The role of radiation in an inversion-capped planetary boundary layer

In an inversion-capped planetary boundary layer (PBL), the structure of the turbulent fluxes as well as the height of the inversion are determined by the interaction of turbulent mixing in the PBL, large-scale subsidence above the PBL and radiational cooling. Here the sensitivity of the inversion height and of the turbulent fluxes due to radiational processes is investigated with the aid of a three-layered model for a well mixed PBL. For an example of the Trade-Wind region, the inversion height (i.e., the difference between surface pressure and pressure at the inversion level) varies between 46 and 257 mb and the surface flux of moist static energy between 417 and 99 W m^-2, if the (mean) radiative net flux divergence for both the inversion and the well-mixed layer is changed over a reasonable range of values. None of the parameterization schemes existing in the literature is able to describe these radiational effects in an appropriate way. This is due to the fact that these parameterizations are either not or not flexibly enough linked to the thermodynamical model parameter. Therefore the demand for an adequate parameterization of the radiational influence in a well-mixed PBL under a subsidence inversion is obvious.     

Crystallization and age of zircon from Corsican ophiolitic albitites: consequences for oceanic expansion in Jurassic times

In Corsica, albitites and albite-granites are considered to be the latest products of an ophiolitic magma. Two albitites have been selected for a study of the morphology, typology and age of their zircons, applying for the first time the U-Pb method to Western Tethyan ophiolites. Both samples come from the Rospigliani series, possibly formed in a transform fault zone. The first one shows a cumulate texture, whereas the second has features indicative of more rapid cooling. Zircons have precipitated at the end of the fractional crystallization process after a strong enrichment in alkali and incompatible elements. In a typological diagram they plot at high temperature and high agpaicity indexes. These abundant large, euhedral to subhedral zircons, sometimes with fine zoning, may also contain inclusions of granitic composition which testifies to K fractionation in ophiolitic magmas. The U-Pb age of 161±3Myr is in the range of the ages obtained for Alpine and Apennines ophiolites. All these ophiolitic remnants belonging to the Liguro-Piedmont Basin may represent a portion of the Central Atlantic Ocean created during Middle and Upper Jurassic times.     

Pb and Sr isotopic systematics of some basalts and sulfides from the East Pacific Rise at 21°N (project RITA)

Tholeiitic basalts and sulfide deposits from the “Cyana” and “Alvin” diving programs (RITA project) on the East Pacific Rise were analyzed for Pb and Sr isotopes. The basalt data plot within the field defined previously by other East Pacific Rise basalts (²⁰⁶Pb/²⁰⁴Pb: 18.35–18.58;²⁰⁷Pb/²⁰⁴Pb: 15.48–15.53;²⁰⁸Pb/²⁰⁴Pb: 37.8–38.1;⁸⁷Sr/⁸⁶Sr: 0.7022–0.7025). Pb, U and Sr contents (～0.5, ～0.05 and ～110 ppm, respectively) and μ values (～6) are typical of MORB, whereas Th/U ratios (～3.5) are significantly higher.The Pb isotopic ratios of the sulfide samples are very homogeneous (²⁰⁶Pb/²⁰⁴Pb～18.47²⁰⁷Pb/²⁰⁴Pb～15.49²⁰⁸Pb/²⁰⁴Pb～37.90), and plot in the middle of the basalt field. This indicates that (1) the sulfide Pb was derived from the basaltic crust without any significant contribution from either seawater or hemipelagic sediments, and (2) the solutions from which the sulfides were deposited had uniform Pb isotopic composition. The Pb contents of three sulfide samples is relatively high (170–1310 ppm).The Sr contents of five sulfide samples are widely scattered from 12 to 210 ppm, with⁸⁷Sr/⁸⁶Sr ratios intermediate between basaltic and seawater values (0.70554±0.00005 to0.70795±0.00011). Leaching experiments show that both basalt-derived Sr and seawater Sr were present in the solutions which deposited the sulfides. In some cases, Sr was also adsorbed from seawater onto the sulfides following their deposition. Basalt-derived Sr and seawater Sr are also present in associated non-sulfide phases.     

Le Batholite de San Ramon,Cordillère Orientale du Pérou Central

Résumè Le batholite de San Ramon est constitue par un granite à gros grains ou porphyroïde, à biotite et parfois hornblende, de teinte rouge à grise. Il s'étend sur 90 km du Nord au Sud à la bordure est de la Cordillère Orientale du Pérou Central. Il recoupe des terrains carbonifères et on le retrouve en galets dans des conglomérats rouges sous-jacents aux calcaires triasico-liasiques. Son âge est précisé par une isochrone Rb/Sr en roches totales qui le fixe à 238±10 MA. Il s'agit donc d'un granite d'âge permien supérieur à trias inférieur en partie contemporain du volcanisme rhyolitique à andésitique qui accompagne le dépôt des molasses rouges Mitu post-léonardiennes et pré-ladiniennes. Avec d'autre granitoïdes tardi-hercyniens de la Cordillère Orientale, il témoigne de l'importance insuffisamment reconnue jusqu'alors du plutonisme associé à ce volcanisme »permo-triasique«.

