Submarine groundwater discharge: A large, previously unrecognized source of dissolved iron to the South Atlantic Ocean

This paper reports the initial results of a study of groundwater and coastal waters of southern Brazil adjacent to a 240 km barrier spit separating the Patos Lagoon, the largest coastal lagoon in South America, from the South Atlantic Ocean. The objective of this research is to assess the chemical alteration of freshwater and freshwater–seawater mixtures advecting through coastal permeable sands, and the influence of the submarine discharge of these fluids (SGD) on the chemistry of coastal waters. Here we focus on dissolved iron in this system and use radium isotopic tracers to quantify SGD and cross-shelf fluxes. Iron concentrations in groundwaters vary between 0.6 and 180 μM. The influence of the submarine discharge of these fluids into the surf zone produces dissolved Fe concentrations as high as several micromolar in coastal surface waters. The offshore gradient of dissolved Fe, coupled with results for Ra isotopes, is used to quantify the SGD flux of dissolved Fe from this coastline. We estimate the SGD flux to be 2 × 10⁶ mol day^− 1 and the cross-shelf flux to be 3.2 × 10⁵ mol day^− 1. This latter flux is equal to about 10% of the soluble atmospheric Fe flux to the entire South Atlantic Ocean. We speculate on the importance of this previously unrecognized iron input to regional ocean production and on the potential significance of this source to understanding variations in glacial–interglacial ocean production.     

Generation and expulsion of oils from Permian coals of the Sydney Basin,Australia

Organic geochemical and petrological assessment of coals/coaly shales and fine grained sediments, coupled with organic geochemical analyses of oil samples, all from Permo–Triassic sections of the Southern Sydney Basin (Australia), have enabled identification of the source for the widely distributed oil shows and oil seeps in this region. The Permian coals have higher hydrogen indices, higher liptinite contents, and much higher total organic matter extract yields than the fine grained sediments. A variety of source specific parameters obtained from n-alkanes, regular isoprenoids, terpanes, steranes and diasteranes indicate that the oil shows and seeps were generated and expelled predominantly from higher plant derived organic matter deposited in oxic environments. The source and maturity related biomarkers and aromatic hydrocarbon distributions of the oils are similar to those of the coals. The oil-coal relationship also is demonstrated by similarities in the carbon isotopic composition of the total oils, coal extracts, and their individual n-alkanes. Extracts from the Permo–Triassic fine grained sediments, on the other hand, have organic geochemical signatures indicative of mixed terrestrial and prokaryotic organic matter deposited in suboxic environments, which are significantly different from both the oils and coal extracts. The molecular signatures indicating the presence of prokaryotic organic matter in some of the coal extracts and oils may be due to thin sections of possibly calcareous lithologies interbedded within the coal measures. The genetic relationship between the oils and coals provides new evidence for the generation and expulsion of oils from the Permian coals and raises the possibility for commercial oil accumulations in the Permian and Early Triassic sandstones, potentially in the deeper offshore part of the Sydney Basin.     

Numerical Analysis of the 650,000 m<Superscript>2</Superscript> Åknes Rock Slope based on Measured Displacements and Geotechnical Data

The unstable 650,000 m² Åknes rock slope (Western Norway) poses a hazard, as a sudden failure may cause a destructive tsunami in the fjord. In this study the slope was divided into blocks based on displacements measured at the slope surface. Discontinuous deformation analysis (DDA) showed that three or four blocks in the upper half may be considered as potential subareas that may fail catastrophically. The lower half may be divided into two or three blocks, but more limited data introduces more uncertainty into block definition. The Universal Distinct Element code (UDEC) was used for two-dimensional (2D) stability analyses. By varying fracture geometry, fracture friction, and groundwater conditions within reasonable limits based on site-specific data a number of possible models were compared. The conclusions show that models that were unstable to great depths were in closer agreement with shear strength parameters derived from an earlier study than models that were unstable to smaller depths. The length (depth) of the outcropping fracture, along which shear displacements are shown to occur, plays an important role. A (shallow) slide at 30 m, in which displacements have been documented by borehole measurements, will reduce the stability at greater depths. Increased groundwater pressure is demonstrated to be less critical for very deep slope instability. The results of the DDA and UDEC modelling will be useful for planning of future investigations, interpretation of the subsequent results, further development of the early warning system and in the tsunami modelling.     

