Water in boninite glass and coexisting orthopyroxene: concentration and partitioning

 Spectroscopic measurements of water in glass inclusions in pyroxene from boninite samples from the Bonin Islands conclusively document the high (2.8–3.2 wt %) primary water contents of boninite magmas. Associated quenched glass from pillow lava rims have slightly lower (2.2–2.4 wt %) water contents, suggesting that minor amounts of degassing occurred between the time of melt entrapment in the orthopyroxenes and subsequent eruption on the sea floor. Some zonation of molecular water contents in pillow rim glasses was observed. OH contents of the host orthopyroxene phenocrysts were also measured, allowing for the calculation of partition coefficients for water between boninite melt and orthopyroxene. These values (0.003–0.004) for water partitioning between orthopyroxene and mafic melts may help constrain petrogenetic models of mantle-derived magmas. Received: 20 September 1993 / Accepted: 26 June 1994     

The distribution and relative toxic potential of organic chemicals in a PCB contaminated bay

For reliable monitoring of environmental improvement, the PCB contaminated bay Orserumsviken on Sweden's Baltic coast was investigated prior to remediation. We examined PCB congener patterns and the relative toxic potential of PCBs in extracts of three matrices: bottom sediment, settling particulate matter and the dissolved phase (obtained from semi-permeable membrane devices). Congener patterns were similar in all matrices. Three fractions were isolated from the extracts: (1) aliphatic and monocyclic aromatic compounds (MAC-fraction), (2) dicyclic aromatic compounds (DAC-fraction), including PCBs, and (3) polycyclic aromatic compounds (PAC-fraction), including PAHs. Total extracts and fractions were injected into newly fertilised rainbow trout eggs. At larval stage, hepatic EROD activities were quantified. Though high, the PCB contamination could explain only an estimated 1-5% of the total EROD induction. The order of EROD induction potential was: total extract > PAC-fraction > DAC-fraction > MAC-fraction in all matrices, suggesting that in Orserumsviken PACs made a larger contribution to the EROD induction potential than PCBs and other DACs.     

Efficient global matrix approach to the computation of synthetic seismograms

Summary. A numerically efficient global matrix approach to the solution of the wave equation in horizontally stratified environments is presented. The field in each layer is expressed as a superposition of the field produced by the sources within the layer and an unknown field satisfying the homogeneous wave equations, both expressed as integral representations in the horizontal wavenumber. The boundary conditions to be satisfied at each interface then yield a linear system of equations in the unknown wavefield amplitudes, to be satisfied at each horizontal wavenumber. As an alternative to the traditional propagator matrix approaches, the solution technique presented here yields both improved efficiency and versatility. Its global nature makes it well suited to problems involving many receivers in range as well as depth and to calculations of both stresses and particle velocities. The global solution technique is developed in close analogy to the finite element method, thereby reducing the number of arithmetic operations to a minimum and making the resulting computer code very efficient in terms of computation time. These features are illustrated by a number of numerical examples from both crustal and exploration seismology.     

From modelling theory to policy: lessons from the LCS project

The Low-Carbon Society (LCS) research project (Strachan et al., 2008) is to be congratulated for providing a rich, useful source of models to inform and precipitate discussion of policy options for moving towards a low-carbon society. This commentary explores additional considerations that warrant inclusion in any policy discussion: the feasibility of political will and leadership, the limitations of technical feasibility, and clarity about what ‘the price of carbon’ means. Difficulties exist with establishing carbon prices due to differences in energy prices between countries and the distinction between baseline (existing policies) and additional parts. An alternative may be to place more emphasis on the energy price for mitigation, along with other indicators (energy efficiency, carbon intensity, renewable power diffusion) for comparison. A policy is proposed, based on the energy price combined with an emphasis on accelerating technological innovation and overcoming barriers to the adoption of energy efficiency measures.     