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The batholith of San Ramon is made of a coarse-grained to porphyritic granite that bears biotite and also hornblende at some places. It extends over 90 km from north to south along the eastern boundary of the Eastern Cordillera of Central Peru. It intrudes Carboniferous and Lower Permian strata and is included as cobbles into the red conglomerates that underlie Triassic to Liassic carbonates. A Rb/Sr whole-rock isochron gives a Late Permian to Early Triassic age of 238±10 m. y. Thus the San Ramon granite appears to be in part coeval with the andesite to rhyolitic volcanism associated to the red Mitu molasses, that as a whole were deposited after the Late Leonardian and before the Lower Ladinian. Some other radiometric ages from the Eastern Cordillera granitoïds stress the extension of this Late Variscan plutonism.

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Zusammenfassung Der Batholit von San Ramon besteht aus einem grobkörnigen bis porphyrartigen Granit mit Biotiten und bisweilen Hornblenden von rötlicher bis grauer Farbe. Er erstreckt sich über 90 km in N—S-Richtung längs dem Ostrand der östlichen Cordillere von Zentralperu. Er durchschneidet Karbon- und Permablagerungen und findet sich in Gerollen des triadisch-liassische Kalke unterlagernden Konglomerats. Aus der Rb/Sr-Gesamtisochrone ergibt sich ein Alter von 238±10 M. J. Es handelt sich also um einen Granit aus dem Grenzbereich Perm—Trias, der zum Teil gleichaltrig mit dem rhyolitischen bis andesitischen Vulkanismus ist, der die Ablagerung der postleonardischen und praeladinischen roten Molasse Mitubegleitet. Im Verein mit anderen spätvariszischen Granitoïden weist er auf die bisher ungenügend erkannte Bedeutung des diesen permo-triadischen Vulkanismus begleitenden Plutonismus hin.

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Resumen El batolito de San Ramón esta localizado a lo largo del limite este de la Cordillera Oriental en el Perú Central. Esta compuesto por un granito de grano grueso que puede tambien ser porfiroide, contiene biotita y tambien hornablenda y su color varia de rojo a gris. Dicho granito intruye terrenos carboniferos y eo-pérmicos y se le encuentra formando parte de los cantos en los conglomerados rojos infrayacentes a la serie carbonatada triásico-liásica. Una isocrona Rb/Sr en rocas totales le da una edad de 238±10 m. y. es decir del Permico terminal o de la base del Triásico. Por lo tanto, el granito de San Ramón es contemporáneo con parte del volcanismo riolitico a andesítico asociado a la sedimentacion de las molasas rojas del grupo Mitu, la cual ocure entre el Leonardiano superior y el Ladiniano inferior. Junto con otros granitoïdes de la Cordillera oriental, el batolito de San Ramón demuestra la importancia del plutonismo asociado a este volcanismo »permo-triásico«.

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Geochemical study on a well in the Western Canada Basin: relation of the aromatic distribution pattern to maturity of organic matter

Thirty-one rock samples from a Western Canada Basin well have been analysed for aromatics, using glass capillary gas chromatography with simultaneous flame ionization and sulfur-selective flame photometric detection. A uniform aromatic distribution pattern with a marked predominance of di- and tricyclic aromatic hydrocarbons was observed throughout a depth interval of 3000 meters comprising Cretaceous and Jurassic sediments. The very high relative abundance of sulfur aromatics at two narrow intervals in the Triassic and Mississippian is attributed to a major change in facies. Gradual changes with increasing depth have been observed for a series of compound ratios, which had been calculated from the isomers of methyl- and dimethylphenanthrene, and their parent compounds. These changes reflect the increasing thermal maturation of the sedimentary organic matter. A Methylphenanthrene Index (MPI) has been introduced, which exhibited a very good correlation with vitrinite reflectance data. The MPI is the first maturity parameter which is based on a series of aromatic hydrocarbons. This hydrocarbon internal maturity parameter permits the recognition and definition of maturity levels in extracts which can be compared to the maturity (e.g. vitrinite reflectance) of source rocks.     

Untersuchungen an stengeligem Quarz eines Schriftgranites von Zwiesel,Bayern

Inhalt Optische und röntgenographische Untersuchungen zeigen, daß die Quarzstengel im Schriftgranit von Zwiesel über mehrere Zentimeter in ihrem optischen Drehvermögen und in der Orientierung konstant bleiben.Mit 1 Textabbildung