diffusion length scale. A numerical model of episodic loss assuming the presence of multiple diffusion domains yields excellent fits between synthetic and actual degassing spectra. We used this model to isolate ⁴⁰Ar^∗ loss from the grains that remained intact during hydrothermal treatment at 10 kbar permitting calculation of diffusion coefficients in the temperature range 730-600 °C. Diffusion data generated in this manner yield an activation energy (E) of 63 ± 7 kcal/mol and frequency factor (D_o) of 2.3  cm²/s. Experiments at 20 kbar yield diffusivities lower by about an order of magnitude and correspond to an activation volume of ∼14 cm³/mol. Together, these parameters predict substantially greater retentivity of Ar in muscovite than previously assumed and correspond to a closure temperature (T_c) of 425 °C for a 100 μm radius grain cooling at 10 °C/Ma at 10 kbar (T_c = 405 °C at 5 kbar. Age and log (r/r_o) spectra for the run products show strong correlations indicating that muscovites can retain Ar diffusion boundaries and mechanisms that define their natural retentivity during vacuum step heating. This may permit the application of high resolution, continuous ⁴⁰Ar/³⁹Ar thermochronology to low grade, regionally metamorphosed terranes.     

Meridional transport of particles and standard vector deviation of upper winds

Summary The meridional dispersion of particles depends from the mean meridional circulation (Hadley-type) and the turbulent mass exchange. The velocity of the latter process can be estimated with the standard deviation of the meridional wind component, which is represented in two diagrams.

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Zusammenfassung Die meridionale Ausbreitung von Partikeln hängt von der mittleren Meridionalzirkulation in der Vertikalebene (Hadley-Zirkulation) und dem turbulenten Massenaustausch ab. Die Geschwindigkeit des turbulenten Austauschs kann mit Hilfe der Streung der meridionalen Windkomponente abgeschätzt werden. Diese Größe wird in zwei Diagrammen dargestellt.

     

The 11 March 2011 Tohoku Tsunami Survey in Rikuzentakata and Comparison with Historical Events

On 11 March 2011, a moment magnitude M _w = 9.0 earthquake occurred off the Japan Tohoku coast causing catastrophic damage and loss of human lives. In the immediate aftermath of the earthquake, we conducted the reconnaissance survey in the city of Rikuzentakata, Japan. In comparison with three previous historical tsunamis impacting the same region, the 2011 event presented the largest values with respect to the tsunami height, the inundation area and the inundation distance. A representative tsunami height of 15 m was recorded in Rikuzentakata, with increased heights of 20 m around rocky headlands. In terms of the inundation area, the 2011 Tohoku tsunami exceeded by almost 2.6 times the area flooded by the 1960 Chilean tsunami, which ranks second among the four events compared. The maximum tsunami inundation distance was 8.1 km along the Kesen River, exceeding the 1933 Showa and 1960 Chilean tsunami inundations by factors of 6.2 and 2.7, respectively. The overland tsunami inundation distance was less than 2 km. The tsunami inundation height linearly decreased along the Kesen River at a rate of approximately 1 m/km. Nevertheless, the measured inland tsunami heights exhibit significant variations on local and regional scales. A designated “tsunami control forest” planted with a cross-shore width of about 200 m along a 2 km stretch of Rikuzentakata coastline was completely overrun and failed to protect the local community during this extreme event. Similarly, many designated tsunami shelters were too low and were overwashed by tsunami waves, thereby failing to provide shelter for evacuees—a risk that had been underestimated.     

Reliable estimation of orbit errors in spaceborne SAR interferometry

An approach to improve orbital state vectors by orbit error estimates derived from residual phase patterns in synthetic aperture radar interferograms is presented. For individual interferograms, an error representation by two parameters is motivated: the baseline error in cross-range and the rate of change of the baseline error in range. For their estimation, two alternatives are proposed: a least squares approach that requires prior unwrapping and a less reliable gridsearch method handling the wrapped phase. In both cases, reliability is enhanced by mutual control of error estimates in an overdetermined network of linearly dependent interferometric combinations of images. Thus, systematic biases, e.g., due to unwrapping errors, can be detected and iteratively eliminated. Regularising the solution by a minimum-norm condition results in quasi-absolute orbit errors that refer to particular images. For the 31 images of a sample ENVISAT dataset, orbit corrections with a mutual consistency on the millimetre level have been inferred from 163 interferograms. The method itself qualifies by reliability and rigorous geometric modelling of the orbital error signal but does not consider interfering large scale deformation effects. However, a separation may be feasible in a combined processing with persistent scatterer approaches or by temporal filtering of the estimates.     

Über den Einfluß von Meeresspiegelschwankungen auf Flachwassersedimente im Schwäbischen Jura

Zusammenfassung Im Ablagerungsbecken des Unteren Lias und Dogger dürften, wenn nicht Ebbe und Flut, so doch aperiodische Schwankungen des Meeresspiegels um mehrer Meter aufgetreten sein. Durch die Spiegelschwankungen wird das Sedimentgefüge in von Ort zu Ort wechselndem Ausmaß geändert, austretendes Porenwasser trägt außerdem zur Sedimentbildung bei.

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Summary Aperiodic fluctuations of sea level, caused by wind, during some periods of Lower and Middle Jurassic in Southern Germany should have had similar effects as tides in Watten today, altering the fabric of sediments and bringing pore water low in pH and eH to the surface. Glauconite and Chamosite may have been formed by mixing of normal sea water with pore water.

