Determination of Gold in Twenty Geochemical Reference Samples by Flameless Atomic Absorption Spectrometry

After acid digestion, gold is extracted with MIBK and determinated by flameless atomic absorption spectrometry. The results for six USGS reference samples and fourteen French geochemical standards are presented and discussed. The agreement with working values for these standards is in the range of pm 5%.     

The genesis of lateral accretion deposits in recent intertidal mudflat channels, Solway Firth, Scotland

ABSTRACT The pattern of lateral accretion on an intertidal point bar is a response to the suspended sediment concentrations to which it is exposed. In summer, high sediment concentrations occur only during shallow (ebb) channel flows; deposition therefore takes place mainly on the point bar toe. In winter, high concentrations obtain at all depths and deposition therefore occurs on the upper point bar slopes. Accretion of the point bar toe is limited by scouring resulting from the high rainfall runoff of winter. High suspended sediment concentrations have little effect, however, if flow velocities are too high to allow deposition. Deposition is dependent on the non-uniformity of curved channel flow and is often confined to the downstream (ebb-sense) portion of the point bar. The lateral accretion deposits form a series of wedge-shaped units. Each unit represents one year's deposition, bounded by erosion scarps produced during successive winters. The base of the point bar deposit shows a gradual aggradation, keeping pace with the build-up of the adjacent interchannel flats.     

EFFECTS OF RIVER NETWORK WORKS AND SOIL CONSERVATION MEASURES ON RESERVOIR SILTATION

Knowledge of the morphological dynamics of a water course is essential for management of reservoir siltation. With an example of sedimentation in a reservoir in Basilicata, Italy, this paper demonstrates the effect on reservoir siltation of the hydraulic works, which are aimed to reduce sediment transport along the fluvial network and to prevent part of the sediment discharge from reaching the lake. The effect depends on the river type and on the the geological features of river basin slopes. The paper also shows how mass erosion can significantly contribute to development of reservoir siltation. Finally, preliminary results are provided about the time needed for river training works to be effective.     

Magmatic Evolution of the La Pacana Caldera System, Central Andes, Chile: Compositional Variation of Two Cogenetic, Large-Volume Felsic Ignimbrites

La Pacana is one of the largest known calderas on Earth, andis the source of at least two major ignimbrite eruptions witha combined volume of some 2700 km³. These ignimbrites have stronglycontrasting compositions, raising the question of whether theyare genetically related. The Toconao ignimbrite is crystal poor,and contains rhyolitic (76–77 wt % SiO₂) tube pumices.The overlying Atana ignimbrite is a homogeneous tuff whose pumiceis dacitic (66–70 wt % SiO₂), dense (40–60% vesicularity)and crystal rich (30–40 % crystals). Phase equilibriaindicate that the Atana magma equilibrated at temperatures of770–790°C with melt water contents of 3·1–4·4wt %. The pre-eruptive Toconao magma was cooler (730–750°C)and its melt more water rich (6·3–6·8 wt% H₂O). A pressure of 200 MPa is inferred from mineral barometryfor the Atana magma chamber. Isotope compositions are variablebut overlapping for both units (⁸⁷Sr/⁸⁶Sr_i 0·7094–0·7131;¹⁴³Nd/¹⁴⁴Nd 0·51222–0·51230) and are consistentwith a dominantly crustal origin. Glass analyses from Atanapumices are similar in composition to those in Toconao tubepumices, demonstrating that the Toconao magma could representa differentiated melt of the Atana magma. Fractional crystallizationmodelling suggests that the Toconao magma can be produced by30% crystallization of the observed Atana mineral phases. Toconaomelt characteristics and intensive parameters are consistentwith a volatile oversaturation-driven eruption. However, thelow H₂O content, high viscosity and high crystal content ofthe Atana magma imply an external eruption trigger. KEY WORDS: Central Andes; crystal-rich dacite; eruption trigger; high-silica rhyolite; zoned magma chamber     

Global climatic change,hurricanes, and a tropical forest

Most, if not all forests in the Caribbean are subject to occasional disturbances from hurricanes. If current general circulation model (GCM) predictions are correct, with doubled atmospheric CO₂ (2 × CO₂), the tropical Atlantic will be between 1 °C and 4 °C warmer than it is today. With such a warming, more than twice as many hurricanes per year could be expected in the Caribbean. Furthermore, Emanuael (1987) indicates that in a warmed world the destructive potential of Atlantic hurricanes could be increased by 40% to 60%. While speculative, these increases would dramatically change the disturbance regimes affecting tropical forests in the region and might alter forest structure and composition. Global warming impacts through increased hurricane damage on Caribbean forests are presented.An individual tree, gap dynamics forest ecosystem model was used to simulate the range of possible hurricane disturbance regimes which could affect the Luquillo Experimental Forest in Puerto Rico. Model storm frequency ranged from no storms at all up to one storm per year; model storm intensity varied from no damage up to 100% mortality of trees. The model does not consider the effects of changing temperature and rainfall patterns on the forest. Simulation results indicate that with the different hurricane regimes a range of forest types are possible, ranging from mature forest with large trees, to an area in which forest trees are never allowed to reach maturity.     

