Characterization of magnetite particles in shocked quartz by means of electron- and magnetic force microscopy: Vredefort, South Africa

Submicroscopic opaque particles from highly shocked granite-gneisses close to the core of the Vredefort impact structure have been investigated by means of micro-analytical techniques with high spatial resolution such as electron diffraction, orientation contrast imagery and magnetic force microscopy. The opaque particles have been identified as nano- to micro-sized magnetite that occur in several distinct modes. In one sample magnetite occurs along relict planar deformation features (PDFs) in quartz, generally accepted as typical shock lamellae. The magnetite particles along shock lamellae in quartz grains virtually all show uniform crystallographic orientations. In most instances, the groups of magnetite within different quartz grains are systematically misorientated such that they share a subparallel <101> direction. The magnetite groups of all measured quartz grains thus appear to have a crystallographic preferred orientation in space. In a second sample, orientations of magnetite particles have been measured in microfractures (non-diagnostic of shock) of quartz, albite and in the alteration halos, (e.g. biotite grains breaking down to chlorite). The crystallographic orientations of magnetite particles are diverse, with only a minor portion having a preferred orientation. Scanning electron microscopy shows that magnetite along the relict PDFs is invariably associated with other microcrystalline phases such as quartz, K-feldspar and biotite. Petrographic observations suggest that these microcrystalline phases crystallized from locally formed micro-melts that intruded zones of weakness such as microfractures and PDFs shortly after the shock event. The extremely narrow widths of the PDFs suggest that heat may have dissipated rapidly resulting in melts crystallizing relatively close to where they were generated. Magnetic force microscopy confirms the presence of magnetic particles along PDFs. The smallest particles, <5 μm with high aspect ratios 15:1 usually exhibit intense, uniform magnetic signals characteristic of single-domain magnetite. Consistent offsets between attractive and repulsive magnetic signals of individual single-domain particles suggest consistent directions of magnetization for a large proportion of particles. Received: 16 November 1998 / Accepted: 17 May 1999     

Spatially distributed hydrotope‐based modelling of evapotranspiration and runoff in mountainous basins

River basins in mountainous regions are characterized by strong variations in topography, vegetation, soils, climatic conditions and snow cover conditions, and all are strongly related to altitude. The high spatial variation needs to be considered when modelling hydrological processes in such catchments. A complex hydrological model, with a great potential to account for spatial variability, was developed and applied for the hourly simulation of evapotranspiration, soil moisture, water balance and the runoff components for the period 1993 and 1994 in 12 subcatchments of the alpine/pre‐alpine basin of the River Thur (area 1703 km²). The basin is located in the north‐east of the Swiss part of the Rhine Basin and has an elevation range from 350 to 2500 m a.s.l. A considerable part of the Thur Basin is high mountain area, some of it above the tree‐line and a great part of the basin is snow covered during the winter season. In the distributed hydrological model, the 12 sub‐basins of the Thur catchment were spatially subdivided into sub‐areas (hydrologically similar response units—HRUs or hydrotopes) using a GIS. Within the HRUs a hydrologically similar behaviour was assumed. Spatial interpolations of the meteorological input variables wereemployed for each altitudinal zone. The structure of the model components for snow accumulation and melt, interception, soil water storage and uptake by evapotranspiration, runoff generation and flow routing are briefly outlined. The results of the simulated potential evapotranspiration reflect the dominant role of altitudinal change in radiation and albedo of exposure, followed by the influence of slope. The actual evapotranspiration shows, in comparison with the potential evapotranspiration, a greater variability in the lower and medium altitudinal zones and a smaller variability in the upper elevation zones, which was associated with limitations of available moisture in soil and surface depression storages as well as with the evaporative demand of the local vegetation. The higher altitudinal dependency and variability of runoff results from the strong increase in precipitation and the decrease in evaporation with increased altitude. An increasing influence of snow cover on runoff as well as evapotranspiration with altitude is obvious. The computed actual evapotranspiration and runoff were evaluated against the observed values of a weighting lysimeter and against runoff hydrographs. Copyright © 1999 John Wiley & Sons, Ltd.     

Phenomenology of the Lense-Thirring effect in the solar system

Recent years have seen increasing efforts to directly measure some aspects of the general relativistic gravitomagnetic interaction in several astronomical scenarios in the solar system. After briefly overviewing the concept of gravitomagnetism from a theoretical point of view, we review the performed or proposed attempts to detect the Lense-Thirring effect affecting the orbital motions of natural and artificial bodies in the gravitational fields of the Sun, Earth, Mars and Jupiter. In particular, we will focus on the evaluation of the impact of several sources of systematic uncertainties of dynamical origin to realistically elucidate the present and future perspectives in directly measuring such an elusive relativistic effect.     

