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331.
T. Malcherek M. A. Carpenter H. Kroll E. K. H. Salje 《Physics and Chemistry of Minerals》1999,26(4):354-366
BaAl2Ge2O8-Feldspar undergoes an order-disorder phase transition I2/c↔C2/m at T
tr
≈1690 K. The thermodynamics of the Al,Ge cation ordering process is described in terms of the compressible Ising model in
mean field approximation. The mean field potential predicts a first order character of the phase transition. This is compared
to antiferromagnetic ordering in a two-dimensional square Ising model with NN-pair interactions and four-spin interactions
on alternating squares. Calculated order parameters and short range ordering are in good agreement with the corresponding
properties observed in BaAl2Ge2O8-feldspar by means of X-ray diffraction, hard mode infrared spectroscopy and TEM. Using known calorimetric data a similar
model is postulated for Al,Si ordering in anorthite, CaAl2Si2O8, for which the derived potential describes a transition with slightly stronger first order character at T
tr
≈1928 K.
Received: 30 January 1998 / Revised, accepted: 29 August 1998 相似文献
332.
333.
Helfried K. Biernat Norbert I. Kömle Herbert I.M. Lichtenegger 《Planetary and Space Science》1985,33(1):45-52
A model of a quadrupole magnetosphere is developed with the aid of conformal mappings. Such a type of magnetosphere might have occurred at the Earth during times of polarity reversals of the dipole field, when the residual field essentially may have had a quadrupole structure. The magnetospheric field-line configuration is calculated for an axial quadrupole directed perpendicular to the solar-wind flow. The model is two-dimensional and leads to analytical formulae. 相似文献
334.
Herbert E. Huppert J.Stewart Turner Steven N. Carey R. Stephen J. Sparks Mark A. Hallworth 《Journal of Volcanology and Geothermal Research》1986,30(3-4)
Laboratory experiments are described which explore the dynamical consequences of buoyant convective upflow observed above hot pyroclastic flows. In nature, the convection is produced by the hot ash particles exchanging heat with air mixed into the front and top of the pyroclastic flow. This effect on the buoyancy due to the mixing of air and ash has been modelled in the laboratory using mixtures of methanol and ethylene glycol (MEG), which have a nonlinear density behaviour when mixed with water. Intermediate mixtures of these fluids can be denser than either initial component, and so the laboratory experiments were inverted models of the natural situation. We studied MEG flowing up under a sloping roof in a tank filled with water. The experiments were performed both in a narrow channel and on a laterally unconfined slope. The flow patterns were also compared with those of conventional gravity currents formed using fresh and salt water. The presence of the region of reversed buoyancy outside the layer flowing along the slope had two significant effects. First, it periodically protected the flow from direct mixing with the environment, resulting in pulses of relatively undiluted fluid moving out intermittently ahead of the main flow. Second, it produced a lateral inflow towards the axis of the current which kept the current confined to a narrow tongue, even on a wide slope.In pyroclastic flows the basal avalanche portion has a much larger density contrast with its surroundings than the laboratory flows. Calculations show that mixing of air into the dense part of a pyroclastic flow cannot generate a mixture that is buoyant in the atmosphere. However, the overlying dilute ash cloud can behave as a gravity current comparable in density contrast to the laboratory flows and can become buoyant, depending on the temperature and ash content. In the August 7th pyroclastic flow of Mount St. Helens, Hoblitt (1986) describes pulsations in the flow front, which are reminiscent of those observed in the experiments. As proposed by Hoblitt, the pulsations are caused by the ash cloud accelerating away from the front of the dense avalanche as a density current. The ash cloud then mixes with more air, becomes buoyant and lifts off the ground, allowing the avalanche to catch up with and move ahead of the cloud. The pulsing behaviour at the fronts of pyroclastic flows could account for the occurrence of cross-bedded layer 1 deposits which occur beneath layer 2 deposits in many sequences. 相似文献
335.