Basin dimensions and morphology as controls on amplification of tidal motions (the Early Miocene North Hungarian Bay)

Following the Late Aquitanian sea-level fall, tide-influenced deposition started in the North Hungarian Bay, an embayment in the Paratethys open to the north-east. The relatively narrow, funnel shape of the bay supported amplification of tidal movements, resulting in the generation of strong tidal currents. The length and the depth of the North Hungarian Bay and the connecting seaway through East Slovakia fell into the ‘Tidal Amplification Window’and thus fulfilled the conditions needed for resonant amplification of semidiurnal (M2) tides. Tide-influenced deposits were formed at both sides of the North Hungarian Bay. They reflect dominant currents in opposite directions and of different strengths at either side of the basin. This difference was the result of bottom-tide interactions. Cyclonic (anticlockwise) residual currents were induced above the asymmetrical central depression in the bay and were superimposed upon the tidal currents, producing an anticlockwise, time-and-velocity asymmetrical current system. The North Hungarian Bay and other examples show that amplification of tidal motions and formation of tide-influenced deposits may occur if basin dimensions pass through the ‘Tidal Amplification Window’. This window represents ideal conditions for resonant or amphidromic amplification of tidal currents. It determines an ideal length/depth or width/depth ratio relative to the wavelength of the astronomical tides. Thus signs of strong tidal influence in fossil basin fills can be used to reconstruct the dimensions (length, depth and width) of such basins.     

Aluminum-26 in meteorites—VII. Ureilites,their unique radiation history

Cosmogenic ²⁶A1 activities have been measured by γ-γ coincidence counting in the three ureilites which had not previously been studied. The values in dpm/kg are: Dingo Pup Donga, 38.4 ± 2.4; North Haig, 39.3 ± 4.8; Dyalpur, 55.8 ± 4.8. Five of the six known ureilites thus have lower ²⁶A1 contents, 63 per cent to 77 per cent, than the calculated saturation values, in marked contrast to most other stony meteorites. This cannot be attributed to short cosmic ray exposure ages. Nor do size and depth effects account for the narrow range of ²⁶A1 activities, because a nuclear particle track study indicates that preatmospheric radii were highly variable, from ≥ 40 cm for Goalpara to only a few cm for Dingo Pup Donga. By default, the most likely explanation is that the ureilites had much smaller or much larger orbits than all other stony meteorites.     

Sedimentology and geomorphology of drumlins in western Allgäu, South Germany

Form, lithological composition, geomorphological situation and internal structure of three different drumlins belonging to the Pleistocene Rhine and Iller glacial systems in South Germany are described: one consisting almost completely of subglacial till, another consisting of ice-marginal deposits with an incomplete mantle of till, the third consisting of delta deposits. It is concluded that no precise limits should be drawn between accumulation and erosion drumlins.     

Analysis and modeling of the seasonal South China Sea temperature cycle using remote sensing

The present paper describes the analysis and modeling of the South China Sea (SCS) temperature cycle on a seasonal scale. It investigates the possibility to model this cycle in a consistent way while not taking into account tidal forcing and associated tidal mixing and exchange. This is motivated by the possibility to significantly increase the model’s computational efficiency when neglecting tides. The goal is to develop a flexible and efficient tool for seasonal scenario analysis and to generate transport boundary forcing for local models. Given the significant spatial extent of the SCS basin and the focus on seasonal time scales, synoptic remote sensing is an ideal tool in this analysis. Remote sensing is used to assess the seasonal temperature cycle to identify the relevant driving forces and is a valuable source of input data for modeling. Model simulations are performed using a three-dimensional baroclinic-reduced depth model, driven by monthly mean sea surface anomaly boundary forcing, monthly mean lateral temperature, and salinity forcing obtained from the World Ocean Atlas 2001 climatology, six hourly meteorological forcing from the European Center for Medium range Weather Forecasting ERA-40 dataset, and remotely sensed sea surface temperature (SST) data. A sensitivity analysis of model forcing and coefficients is performed. The model results are quantitatively assessed against climatological temperature profiles using a goodness-of-fit norm. In the deep regions, the model results are in good agreement with this validation data. In the shallow regions, discrepancies are found. To improve the agreement there, we apply a SST nudging method at the free water surface. This considerably improves the model’s vertical temperature representation in the shallow regions. Based on the model validation against climatological in situ and SST data, we conclude that the seasonal temperature cycle for the deep SCS basin can be represented to a good degree. For shallow regions, the absence of tidal mixing and exchange has a clear impact on the model’s temperature representation. This effect on the large-scale temperature cycle can be compensated to a good degree by SST nudging for diagnostic applications.     

New Chilean iron meteorites: Medium octahedrites from Northern Chile are unique

Abstract— We report data on three new iron meteorites from Northern Chile and propose names. All are unnamed iron meteorites from the meteorite collection at the Universidad de La Serena. For two, the provenance is unknown; for the third, the presumed discovery site is in the countryside east of Iquique. The three meteorites have been analyzed by instrumental neutron activation analysis (INAA) and their structures examined with a binocular microscope. La Serena is a complete 663 g iron, a new member of group IIICD; it is not paired with any other iron. Elqui has a mass of 260 g; two faces are fractures, possibly produced by human actions, but fusion crust appears to be present on some of the remaining surface. It is a hexahedrite and a member of group IIAB, but its composition differs from that of all other Chilean hexahedrites. The third iron, Pozo Almonte, is a medium octahedrite member of group IIIAB, one of the most common meteorite groups. To find out whether it is paired, we assembled a full set of IIIAB iron meteorites from Northern Chile. Our compositional data show that Pozo Almonte is not paired with any other IIIAB iron, and that there are no pairings within the full set with the possible exception of Joel's Iron and Sierra Sandon, which differ only in their contents of Ir, 0.39 and 0.34 μg/g, respectively. However, Buchwald's (1975) structural observations rule out this possible pairing. We find appreciable differences in Cu, As and Au between the previously paired IIIAB irons Chañaral and Ilimaës and conclude that these should not be paired.