On the global structure of self-gravitating discs for softened gravity

The effects of gravitational softening on the global structure of self-gravitating discs in centrifugal equilibrium are examined in relation to hydrodynamical/gravitational simulations. The one-parameter spline softening proposed by Hernquist & Katz is used.
It is found that if the characteristic size of a disc, r , is comparable to or less than the gravitational softening length, ε, then the cross-section of the simulated disc is significantly larger than that of a no-softening (Newtonian) disc with the same mass and angular momentum.
We demonstrate, furthermore, that if r ≲ε/2 then the scaling relation r ∝ε^3/4 holds for a given mass and specific angular momentum distribution with mass. Finally, we compare some of the theoretical results obtained in this paper and a previous one with the results of numerical Tree-SPH simulations and find qualitative agreement.     

Stop making sense: the trials and tribulations of qualitative data analysis

An account is given of a research project with particular attention to the place of data analysis and interpretation. It shines some light into what often remains the black box of qualitative research practice, the mysterious process of generating a research narrative based on the data. The paper provides other apprentice researchers with an insight into what the data analytical experience can be like, warts and all. It raises issues to do with qualitative data analysis, the use of CAQDAS, grounded theory, the relationship between the narratives of the researcher and the researched, and about the training of qualitative researchers.     

A micro-Mössbauer study of chromites included in diamond and other mantle-related rocks

Oxygen fugacity ( $ f_{{{\text{O}}_{ 2} }} $ f O 2 ) is a fundamental but little known intensive variable in mantle processes. It influences the P/T position of a mantle solidus and the composition of mantle-derived melts and fluids and constrains mantle-core equilibria and a number of geophysical properties of the mantle. An important source of information on oxidation states is the ferric–ferrous iron ratio in mantle spinels. Since the magnetite component is low in mantle spinels, normal analytical errors translate into considerable $ f_{{{\text{O}}_{ 2} }} $ f O 2 uncertainties. In this study, we analyzed the Fe³⁺–Fe_tot ratio of chromites present as inclusions in diamond and other mantle-related occurrences by point-source Mössbauer spectroscopy using single-crystal absorbers as well as conventional Mössbauer spectroscopy using powder absorbers. The studied spinels have been previously analyzed by single-crystal X-ray diffraction and electron microprobe. The ferric–ferrous ratios found are normally similar to the different techniques apart from some samples where a large number of grains have been used for the analyses (powder absorbers). The general agreement between the different techniques allows us to conclude that the studied chromites are stoichiometric. However, conventional Mössbauer spectroscopy on powder absorbers should be conducted with great care, since the method requires a relatively large amount of sample material. Spinel frequently occurs as small grains, and the large number of crystals required may possess different degrees of oxidation/alteration and, consequently, different ferric–ferrous ratio leading to possible errors in the interpretation of the results.     

Case study on the strategy and application of enhancement solutions to improve remediation of soils contaminated with Cu, Pb and Zn by means of electrodialysis

Numerous studies have been conducted with electrochemical removal of heavy metals from spiked kaolinite. Meanwhile, when moving from kaolinite to real soils, new factors must be taken into account—factors influencing, e.g., the buffering capacity of the soil against acidification and the adsorption/desorption processes of the heavy metals. The present study gives some examples where it is necessary to use an enhancement solution to aid desorption of Cu, Zn and Pb during electrodialytic treatment. Dependent on the composition of the pollution, different choices can be made. In the case of a Cu-polluted calcareous soil, ammonia may be used as enhancement solution, due to the formation of charged complexes between ammonia and Cu. Thus, Cu is mobile at high pH when ammonia is added and Cu can be removed without dissolving the calcareous parts. Zn is also mobilized by ammonia, but to a lesser extent than Cu. In the case of Cu, Zn and Pb at the same time, alkaline ammonium citrate may be a solution. It was shown that this enhancement solution could mobilize these three pollutants, but optimization of concentration and pH of the ammonium citrate is still needed. When choosing a remediation scheme for electrochemical treatment of an actual industrially polluted soil, this scheme must be chosen on basis of characterization of soil and pollution combination.     

Detecting the near-surface redox front in crystalline bedrock using fracture mineral distribution,geochemistry and U-series disequilibrium

Oxidizing conditions normally prevail in surface waters and near-surface groundwaters, but there is usually a change to reducing conditions in groundwater at greater depth. Dissolved O₂ originally present is consumed through biogenic and inorganic reactions along the flow paths. Fracture minerals participate in these reactions and the fracture mineralogy and geochemistry can be used to trace the redox front. An important task in the safety assessment of a potential repository for the disposal of nuclear waste in crystalline bedrock, at an approximate depth of 500 m in Sweden, is to demonstrate that reducing conditions can be maintained for a long period of time. Oxygen may damage the Cu canisters that host nuclear waste; additionally, in the event of a canister failure, oxidizing conditions may increase the mobility of some radionuclides. The present study of the near-surface redox front is based on mineralogical (redox-sensitive minerals), geochemical (redox-sensitive elements) and U-series disequilibrium investigations of mineral coatings along open fractures. The fractures have been sampled along drill cores from closely spaced, 100 m deep boreholes, which were drilled during the site investigation work in the Laxemar area, south-eastern Sweden, carried out by the Swedish Nuclear Fuel and Waste Management Co. (SKB). The distribution of the redox-sensitive minerals pyrite and goethite in open fractures shows that the redox front (switch from mainly goethite to mainly pyrite in the fractures) generally occurs at about 15–20 m depth. Calcite leaching by recharging water is indicated in the upper 20–30 m and positive Ce-anomalies suggest oxidation of Ce down to 20 m depth. The U-series radionuclides show disequilibrium in most of the samples, indicating mobility of U during the last 1 Ma. In the upper 20 m, U is mainly removed (due to oxidation) or has experienced complex removal and/or deposition. At depths of 35–55 m, both deposition and removal of U are indicated. Below 55 m, recent deposition of U is generally indicated which suggests removal of U near surface (oxidation) and deposition of U below the redox front. Scattered goethite occurrences below the general redox front (down to ca 80 m) and signs of U removal at 35–55 m mostly correlate with sections of high transmissivity (and/or high fracture frequencies). This shows that highly transmissive fractures are generally required to allow oxygenated groundwaters at depth greater than ca 30 m. Removal of U (oxidation) below 55 m within the last 300 ka is not observed. Although penetration of glacial waters to great depths has been confirmed in the study area, their potential O₂ load seems to have been reduced near the surface.     

