Petrological, organic geochemical and geochemical characteristics of coal from the Soko mine, Serbia

A petrological, organic geochemical and geochemical study was performed on coal samples from the Soko Mine, Soko Banja basin, Serbia. Ten coal and two carbonaceous clay samples were collected from fresh, working faces in the underground brown coal mine from different parts of the main coal seam. The Lower Miocene, low-rank coal of the Soko Mine is a typical humic coal with huminite concentrations of up to 76.2 vol.%, liptinite less than 14 vol.% and inertinite less than 11 vol.%. Ulminite is the most abundant maceral with variable amounts of densinite and clay minerals. Sporinite and resinite are the most common macerals of the liptinite group. Inertodetrinite is the most abundant maceral of the inertinite group. The mineral-bituminous groundmass identified in some coal samples, and carbonaceous marly clay, indicate sub-aquatic origin and strong bacterial decomposition. The mean random huminite reflectance (ulminite B) for the main coal seam is 0.40 ± 0.05% Rr, which is typical for an immature to early mature stage of organic matter.The extract yields from the coal of the Soko Banja basin ranges from 9413 to 14,096 ppm, in which alkanes constituted 1.0–20.1%, aromatics 1.3–14.7%, asphaltenes 28.1–76.2% and resins 20.2–43.5%. The saturated hydrocarbon fractions included n-C₁₅ to n-C₃₂, with an odd carbon number that predominate in almost all the samples. The contents of n-C₂₇ and n-C₂₉ alkanes are extremely high in some samples, as a contribution of epicuticular waxes from higher plants. Acyclic isoprenoid hydrocarbons are minor constituents in the aliphatic fraction, and the pristane/phytane (Pr/Ph) ratio varies between 0.56 and 3.13, which implies anaerobic to oxic conditions during sedimentation. The most abundant diterpanes were abietane, dehydroabietane and 16α(H)-phyllocladane. In samples from the upper part of the coal seam, diterpanes are the dominant constituents of the alkane fraction. Polycyclic alkanes of the triterpane type are important constituents of alkane fractions. The occurrence of ββ- and αβ-type hopanes from C₂₇ to C₃₁, but without C₂₈, is typical for the Soko Banja coals.The major and trace elements in the coal were analysed using X-ray fluorescence (XRF), and inductively coupled plasma-mass spectrometry (ICP-MS). In comparison with world lignites, using the geometric mean value, the coal from the Soko Banja Basin has a high content of strontium (306.953 mg/kg). Higher values than the world lignites were obtained for Mo (3.614 mg/kg), Ni (8.119 mg/kg), Se (0.884 mg/kg), U (2.642 mg/kg) and W (0.148 mg/kg). Correlation analysis shows inorganic affinity for almost all the major and trace elements, except for S, which has an organic affinity.     

Sub-pixel classification of SPOT-VEGETATION time series for the assessment of regional crop areas in Belgium

Global time series of low resolution images are available with high repeat frequency and at low cost, but their analysis is hampered by the presence of mixed pixels and the difficulty in locating detailed spatial features. This study examined the potential of sub-pixel classification for regional crop area estimation using time series of monthly NDVI-composites of the 1 km resolution sensor SPOT-VEGETATION. Belgium was selected as test zone, because of the availability of ample reference data in the form of a vectorial GIS with the boundaries and cover type of the large majority of agricultural fields. Two different methods were investigated: the linear mixture model and neural networks. Both result in area fraction images (AFIs), which contain for each 1 km pixel the estimated area proportions occupied by the different cover types (crops or other land use). Both algorithms were trained with part of the reference data and validated with the remainder. Validation was repeated at three different levels: the 1 km pixel, the municipality and the agro-statistical district. In general, the neural network outperformed the linear mixture model. For the major classes (winter wheat, maize, forest) the obtained acreage estimates showed good agreement with the true values, especially when aggregated to the level of the municipality (R² ≈ 85%) or district (R² ≈ 95%). The method seems attractive for wide-scale, regional area estimation in data-poor countries.     

