The surface of labradorite feldspar after acid hydrolysis

After reaction with a pH < 4, the surface of labradorite is extensively enriched in Si and H, and depleted in Al, Ca and Na relative to an unreacted crystal. However, the amount of hydrogen measured in the reacted surface is less than that predicted on the basis of exchange of hydrogen (or hydronium) ions for cations in the feldspar. By analogy with studies of silicate glass, this low concentration of hydrogen suggests that some silanol groups in the reacted surface repolymerize subsequent to ion-exchange and depolymerization reactions. The net result is a relatively porous, Si-rich leached layer which is amorphous to electron diffraction, and which allows rapid diffusion of unreactive solutes.

Both the surface area of the reacted feldspar and the porosity increase with acid hydrolysis. Modeling of nitrogen sorption onto the surface suggests that the pores have a nominal radius of 20–80 Å or less. This distribution of pore sizes resembles other acid-reacted silicate materials, such as glass, chrysotile and kaolinite. Although the mineral surface clearly becomes more porous during acid hydrolysis, the increase in powder area also does not coincide with an increase in the flux of dissolved Si from the powder. We thus attribute most of this increase in area to spallation of the silica-rich surface from the feldspar upon drying.     

Cumulate gabbros from the Southwest Indian Ridge, 54°S-7° 16′ E: implications for magmatic processes at a slow spreading ridge

A diverse volcanic and plutonic rock suite was recovered from the center of the 80 km long ridge segment of the Southwest Indian Ridge (54°S, 7°16 E) between the Islas Orcadas and Shaka Fracture Zones. The cumulus nature of the gabbroic rocks in the suite is indicated by phase, modal and cryptic layering, igneous lamination, and low incompatible element abundances. We present a mass-balance model for calculating the proportions and compositions of cumulus phases and crystallized intercumulus liquid from bulk-rock major element compositions. The model is based on the ability to define a compositional array of basaltic liquids and on the assumption that cumulus minerals are initially in equilibrium with trapped liquid. Calculated proportions of trapped liquid range from 3%–15%; values that are characteristic of adcumulates to mesocumulates. Models of postcumulus crystallization indicate significant enrichments of incompatible elements and buffering of compatible elements in residual trapped liquids, thus explaining the high TiO₂ contents observed in magnesian clinopyroxenes. Cumulus phase assemblages and compositions suggest solidification in shallow level magma chambers, but disequilibrium plagioclase compositions suggest some crystallization at greater depth. Furthermore, basalt compositions projected onto the olivine-clinopyroxenequartz pseudoternary suggest magma generation over a range of pressures (from less than 10 to greater than 20 kb) as well as polybaric fractional crystallization. We suggest that the Southwest Indian Ridge is characterized by low magma supply with small batches of melt that either ascend directly to the surface having undergone limited polybaric crystallization or are trapped in shallow crustal magma chambers where they evolve and solidify to form cumulate gabbros. The adcumulus nature of the gabbros investigated here suggests slow cooling rates typical of large intrusions implying relatively large, but ephemeral magma chambers below segments of the Southwest Indian Ridge.     

Modern and ancient geotherms beneath southern Africa

Estimates of subsurface temperatures in the Archean craton of southern Africa during the Archean derived from diamond thermobarometry studies are remarkably similar to temperatures estimated for the same depths today, even though heat production in the earth and the mean global heat flow were probably substantially higher in the Archean. We present multi-dimensional numerical models for the thermal environment of the Archean craton in southern Africa during the Archean in which deep mantle heat is diverted away from the craton toward the surrounding oceanic lithosphere by a lithospheric root beneath the craton. Extrapolation of present-day models to thermal conditions appropriate for the Archean is inadequate to explain the similarity of present-day and Archean temperatures in the cratonic root. Reconciliation of the modern and ancient temperature estimates requires either relaxation of the constraints that the cratonic crustal heat production and/or the earth's mean mantle temperature were higher in the Archean than they are today, or that substantial “erosion” of the lithosphere comprising the cratonic root has occurred since the Archean. The latter possibility could perhaps result from revolatilization of the cratonic root in association with thermal perturbations in the mantle, for which there is evidence in southern Africa in the form of post-Archean tectonic and igneous activity.     