General Steady-State Shape Factor for a Partially Penetrating Well

We present the closed form of a general steady-state shape factor for a partially penetrating well in a uniform anisotropic aquifer. Our simple analytical expression for the shape factor has a uniform representation for full range of parameters and meets or exceeds the accuracy of previous results obtained through semiempirical methods (e.g., Bouwer and Rice [1976] equations). This general shape factor pertains to the flow of fluids (water or air) in subsurface formations when the upper formation boundary has constant potential and the lower boundary is impermeable. The results of our investigation are directly applicable to analyses of (1) slug tests with falling or rising head and (2) injection/extraction tests with constant head, essential techniques for the characterization of hydraulic conductivity of aquifers, streambeds, or lakebeds as well as the design of aquifer and soil remediation systems.     

Quartz as indicator mineral in the Central Swiss Alps: the quartz recrystallization isograd in the rock series of the northern Aar massif

Earlier observations on the deformation of rock-forming quartz during Alpine metamorphism that were made by Voll (1976) along a traverse following the Reuss valley (Aar massif, Central Swiss Alps) are still relevant but can be explained in more modern term. Voll found that a few kilometres south of the contact between the Aar massif and its sedimentary cover quartz has partly undergone a combination of dynamic recrystallization and nucleation along grain boundaries and fractures at the expense of the deformed parent grains. Further to the south, increasing grain growth of quartz under nearly static conditions is observed, with polygonal grain shapes typical of annealed microfabrics. Comparable stages of recrystallization could be found in several N–S traverses through the Aar massif so that “points of first occurrence” of newly formed quartz could be connected to define a quartz recrystallization isograd. This isograd extents over 90 km through the northern Aar massif, following a course parallel to the sanidine/microcline isograd but at a distance of 10–15 km further to the north. The evolution of the quartz microfabric is discussed with respect to recent estimates of the T-t path of the Aar massif.     

Preliminary Interlaboratory Trial for ISO/DIS 12010: Determination of Short Chain Polychlorinated Alkanes (SCCP) in Water

A first preliminary interlaboratory trial was planned to prepare ISO/DIS 12010: Water quality – determination of short chain polychlorinated alkanes (SCCP) in water – method using GC/MS and electron capture negative ionisation (ECNI). The task was to determine the sum of short chain polychlorinated n‐alkanes with carbon chain lengths of C₁₀–C₁₃ and a chlorine content between 49 and 67% in water by GC‐ECNI‐MS and quantification by multiple linear regression described in ISO/DIS 12010 as the compulsory method. Distributed samples were obtained from a real water extract spiked with a target concentration of 0.4 µg/mL sum of SCCP, i.e. the environmental quality target level according to the Water Framework Directive. The interlaboratory trial included the calibration, a column chromatographic clean up, a concentration step and an integration of chromatographic unresolved humps as well as the quantification with multiple linear regression. Reproducibility standard deviations between 21.5 and 22.9% were achieved by 17 participating laboratories from four countries. The method outlined no significant difference of the results between the standard solution and a real water matrix extract. On the basis of this succeeded preliminary interlaboratory trial the final interlaboratory trial for validation of ISO 12010 was prepared in autumn 2010.     

First record of Karydomys (Rodentia, Mammalia) from the German part of the North Alpine Foreland Basin

Karydomys, a rare genus of cricetid rodents from the Middle Miocene of central Europe, had previously been reported only from the Swiss part of the North Alpine Foreland basin; documented evidence from the German part was lacking. This paper describes several new specimens of Karydomys from the German localities Höll and Laimering 3. A correlation of both localities to the Bavarian local biostratigraphic scale OSM F is proposed. Taxonomically, the fossils are most probably linked to K. wigharti from Hambach 6C (north-west Germany), and thus assigned to K. cf. wigharti. In spite of the scarcity of Karydomys fossils in the Upper Freshwatermolasse, the taxon is an important biostratigraphical marker because of its short stratigraphical range.     

Great Microwave Bursts and hard X-rays from solar flares

The microwave and hard X-ray characteristics of 13 solar flares that produced microwave fluxes greater than 500 solar flux units have been analyzed. These Great Microwave Bursts were observed in the frequency range from 3 to 35 GHz at Bern, and simultaneous hard X-ray observations were made in the energy range from 30 to 500 keV with the Hard X-Ray Burst Spectrometer on the Solar Maximum Mission spacecraft. The principal aim of this analysis is to determine whether or not the same distribution of energetic electrons can explain both emissions. The temporal and spectral behaviors of the microwaves as a function of frequency and the X-rays as a function of energy were tested for correlations, with results suggesting that optically thick microwave emission, at a frequency near the peak frequency, originates in the same electron population that produces the hard X-rays. The microwave emission at lower frequencies, however, is poorly correlated with emission at the frequency which appears to characterize this common source. A single-temperature and a multitemperature model were tested for consistency with the coincident X-ray and microwave spectra at microwave burst maximum. Four events are inconsistent with both of the models tested, and neither of the models attempts to explain the high-frequency part of the microwave spectrum. A source area derived on the basis of the single-temperature model agrees to within the uncertainties with the observed area of the one burst for which spatially resolved X-ray images are available.Swiss National Science Foundation Fellow from the University of Bern.Also Energy/Environmental Research Group, Incorporated, Tucson, Arizona, and Department of Physics and Astronomy, University of North Carolina, Chapel Hill. Present address: Johns Hopkins University Applied Physics Laboratory, Laurel, Maryland.