Empirical regression models using NDVI, rainfall and temperature data for the early prediction of wheat grain yields in Morocco

In Morocco, no operational system actually exists for the early prediction of the grain yields of wheat (Triticum aestivum L.). This study proposes empirical ordinary least squares regression models to forecast the yields at provincial and national levels. The predictions were based on dekadal (10-daily) NDVI/AVHRR, dekadal rainfall sums and average monthly air temperatures. The Global Land Cover raster map (GLC2000) was used to select only the NDVI pixels that are related to agricultural land. Provincial wheat yields were assessed with errors varying from 80 to 762 kg ha⁻¹, depending on the province. At national level, wheat yield was predicted at the third dekad of April with 73 kg ha⁻¹ error, using NDVI and rainfall. However, earlier forecasts are possible, starting from the second dekad of March with 84 kg ha⁻¹ error, at least 1 month before harvest. At the provincial and national levels, most of the yield variation was accounted for by NDVI. The proposed models can be used in an operational context to early forecast wheat yields in Morocco.     

Constraining provenance,thickness and erosion of nappes using low‐temperature thermochronology: the Northland Allochthon,New Zealand

The Northland Allochthon, an assemblage of Cretaceous–Oligocene sedimentary rocks, was emplaced during the Late Oligocene–earliest Miocene, onto the in situ Mesozoic and early Cenozoic rocks (predominantly Late Eocene–earliest Miocene) in northwestern New Zealand. Using low‐temperature thermochronology, we investigate the sedimentary provenance, burial and erosion histories of the rocks from both the hanging and footwalls of the allochthon. In central Northland (Parua Bay), both the overlying allochthon and underlying Early Miocene autochthon yield detrital zircon and partially reset apatite fission‐track ages that were sourced from the local Jurassic terrane and perhaps Late Cretaceous volcanics; the autochthon contains, additionally, material sourced from Oligocene volcanics. Thermal history modelling indicates that the lower part of the allochthon together with the autochthon was heated to ca. 55–100°C during the Late Oligocene and Early Miocene, most likely due to the burial beneath the overlying nappe sequences. From the Mesozoic basement exposed in eastern Northland, we obtained zircon fission‐track ages tightly bracketed between 153 and 149 Ma; the apatite fission‐track ages on the other hand, generally young towards the northwest, from 129 to 20.9 Ma. Basement thermochronological ages are inverted to simulate the emplacement and later erosion of the Northland Allochthon, using a thermo‐kinematic model coupled with an inversion algorithm. The results suggest that during the Late Oligocene, the nappes in eastern Northland ranged from ca. 4–6‐km thick in the north to zero in the Auckland region (over a distance >200 km). Following the allochthon emplacement, eastern Northland was uplifted and unroofed during the Early Miocene for a period of ca. 1–6 Myr at the rate of 0.1–0.8 km/Myr, leading to rapid erosion of the nappes. Since Middle Miocene, the basement uplift ceased and the erosion of the nappes and the region as a whole slowed down (ca. 0–0.2 km/Myr), implying a decay in the tectonic activity in this region.     

Venus: Cloud optical depth and surface albedo from Venera 8

We have used the measurements of the solar flux obtained by the Venera 8 spacecraft inside the atmosphere of Venus and the values of the Venus spherical albedo to deduce the characteristics of the clouds and of the ground. The method used is the exponential kernel approximation and the results have been tested by exact computations with the spherical harmonics method.A cloud layer with an optical thickness $\text{τ}{}_1\text{? 144}$, an albedo for single scattering $\text{ω}{}_0\text{= 0.9998}$ in the rear infrared, above a Rayleigh layer between 0 and 32 km and a ground of reflectivity ? = 0.4, gives a good agreement with the experimental results. A model with two cloud layers is also discussed.     