Siberian gas venting and the end-Permian environmental crisis

The end of the Permian period is marked by global warming and the biggest known mass extinction on Earth. The crisis is commonly attributed to the formation of the Siberian Traps Large Igneous Province although the causal mechanisms remain disputed. We show that heating of Tunguska Basin sediments by the ascending magma played a key role in triggering the crisis. Our conclusions are based on extensive field work in Siberia in 2004 and 2006. Heating of organic-rich shale and petroleum bearing evaporites around sill intrusions led to greenhouse gas and halocarbon generation in sufficient volumes to cause global warming and atmospheric ozone depletion. Basin scale gas production potential estimates show that metamorphism of organic matter and petroleum could have generated > 100,000 Gt CO₂. The gases were released to the end-Permian atmosphere partly through spectacular pipe structures with kilometre-sized craters. Dating of a sill intrusion by the U–Pb method shows that the gas release occurred at 252.0 ± 0.4 million years ago, overlapping in time with the end-Permian global warming and mass extinction. Heating experiments to 275 °C on petroleum-bearing rock salt from Siberia suggests that methyl chloride and methyl bromide were significant components of the erupted gases. The results indicate that global warming and ozone depletion were the two main drivers for the end-Permian environmental crisis. We demonstrate that the composition of the heated sedimentary rocks below the flood basalts is the most important factor in controlling whether a Large Igneous Provinces causes an environmental crisis or not. We propose that a similar mechanism could have been responsible for the Triassic-Jurassic (~ 200 Ma) global warming and mass extinction, based on the presence of thick sill intrusions in the evaporite deposits of the Amazon Basin in Brazil.     

Estimated energy balance in the jovian upper atmosphere during an auroral heating event

We present an analysis of a series of observations of the auroral/polar regions of Jupiter, carried out between September 8 and 11, 1998, making use of the high-resolution spectrometer, CSHELL, on the NASA InfraRed Telescope Facility (IRTF), Mauna Kea, Hawaii; these observations spanned an “auroral heating event.” This analysis combines the measured line intensities and ion velocities with a one-dimensional model vertical profile of the jovian thermosphere/ionosphere. We compute the model line intensities both assuming local thermodynamic equilibrium (LTE) and, relaxing this condition (non-LTE), through detailed balance calculations, in order to compare with the observations. Taking the model parameters derived, we calculate the changes in heating rate required to account for the modelled temperature profiles that are consistent with the measured line intensities. We compute the electron precipitation rates required to give the modelled ion densities that are consistent with the measured line intensities, and derive the corresponding Pedersen conductivities. We compute the changes in heating due to Joule heating and ion drag derived from the measured ion velocities, and modelled conductivities, making use of ion-neutral coupling coefficients derived from a 3-D global circulation model. Finally, we compute the cooling due to the downward conduction of heat and the radiation-to-space from the molecular ion and hydrocarbons. Comparison of the various heating and cooling terms enables us to investigate the balance of energy inputs into the auroral/polar atmosphere. Increases in Joule heating and ion drag are sufficient to explain the observed heating of the atmosphere; increased particle precipitation makes only a minor heating contribution. But local cooling effects—predominantly radiation-to-space—are shown to be too inefficient to allow the atmosphere to relax back to pre-event thermal conditions. Thus we conclude that this event provides observational, i.e. empirical, evidence that heat must be transported away from the auroral/polar regions by thermally or mechanically driven winds.     

AGN effect on cooling flow dynamics

We analyzed the feedback of AGN jets on cooling flow clusters using three-dimensional AMR hydrodynamic simulations. We studied the interaction of the jet with the intracluster medium and creation of low X-ray emission cavities (Bubbles) in cluster plasma. The distribution of energy input by the jet into the system was quantified in its different forms, i.e. internal, kinetic and potential. We find that the energy associated with the bubbles, (pV+γ pV/(γ−1)), accounts for less than 10 percent of the jet energy.     