Habitat partitioning between the xanthid crabsPanopeus herbstii andEurypanopeus depressus on intertidal oyster reefs (Crassostrea virginica) in southeastern North Carolina

The abundances of the xanthid crabsPanopeus herbstii andEurypanopeus depressus were examined relative to surface oyster shell cover, surface oyster cluster volume, subsurface shell content, substrate sand and silt composition, and oyster reef elevation. During August 1986 through July 1987, xanthid crabs were collected monthly from twelve 0.25 m²×15 cm deep quadrats, during low tide, from intertidal oyster reefs in Mill Creek, Pender County, North Carolina, USA, with respective quadrat details recorded. The abundance ofP. herbstii, and to a lesser degreeE. depressus, was positively correlated with surface shell cover. The abundance ofE. depressus, and to a lesser degreeP. herbstii, was positively correlated with surface cluster volume. The majority ofP. herbstii inhabited the subsurface stratum of the oyster reef, whereas the majority ofE. depressus inhabited the cluster stratum. Seasonality (i.e., temperature) appeared to influence the strata habitation of both species, with a higher incidence of cluster habitation during warmer months and a lower incidence during colder months. Crab abundance was not related to other factors examined, such as subsurface shell, substrate sand and silt composition, or elevation within the oyster reef. The analyses show thatP. herbstii andE. depressus have partitioned the intertidal oyster reef habitat, withE. depressus exploiting surface shell clusters andP. herbstii the subsurface stratum.     

Analysis of swarms of high-frequency seismic events at Nevado del Ruiz volcano, Colombia (January 1986–August 1987): Development of a procedure

The determination of signal properties like frequency, amplitude, “signature” of the sequence of arrivals of P- and S-phases and the subsequent computation of hypocenter parameters, are the steps of a procedure in the analysis of swarms of high-frequency seismic events from Nevado del Ruiz volcano, which could be useful in other volcanic areas. The use of this procedure on Ruiz data led to the determination of various seismic source volumes, which together with hypocenters of non-swarmed events and the identification of geological features such as faults which cross the area, alignment of domes and volcanic edifices, and the record of low-frequency seismic events not centered in the area of the active vent, suggest the existence of a magma chamber of a rather complex geometry. This hypothesis would suggest that magma, emplaced in zones of weakness (faults) that affect the area, may act as the source of seismic activity. This demands a revision of the methodology used in the deformation measurements, and in the analysis of released energy and event occurrence too. The relations between hypocenters (sources), location and relative energy of the swarms, as well as the general volcanic activity (tremor, ash and gas emission, deformation) could turn out to be a possible means to assist in the identification of premonitory activity and thus be relevant to the process of monitoring and forecasting.     

A numerical investigation of the JASIN atmospheric boundary layer

A numerical model of the cloudy marine boundary layer is described and used to investigate the role of entrainment instability on the developing boundary layer. In general, previous studies have been limited to boundary layers capped by convectively stable inversions or have described only cumulus fields. Here we extend a stratus-capped boundary-layer model to consider the transition to a convectively unstable cloud layer capped by an inversion across which there is a rapid decrease in wet-bulb or equivalent potential temperature. In this case, the inversion is very active and the entrainment rate is determined by the active instability at the interface, in contrast to the mean turbulent motion within the boundary layer.The model is used to interpret the observed boundary layer from the JASIN experiment. Cool, dry air is modified by prolonged passage over increasingly warmer ocean which leads to the development of a convectively unstable cloud layer.     