Photometry of Venus: II. Theoretical brightness distribution over the disk

Theoretical brightness distributions over the Venus disk have been computed for homogeneous and multilayered cloud models. With homogeneous models, the relative brightness does not depend very much on the optical properties of the cloud, except near the limb or for small phase angles. For multilayered cloud structures, the relative brightness is nearly fixed by the structures and the relative brightness is nearly fixed by the scattering function of the uppermost cloud; the vertical distribution of the absorption is unimportant if the spherical albedo of the planet is given. If the horizontal inhomogeneities currently seen on Venus are due to a layered structure, with an optical thickness of the upper cloud varying from point to point, large simplifications seem possible, and measured contrasts at various wavelengths should permit a test of such a model.     

Hypoxia in a Coastal Embayment of the Chesapeake Bay: A Model Diagnostic Study of Oxygen Dynamics

Two distinct hypoxic patterns were revealed from high-frequency dissolved oxygen (DO) data collected from North Branch of Onancock Creek, a shallow coastal estuary of the Chesapeake Bay, from July to October 2004. Diurnal hypoxia developed associated with large DO swings during fair weather and hypoxia/anoxia developed for prolonged 2–5-day periods following rainfall events. A simplified diagnostic DO-algae model was used to investigate DO dynamics in the creek. The model results show that the modeling approach enables important features of the DO dynamics in the creek to be captured and analyzed. Large anthropogenic inputs of nutrients to the creek stimulated macroalgae blooms in the embayment. High DO production resulted in supersaturated DO in daytime, whereas DO was depleted at night as the high respiration overwhelmed the DO supply, leading to hypoxia. Unlike deep-water environments, in this shallow-water system, biological processes dominate DO variations. High macroalgae biomass interacting with low light and high temperature trigger the development of prolonged hypoxic/anoxic postrainfall events.     

Plio-Pleistocene geological evolution of the northern Sicily continental margin (southern Tyrrhenian Sea): new insights from high-resolution,multi-electrode sparker profiles

High-resolution seismic profiles were acquired in the north Sicily offshore region with an innovative, multi-tip sparker array which lacks ringing and has a base frequency around 600 Hz. The new data, combined with published data, suggest that intra-slope and extensional basins formed as a consequence of the late Miocene (?)–early Pliocene shortening and thrusting, and the middle (?)–late Pliocene continental rifting affecting the internal side of the Sicilian-Maghrebian chain. Early (?) Pleistocene to Holocene high-amplitude and high-frequency sea-level changes resulted in repeated sub-aerial exposure and flooding of the shelf, and the deposition of cyclically arranged hemipelagic and shelf sediments. An uplift of the shelf could explain the non-preservation of the transgressive and of the lowstand wedge systems tracts in the oldest sequences.     

An efficient clean-up method for the GC-MS determination of methylsulfonyl-PCBs/DDEs extracted from various marine mammal tissues

Existing methods for analyzing methylsulfonyl-PCBs in animal tissues require multiple laborious clean-up steps prior to quantitation. In this paper, we report a new, efficient method for the isolation and determination of methylsulfonyl-PCB metabolites in the blubber, liver, kidney, lung, and milk from mammals of marine origin using: solvent extraction, GPC fractionation, and clean-up on an adsorption chromatography column prior to analysis by gas chromatography-mass spectrometry. The method is rapid and can be completed in about half the analysis time required by most other reported methods. The method exhibits excellent analyte recoveries (89-95%), and good reproducibilities with CV's ranging from 3-12% depending on analyte concentration. Detection limits are approximately 1 ng/g lipid. The method is further validated by comparing its quantitative results to that of an independent reference analytical method for several different marine mammal blubber samples. Finally, the method is applied to profile the distribution of methylsulfones among the various tissue types studied for a single bottle-nose dolphin (Tursiops truncatus) sample. In addition, the extent of their transplacental transfer from mother to unborn fetus for several pilot whale (Globicephala melaena) mother-fetus pairs is examined.