Submarine cables: a challenge for ocean management

The international submarine cable industry is a major component of the global telecommunications system, providing important services and requiring increased levels of protection for the maintenance of global economic and maritime security, broadly defined. An overview is given of the submarine cable industry, including its technological developments, legal aspects, security considerations, and implications for integrated ocean planning and management. In the context of multiple ocean use, submarine cables can cause spatial conflicts with other ocean users, particularly the fishing industry. Issues to be examined include compensation for lost or damaged gear, legal liability for cable damage, and regulation and licensing of cables on the seabed of the continental shelf and the high seas. Recent industry-to-industry agreements and programs for compensation to fishers in the USA and Canada are significant advancements in the implementation of integrated approaches to ocean management and planning. The development of transparent and stable interdepartmental processes for the coordinated planning, management and regulation of submarine cables is required for national EEZs. The regulation of international cable industry practices must be harmonized with national management approaches.     

The solar system abundances of phosphorus and titanium and the nebular volatility of phosphorus

Abstract— The bulk chemical composition of Orgueil and 25 other carbonaceous chondrites was determined by x‐ray fluorescence analysis. The sample sizes of the analyzed meteorites were in all cases 120 mg. The abundances of P and Ti in Orgueil and Ivuna were precisely determined by the standard addition method. The new P CI abundance is 926 ± 65 ppm. Excluding the low P of Ivuna and one Orgueil sample with unusual chemistry gives a CI P content of 930 ± 23 ppm. A CI abundance of 926 ppm corresponds to a P/Si wt ratio of 8.66 times 10^?3 (atomic ratio 7.85 times 10^?3). For Ti a CI content of 458 ± 18 ppm and a Ti/Si wtratio of 4.28 times 10^?3 (atomic ratio 2.51 times 10^?3) were found. A Si content of 10.69% was obtained for average CI. The new P CI abundance is 20 to 30% below earlier estimates, while the Ti CI abundance is in agreement with earlier determinations. From the results of the analyses of bulk carbonaceous chondrites it is concluded: (1) Refractory element/Mg ratios increase from CI through CM and C3O to C3V, but ratios among Al, Ca and Ti are constant, except for low Ca/Al ratios in the reduced subgroup of C3V. (2) The Si/Mg ratios are constant in all groups of carbonaceous chondrites. (3) There is a volatility related depletion of Cr and Fe, but the Cr/Fe ratios are constant. (4) The sequence of volatility related depletions of the moderately volatile elements P, Au, As, Mn, and Zn follows condensation temperatures (except for As), if in condensation calculations non‐ideal solid solution in the host phase is considered.     

A finite element slideline approach for calculating tunnel response in jointed rock

The general purpose finite element code DYNA2D is used to calculate the response of an unlined tunnel in jointed rock, with sliding interfaces used to represent the joints. The model problem selected for analysis closely follows a calculation using the discrete element code UDEC. Results for two cases [(1) jointed rock with lubricated joints (no joint friction) and (2) jointed rock with frictional resistance to joint motion] are presented and compared with each other and the UDEC results.     

Latitudinal variation of the solar limb-darkening function

In an effort to monitor solar limb-darkening variability, the continuum radiation intensity at 550 nm over the outermost 32 arcseconds of the limb is measured at various solar latitudes. Using the Finite Fourier Transform Definition, the edge location of the Sun is determined for a series of scan amplitudes at each of the observed positions. The differential radius is the difference between edge locations for a fixed pair of scan amplitudes, and is a quantity which characterizes the slope of the solar limb-darkening function. Utilizing the differential radius, such observations offer the possibility of revealing a latitudinal variation of the photospheric temperature gradient and could provide clues to the mechanisms and variability of energy transport out of the Sun. These observations began in 1988 with measurements at 24 separate limb positions and include observations since 1990 when 36 positions were observed. The daily differential radius measurements for each position that is free of contamination from solar active regions are weighted according to the corresponding daily variance and averaged to obtain an overall value at each position for the observing season. The results indicate that during the 1991 observing season, there were regions near 20°N latitude and 30°S latitude on the Sun where the differential radius values were significantly greater than surrounding regions. This suggests that perturbations to the temperature gradient occur in latitudinally localized regions and persist for at least several months. It is shown that this phenomenon could have the same origin as the observed latitudinal variations of surface temperature and could also speak to the question of a lag time between the cycles of irradiance and magnetic variation.