Observations of martian gullies and constraints on potential formation mechanisms: II. The northern hemisphere

The formation process(es) responsible for creating the observed geologically recent gully features on Mars has remained the subject of intense debate since their discovery. We present new data and analysis of northern hemisphere gullies from Mars Global Surveyor data which is used to test the various proposed mechanisms of gully formation. We located 137 Mars Orbiter Camera (MOC) images in the northern hemisphere that contain clear evidence of gully landforms and analyzed these images in combination with Mars Orbiter Laser Altimeter (MOLA) and Thermal Emission Spectrometer (TES) data to provide quantitative measurements of numerous gully characteristics. Parameters we measured include apparent source depth and distribution, vertical and horizontal dimensions, slopes, orientations, and present-day characteristics that affect local ground temperatures. Northern hemisphere gullies are clustered in Arcadia Planitia, Tempe Terra, Acidalia Planitia, and Utopia Planitia. These gullies form in craters (84%), knobby terrain (4%), valleys (3%), other/unknown terrains (9%) and are found on all slope orientations although the majority of gullies are equator-facing. Most gullies (63%) are associated with competent rock strata, 26% are not associated with strata, and 11% are ambiguous. Assuming thermal conductivities derived from TES measurements as well as modeled surface temperatures, we find that 95% of the gully alcove bases with adequate data coverage lie at depths where subsurface temperatures are greater than 273 K and 5% of the alcove bases lie within the solid water regime. The average alcove length is 470 m and the average channel length is 690 m. Based on a comparison of measured gully features with predictions from the various models of gully formation, we find that models involving carbon dioxide, melting ground ice in the upper few meters of the soil, dry landslide, and surface snowmelt are the least likely to describe the formation of the martian gullies. Although some discrepancies still exist between prediction and observation, the shallow and deep aquifer models remain as the most plausible theories. Interior processes involving subsurface fluid sources are generally favored over exogenic processes such as wind and snowfall for explaining the origin of the martian gullies. These findings gleaned from the northern hemisphere data are in general agreement with analyses of gullies in the southern hemisphere [Heldmann, J.L., Mellon, M.T., 2004. Icarus 168, 285-304].     

Applications of multivariate statistical analysis in remote sensing of agriculture

Rasmussen, Kjeld & Olesen, Henrik Hagen: Applications of multivariate statistical analysis in remote sensing of agriculture. Geografisk Tidsskrift 88:100–107. Copenhagen 1988.

Applications of satellite remote sensing to agriculture involve two main objectives, the identification and mapping of crops, including estimation of acreages, and monitoring of plant growth or production factors, aiming at estimation/prediction of yields.

Deterministic models of the interaction of electromagnetic radiation and plant canopies are used to relate the measured reflected or emitted radiation to crop type and agronomically relevant parameters. The great natural variation of reflectance properties of crops does, however, call for use of a statistical approach. The high dimensionality of the data-sets involved, very often more than ten, requires the use of multivariate techniques.

This paper will deal with the use of multivariate statistical techniques for both crop identification and crop monitoring based on high-resolution satellite remote sensing data, such as those produced by Landsat MSS and -TM and SPOT. Emphasis will be placed upon use of statistical methods in classification and on removal of redundancy in multi-dimensional data-sets. The relative merits of deterministic and statistical methods will be discussed as will the possibilities of incorporating spatial information into statistical methods.     

Estimation of the surface energy balance in the Sahelian zone of Western Africa

Søgaard, Henrik: Estimation of the surface energy balance in the Sahelian zone of Western Africa. Geografisk Tidsskrift 88: 108- 115. Copenhagen 1988.

In studies of desertification in the Sahelian zone of Western Africa an improved knowledge of the water and surface energy balance is recognized to be of major importance. Based on micro-climatological measurements collected during an ongoing field study in the northern part of Burkina Faso, a number of methods for deriving surface energy balance are examined. It is found that for the actual case, with profile measurements restricted to two levels above the surface, exact values of the sensible heat flux can accurately be obtained by applying non-dimensional gradients based on the Monin-Obukhov turbulence theory. Utilization of the results for deriving actual evapotranspiration from standard observations is demonstrated, and the paper finally discusses applicability of the results in satellite remote sensing.