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Mit 1 Textabbildung

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Herrn Professor Dr.F. Machatschki zum 70. Geburtstag gewidmet.     

Escape models of the Alpine-Carpathian-Pannonian region in the light of palaeomagnetic observations

Recent tectonic models of the Alpine-Carpatho-Pannonian region (ALCAPA) assume a large eastward shift of the Transdanubian Range domain, in the Cenozoic. Since palaeomagnetism is one of the most powerful tools in solving geodynamic processes, the authors present an approach to the escape problem by using all available and relevant palaeomagnetic data. This data set demonstrates consistency with models put forward by geologists for Jurassic and older ages. From the mid-Jurassic on the Northern Calcareous Alps (NCA) did not share the rotations of the Transdanubian Range domain and of the Southern Alps. After individual movements from Neocomian to Miocene, the Transdanubian Range domain must have drifted northward in the mid-Miocene up to the Southern margin of the Northern Calcareous Alps, before starting the escape in the geologists' definition.     

Zircon formation during fluid circulation in eclogites (Monviso, Western Alps): implications for Zr and Hf budget in subduction zones

The zircons from an eclogite and an enclosed eclogite-facies vein from the Monviso ophiolite (Western Alps) display contrasting chemical and morphologic features and document different stages of the evolution of the ophiolite. The zircons from the eclogite show a typical magmatic zoning and are enriched in heavy rare earth elements (HREEs) over middle rare earth elements (MREEs) and have an accentuated negative Eu anomaly, which indicates that the grains co-crystallised with plagioclase. These magmatic zircons document the formation of oceanic crust at 163 ± 2 Ma. In contrast, zircons from the vein contain inclusions of garnet, omphacite, and rutile, which indicate that they crystallised under eclogite-facies conditions. The vein zircons have Th/U ratios < 0.09, lack Eu anomalies, and are only weakly enriched in HREE with respect to MREE. These features are consistent with a garnet-bearing, plagioclase-free, i.e., eclogite-facies paragenesis. Vein zircons yield an age of 45 ± 1 Ma, which is evidence for Eocene subduction-zone metamorphism of the Monviso ophiolite.In the vein, the apparent coexistence of zircon, omphacite, and garnet permits the determination of a set of trace element distribution coefficients among these minerals at high pressure. This set of partitioning can demonstrate chemical equilibrium among these phases in rocks that show less clear evidence of textural equilibrium. In addition, zircon age can now be linked to sensors of metamorphic pressure-temperature conditions. The presence of zircon and rutile in the vein is another example of high field strength element (HFSE) mobility over short distances in aqueous fluids at eclogite-facies conditions. However, the concentrations of Zr and Hf in the aqueous fluid are estimated to be at least a factor of 10 less than primitive mantle values.Mass balance calculations demonstrate that zircon hosts > 95% of the bulk Zr, 90% of Hf, and ∼25% of U in the vein. Zircon is a residual phase in subducted basalts and sediments up to temperatures of at least 800 to 900 °C. Therefore, residual zircon in subducted crust, together with rutile, control the HFSE in liberated subduction zone fluids/melts and might be partly responsible for negative Zr and Hf anomalies in subduction zone magmas.     

Environmental changes in southeastern Amazonia during the last 25,000 yr revealed from a paleoecological record

New pollen, micro-charcoal, sediment and mineral analyses of a radiocarbon-dated sediment core from the Serra Sul dos Carajás (southeast Amazonia) indicate changes between drier and wetter climatic conditions during the past 25,000 yr, reflected by fire events, expansion of savanna vegetation and no-analog Amazonian forest communities. A cool and dry last glacial maximum (LGM) and late glacial were followed by a wet phase in the early Holocene lasting for ca. 1200 yr, when tropical forest occurred under stable humid conditions. Subsequently, an increasingly warm, seasonal climate established. The onset of seasonality falls within the early Holocene warm period, with possibly longer dry seasons from 10,200 to 3400 cal yr BP, and an explicitly drier phase from 9000 to 3700 cal yr BP. Modern conditions with shorter dry seasons became established after 3400 cal yr BP. Taken together with paleoenvironmental evidence from elsewhere in the Amazon Basin, the observed changes in late Pleistocene and Holocene vegetation in the Serra Sul dos Carajás likely reflect large-scale shifts in precipitation patterns driven by the latitudinal displacement of the Inter-Tropical Convergence Zone and changes in sea-surface temperatures in the tropical Atlantic.     

Georadiochemical evidence to weathering of mining residues of the Mansfeld mining district,Germany

Mining heaps are used as archives for the investigation of weathering processes. Aim of this work was to investigate the different weathering behavior of heap materials derived from Kupferschiefer mining with respect to environmental hazard. For this purpose, Kupferschiefer and slag material of two heaps of different age were examined regarding to the radionuclide distribution and geochemical composition. By measuring of the local dose rate, performing digital autoradiography and gamma spectrometry the radiological load of the heaps and the heap materials was determined. The geochemical characterization of the samples was performed by XRF, ICP–OES and ICP–MS. The results show a clear higher radionuclide load of the younger slag heap. A depletion of chalcophile and lithophile elements in the older slag was determined. Apart from a homogeneous radionuclide distribution, considerable radionuclide enrichments in fossil fragments could be proven. The results reveal a different weathering behavior of slag material in comparison to the Kupferschiefer depending on the chemical binding of the elements on organic and inorganic species. Natural organic matter as well as apatite in Kupferschiefer act as retention barrier for some metals.