Long wavelength magnetic anomalies of crustal origin derived from the POGO and MAGSAT satellite data often display a strong continuity across the now-rifted continental margins when the continents are reassembled into Pangaea. These anomalies predate the breakup of the supercontinent and represent major blocks whose crustal properties are broadly similar even though those blocks are no longer contiguous. 相似文献
336.
Practical Solutions for Pumping Tests in Carbonate-Rock Aquifers 总被引:2,自引:0,他引:2
337.
Pumping Tests in Patchy Aquifers 总被引:2,自引:1,他引:2
338.
Impact melt samples from drill hole B1-59 at the 3.8 km diameter Brent crater (Ontario) have been analysed for siderophile trace elements indicative of meteoritic contamination. Samples from the basal melt zone at 823–857 m depth are enriched in Ir, Os, Pd, Ni, Co, Cr and Se over basement, with the abundance pattern suggesting a chondritic projectile for Brent. From a Ni-Cr correlation of 10 melt samples an L or LL chondrite is inferred. The contribution of an ultramafic country rock (alnoite) in the melt is too small to significantly influence its ratio. Glass-rich breccias from the allochthonous breccias filling the crater also contain a meteoritic component. Interelement ratios (e.g. ) are, however, fractionated relative to the melt zone samples. This, as well as the low Au content of all Brent samples, is probably a product of alteration.Additional data on impact melts from the 65 km diameter crater Manicouagan still did not reveal a meteoritic component, as also for the Mistastin crater (28 km diameter) where Cr analyses set an upper limit of 1% of an achondritic projectile component in the melt. Irghizites (tektite like glasses) from the Zhamanshin impact structure have been found to contain high Ni and Co concentrations, and our data show that Ir is also enriched. It is however not possible to define the projectile-type. Enrichment of an Ivory Coast tektite in Ir is confirmed. There are large differences in siderophile element concentrations among tektites, with otherwise similar chemical composition.There are now four known craters formed by chondrites (Clearwater East, Lapparjärvi, Wanapitei, and Brent), with Brent being the smallest of these. For smaller craters the projectiles appear to be limited to iron or stony-iron meteorites, because of atmospheric destruction of relatively small stony meteorites. It appears, however, that all major classes of meteorites are represented among the projectiles at terrestrial impact craters. 相似文献
339.
Submarine groundwater discharge: A large, previously unrecognized source of dissolved iron to the South Atlantic Ocean 总被引:4,自引:5,他引:4
Herbert L. Windom Willard S. Moore L. Felipe H. Niencheski Richard A. Jahnke 《Marine Chemistry》2006,102(3-4):252-266
This paper reports the initial results of a study of groundwater and coastal waters of southern Brazil adjacent to a 240 km barrier spit separating the Patos Lagoon, the largest coastal lagoon in South America, from the South Atlantic Ocean. The objective of this research is to assess the chemical alteration of freshwater and freshwater–seawater mixtures advecting through coastal permeable sands, and the influence of the submarine discharge of these fluids (SGD) on the chemistry of coastal waters. Here we focus on dissolved iron in this system and use radium isotopic tracers to quantify SGD and cross-shelf fluxes. Iron concentrations in groundwaters vary between 0.6 and 180 μM. The influence of the submarine discharge of these fluids into the surf zone produces dissolved Fe concentrations as high as several micromolar in coastal surface waters. The offshore gradient of dissolved Fe, coupled with results for Ra isotopes, is used to quantify the SGD flux of dissolved Fe from this coastline. We estimate the SGD flux to be 2 × 106 mol day− 1 and the cross-shelf flux to be 3.2 × 105 mol day− 1. This latter flux is equal to about 10% of the soluble atmospheric Fe flux to the entire South Atlantic Ocean. We speculate on the importance of this previously unrecognized iron input to regional ocean production and on the potential significance of this source to understanding variations in glacial–interglacial ocean production. 相似文献
340.