Chemical composition and acute toxicity in the water after in situ burning--a laboratory experiment

The chemical composition and toxicity of a water soluble fraction (WSF) of oil versus the underlying water after in situ burning (ISB), has been studied in a laboratory experiment. A system for allowing water sampling after ISB was developed. Seawater samples and oil were collected prior to and immediately after ISB, and chemical analysis was conducted. The chemical characterization of the water showed that the disappearance of water soluble oil components during ISB was insignificant. Acute toxicity tests with the marine copepod Calanus finmarchicus and Microtox® bioassay was performed to establish LC₅₀/EC₅₀ values of the water. The results were compared with regular WAF systems with unburned weathered oil, and indicated no increase in toxicity in the underlying water after ISB.     

Preservation of pre-vegetational mixed fluvio–aeolian deposits in a humid climatic setting: an example from the Middle Proterozoic Eriksfjord Formation, Southwest Greenland

Sedimentological studies of a 30 m thick coastal cliff section within the Middle Proterozoic Eriksfjord Formation in western South Greenland reveals three distinct types of fluvial sand sheet deposits that reflect perennial streams (Type I), semi-perennial streams (Type II), and ephemeral flash floods (Type III). Perennial river sand sheets are characterised by co-sets of medium-scale trough cross-beds, interbedded with isolated medium- and large-scale, high-angle, tabular cross-beds. Indications of desiccation or subaerial exposure are absent. Semi-perennial fluvial sand sheets consist predominantly of low-angle cross-beds, interbedded with isolated sets of high-angle tabular cross-beds with common reactivation surfaces. Horizontal lamination and climbing ripple lamination form subordinate structures. Associated with the sand sheets are adhesion structures and 0.05–0.4 m thick sets of wind ripple-lamination indicating periods of subaerial exposure and aeolian reworking. High-energy ephemeral flash flood sand sheets consist almost exclusively of planar-parallel lamination and climbing ripple lamination with some isolated sets of low-angle cross-bedding. Scouring and internal truncation surfaces are common. The three types of sand sheets are considered to reflect deposition under changing climatic conditions, varying from humid to arid or semi-arid. Aeolian deposits are preserved within the sand sheets showing characteristics of dominantly perennial flow punctuated by shorter periods of desiccation (Type II), while sand sheets showing features typical of arid and or semi-arid flow conditions (Type III) contain no preserved aeolian deposits. This selective preservation is interpreted to be a result of the combined effect of groundwater table level and fluvial style which in turn are inferred to have been controlled by the climatic regime. The deposits show that during pre-vegetational times the preservation of aeolian deposits, under certain conditions, may be more optimal in fluvial systems formed in a humid climate than in fluvial systems formed under semi-arid or arid circumstances. The occurrence of aeolian deposits within a Precambrian succession of fluvial deposits therefore, need not be an indication of the most arid environmental conditions.     

Brittle-plastic deformation in initially dry rocks at fluid-present conditions: transient behaviour of feldspar at mid-crustal levels

We present detailed microstructural and chemical analyses from an initially dry anorthositic rock deformed during wet amphibolite facies conditions. Three different domains representing the microstructural variation of the deformed samples are investigated in detail in terms of fracture morphology and mode, grain characteristics and chemistry of present phases. Results show transient deformational behaviour where a close interaction between brittle, plastic and fluid-assisted deformation mechanisms can be observed. Our analysis allows us to describe the succession, interrelationships and effects of active mechanisms with progressively increasing strain in three so-called stages. In Stage 1, initial fracturing along cleavage planes promoted fluid influx that caused fragmentation and chemical reactions, producing fine-grained mineral assemblages in the fractures. Deformation twins and dislocations developed in clast pieces due to stress relaxation. Passive rotation of conjugate fracture sets and interconnection of intracrystalline fractures formed micro-shear-zones, constituting Stage 2. Microstructures and grain relationships indicate the activity and fluctuation between fracturing, dissolution-precipitation creep, grain boundary sliding and locally dislocation creep, reflecting the transient behaviour of brittle and plastic deformation mechanisms. Further rotation and widening of fractures into overall foliation parallel shear-bands (Stage 3) promoted strain partitioning into these areas through increased fluid influx, influence of fluid-assisted grain boundary sliding, phase mixing and presence of weak phases such as white mica. We suggest that local differences in fluid availability, volume fraction of weak phases produced by fluid present metamorphic reactions coupled with volume increase and local variations in stress concentration induced transient brittle-plastic behaviour. The studied shear-zone represents an example of the transformation of a rigid dry rock to a soft wet rock during deformation through syntectonic fracturing.