Photoluminescence of zircon (ZrSiO4) doped with REE3+ (REE = Pr, Sm, Eu, Gd, Dy, Ho, Er)

The photoluminescence properties of synthetic zircon, ZrSiO₄, doped with REE³⁺ (REE = Pr, Sm, Eu, Gd, Dy, Ho, Er) were investigated using combined excitation and emission spectroscopy. All samples showed luminescence characteristics of intra-ion energy transitions, similar to other lanthanide-doped materials. However, the relative intensities were dependent on the energy of excitation and the presence of charge-transfer bands were inferred from excitation spectra. From the data, we conclude that the lanthanides in zircon occur in more than one type of coordination. Energy transfer between different lanthanides was observed in some co-doped samples and emissions that were unassigned in previous studies have been assigned to specific lanthanides based on excitation spectroscopy.     

An empirical model for predicting flakiness in cone crushing

A fundamental understanding of the factors influencing particle shape is of central importance for optimisation of the output quality from crushing plants for aggregate production. The literature reports that the wear on and setting of a cone crusher influence particle shape, The fact that wear on and the setting of a cone crusher influence particle shape is considered common knowledge and is also reported in the literature. To date, no mathematical model for predicting particle shape has been presented.     

Explanatory analysis of the relationship between atmospheric circulation and occurrence of flood‐generating events in a coastal city

The aim of this study is to enhance the understanding of the occurrence of flood‐generating events in urban areas by analysing the relationship between large‐scale atmospheric circulation and extreme precipitation events, extreme sea water level events and their simultaneous occurrence, respectively. To describe the atmospheric circulation, we used the Lamb circulation type (LCT) classification and re‐grouped it into Lamb circulation classes (LCC). The daily LCCs/LCTs were connected with rare precipitation and water‐level events in Aarhus, a Danish coastal city. Westerly and cyclonic LCCs (W, C, SW and NW) showed a significantly high occurrence of extreme precipitation. Similarly, for extreme water‐level events westerly LCCs (W and SW) showed a significantly high occurrence. Significantly low occurrence of extreme precipitation and water‐level events was obtained in easterly LCCs (NE, E and SE). For concurrent events, significantly high occurrence was obtained in LCC W. We assessed the change in LCC occurrence frequency in the future based on two regional climate models (RCMs). The projections indicate that the westerly directions in LCCs are expected to increase in the future. Consequently, simultaneous occurrence of extreme water level and precipitation events is expected to increase in the future as a result of change in LCC frequencies. The RCM projections for LCC frequencies are uncertain because the representation of current LCCs is poor; a large number of days cannot be classified and the frequencies of the days that can be classified differ from the observed time series. Copyright © 2015 John Wiley & Sons, Ltd.     

The MgCr2O4–MgFe2O4 solid solution series: effects of octahedrally coordinated Fe3+ on T–O bond lengths

The influence on the spinel structure of Fe³⁺ → Cr substitution was studied in flux-grown synthetic single crystals of the magnesiochromite–magnesioferrite (MgCr₂O₄–MgFe₂O₄) solid solution series. Samples were analysed by single-crystal X-ray diffraction, electron microprobe analyses, optical absorption and Mössbauer spectroscopy. With the exception of iron-poor samples (3–12 mol-% MgFe₂O₄), optical absorption and Mössbauer spectra show that iron occurs almost exclusively as trivalent Fe in the present samples. A very intense and broad absorption band at ca 7,800 cm^?1 dominates the optical absorption spectra of samples with higher Fe-contents. The appearance of this band is related to a distinct structural disorder of Fe³⁺ and a development of magnetic ordering as demonstrated by Mössbauer spectra. Profound composition-related changes are observed in the Mössbauer spectra, which are magnetically unsplit in the range 2–41 mol-% magnesioferrite, but become magnetically split in the range 59–100 mol-% magnesioferrite. Structural parameters a ₀ and M–O increase with magnesioferrite content and inversion degree, while u and T–O decrease. Our study confirms the previously reported (Lavina et al. 2002) influence of Fe³⁺ at the M site on T–O bond lengths in the spinel structure.     

The Greenland Ice Core Chronology 2005, 15–42 ka. Part 1: constructing the time scale

The Greenland Ice Core Chronology 2005, GICC05, is extended back to 42 ka b2k (before 2000 AD), i.e. to the end of Greenland Stadial 11. The chronology is based on independent multi-parameter counting of annual layers using comprehensive high-resolution measurements available from the North Greenland Ice Core Project, NGRIP. These are measurements of visual stratigraphy, conductivity of the solid ice, electrolytical melt water conductivity and the concentration of Na⁺, Ca²⁺, SO₄²⁻, NO₃⁻, NH₄⁺. An uncertainty estimate of the time scale is obtained from identification of ‘uncertain’ annual layers, which are counted as 0.5±0.5 years. The sum of the uncertain annual layers, the so-called maximum counting error of the presented chronology ranges from 4% in the warm interstadial periods to 7% in the cold stadials. The annual accumulation rates of the stadials and interstadials are on average one-third and half of the present day values, respectively, and the onset of the Greenland Interstadials 2, 3, and 8, based on 20 year averaged δ¹⁸O values, are determined as 23,340, 27,780, and 38,220 yr b2k in GICC05.     

Upper Devonian tetrapod palaeoecology in the light of new discoveries in East Greenland

For the first time, new material of one of the world's oldest known tetrapods, Acanthostega, has been studied in its sedimentological context. The reported evidence suggests that Acanthostega was primarily aquatic and inhabited active fluvial channels in fluvial-dominated environments.     

Painting the floor with a hammer: Technical fixes in fisheries management

Fisheries management benefits from the contribution of several academic disciplines, each with their own perspectives, concerns and solutions. In this essay we argue that the contribution of biology, economics, sociology and other relevant disciplines to fisheries would be improved if they originated from broader, more integrated analytical perspectives that are attuned to the empirical realities of fisheries management. Today, disciplinary boundaries narrow the perspectives of fisheries management, creating tunnel vision and standardized technical fixes to complex and diverse management problems. Having worked separately and together for a number of years in fisheries research and consultancy in many parts of the world we, as a group of biologists, economists and sociologists, feel that the time to rid ourselves from disciplinary dogmatism is long overdue. We claim that improvements in fisheries management will be realized not through the promotion of technical fixes but instead by embracing and responding to the complexity of the management problem.