Efficiency test of earthquake prediction around Thessaloniki from electrotelluric precursors

Since the completion of the network in January 1983, the electric field of the earth has been continuously monitored at four sites near Thessaloniki, the capital of northern Greece. From the present study and from previous investigations by similar measurements in Greece, it is evident that transient changes of the electrotelluric field occur prior to earthquakes. The analysis of these electric forerunners leads in many cases to a successful prediction of the epicentral area, the magnitude and the time of the impending event. Predictions prior to regional earthquakes are issued and documented with telegrams.From November 1983 until the end of May 1984 twelve earthquakes (M_L > 3.5) occurred in the vicinity of Thessaloniki. Ten of these were predicted and warnings given by telegram, whereas two smaller seismic events were missed. Two additional predictions were unsuccessful. Independent of their magnitudes, predicted events took place within a time window of 6 hrs to 6 days after the observations of the electrotelluric anomalies. The accuracy of the predicted epicenters in eight cases is better than 100 km, which corresponds roughly to the mean distance between the electric stations. Magnitude estimates deviate by less than 0.5 magnitude units from the seismically observed ones.Considering the two largest earthquakes, it is shown that the probability of making each of these predictions by chance is of the order of 10⁻².     

Deglaciation and postglacial timberline in the San Juan Mountains,Colorado

Lake Emma, which no longer exists because of a mining accident, was a tarn in a south-facing cirque near the headwaters of the Animas River in the San Juan Mountains of southwestern Colorado. During the Pinedale glaciation, this area was covered by a large transection glacier centered over the Lake Emma region. Three radiocarbon dates on basal organic sediment from Lake Emma indicate that by ca. 15,000 yr B.P. this glacier, one of the largest in the southern Rocky Mountains, no longer existed. Twenty-two radiocarbon dates on Picea and Abies krummholz fragments in the Lake Emma deposits indicate that from ca. 9600 to 7800 yr B.P., from 6700 to 5600 yr B.P., and at 3100 yr B.P. the krummholz limit was at least 70 m higher than present. These data, in conjunction with Picea:Pinus pollen ratios from both the Lake Emma site and the Hurricane Basin site of J. T. Andrews, P. E. Carrara, F. B. King, and R. Struckenrath (1975, Quaternary Research 5, 173–197) suggest than from ca. 9600 to 3000 yr B.P. timberline in the San Juan Mountains was higher than present. Cooling apparently began ca. 3000 yr B.P. as indicated by decreases in both the percentage of Picea pollen and Picea:Pinus pollen ratios at the Hurricane Basin site (Andrews et al., 1975). Cooling is also suggested by the lack of Picea or Abies fragments younger than 3000 yr B.P. at either the Lake Emma or the Hurricane Basin site.     

Finite strain patterns and their significance in Permian rocks of the Alpes Maritimes (France)

More finite strain data has been obtained from autochthonous Permian mudstones of the Alpes Maritimes, S.E. France. These new data were computed from field measurements of green spots on all available sections, deformed mudcracks and from the quantitative correlation between magnetic susceptibility anisotropy and finite strain in these rocks. Previously published finite strain data and the new results are presented on a series of structural maps and cross-sections for the Dôme de Barrot, the Tinée and Vionène region and the Roya region. As in previous studies difficulties arise in explaining the apparently variable extension parallel with the 100°, subhorizontal bedding-cleavage intersection: either this is real or there were large volume changes during the tectonic deformation. Study of quartz fibres, developed in deformed mudcracks in the Tinée valley, suggest that early in the tectonic history incremental stretching directions were parallel with the bedding—cleavage intersection, while later they were down-dip in the 100° trending cleavage. Since these Permian rocks have remained stuck to the Argentera basement they also record displacements and deformations in the basement. The early 100°, subhorizontal stretching is consistent with NW-SE dextral, strike-slip basement faulting, while later, down-dip stretching in the cleavage is consistent with contraction faults in the basement. This information and new palaeomagnetic data on the same samples are combined with recent geophysical evidence and regional tectonic studies, to provide a new precision to the tectonic history of this part of the Western Alpine External Zone.     

The early Cenozoic tectonic history of the southeast Pacific

It is suggested that the hydrothermal vents of the South Pacific Rise produce a beta-governed circulation at mid-depth, and that perhaps the associated plume of excess³He (Lupton and Craig [1]) points westward because of the dynamics of this circulation rather than as a passive tracer.