Heterotype Mischbarkeit zwischen Wolframit- und Rutilgruppe

Zusammenfassung Untersucht wurden die heterotypen Mischsysteme zwischen Wolframit- und Rutilgruppe FeNbO₄-TiO₂, FeNbO₄-FeTaO₄, FeWO₄- FeTaO₄ und FeWO₄-TiO₂. Aus der Stereometrie der Gitter läßt sich abschätzen, daß ein statistischer Übergang beider Gittertypen nicht wahrscheinlich ist.Im System FeWO₄-FeTaO₄ verkleinert sich die Mischungslücke mit sinkender Temperatur und verschwindet nach unten am FeTaO₄-Rand. Infolge des gleichsinnig geneigten Verlaufes beider Phasengrenzen ist die Temperatur der Umwandlung Rutil-Wolframitgitter für FeTaO₄ nicht extrapolierbar, die wahrscheinlich noch unter 570° C liegt.In den Systemen FeNbO₄- TiO₂ und FeNbO₄-FeTaO₄ hat die Mischungslücke ebenfalls gleichsinnig geneigte Begrenzungen. Die Mischungslücke verschwindet in diesen Systemen mit steigender Temperatur schon vor dem Systemrand. Es koexistieren dann in 1. Ordnung zwei heterotype Mischkristalle gleicher Zusammensetzung, aber verschiedenen Molvolumens. Der experimentell gefundene Diagrammtyp wird diskutiert.Aus Extrapolationen von Gitterkonstanten und Volumen von Mischkristallreihen gegen die Systemränder lassen sich diese Daten für die Rutilmodifikation von FeNbO₄ und die Wolframitmodifikation von FeTaO₄ finden, die beide in den experimentell untersuchten Zustandsbereichen instabil gegen die Wolframitmodifikation von FeNbO₄ bzw. die Rutilmodifikation von FeTaO₄ sind.Die Gehalte von Fe₂O₃ + Nb₂O₅ in Rutil (Ilmenorutil) sind Rutil-FeNbO₄-Mischkristalle.     

Interstitial flow through preferential flow paths in the hyporheic zone of the Oberer Seebach,Austria

We investigated interstitial flow velocities in the Oberer Seebach, Austria, with NaCl tracer injections at a sediment depth of 30 cm to estimate the hydraulic conditions experienced by invertebrates inhabiting the hyporheic zone. Flow velocity measured with tracers is taken as travel time of the water along a straight line between injection and sampling points, although the water flows around sediment particles, and thus travels a somewhat longer distance. From sections of stream sediment in which the interstitial spaces were replaced by concrete, we estimated that this difference amounts, on average, to 27% and used this factor to correct the results of our velocity measurements. Corrected interstitial water velocities ranged from 0.01 to 1.32 cm s^-1 and were independent of surface discharge. We also studied spatial flow patterns in the bed sediments with long-term tracer injections. The three-dimensional distribution of tracer concentrations 24 hours after the start of the injection indicated that interstitial water preferentially flows in a complex network of areas of high hydraulic connectivity. Reynolds numbers for flow in the hyporheic pore space ranged from 0.1 to 489, implying that the flow environment varies from laminar up to the zone of transition to turbulent flow. Therefore, invertebrates may have a size-related active choice of areas where either friction drag or pressure drag predominates. The consequence of flow patterns, such as those observed in our study, is that small-scale variability of hydraulic conditions may be an important determinant of the patchy invertebrate distribution in bed sediments.     

Determination of instantaneous sea surface,wave heights,and ocean currents using satellite observations of the global positioning system

Abstract

Using GPS phase observations in the kinematic mode, we are able to achieve centimeter accuracy in relative three‐dimensional coordinates. This could be verified even for fast‐moving sensors in aircraft, such as airborne photogrammetric cameras, at the time of exposure. Sophisticated kinematic software has been developed resolving cycle slips and carrier‐phase ambiguities during motion. To determine the instantaneous sea surface, the GPS receiver is placed in a free‐drifting buoy with the antenna on top. Differencing the 1‐Hz observations, wave heights can be determined as well as velocity and direction of ocean (tidal) currents.

This article deals with the experiences from a test for the practical realization of this proposal. Hardware installation, software, and data analysis are described. Plans to use such an observational scenario of a GPS buoy array in the North Sea for the calibration of the radar altimeter of the European satellite ERS‐1 are presented.     

Estimation of seismic drift demands for frame structures

A process is outlined and evaluated for the estimation of seismic roof and storey drift demands for frame structures from the spectral displacement demand at the first mode period of the structure. The spectral displacement demand is related to the roof drift demand for the multi‐degree‐of‐freedom (MDOF) structure using three modification factors, accounting for MDOF effects, inelasticity effects, and P‐delta effects. Median values and measures of dispersion for the factors are obtained from elastic and inelastic time history analyses of nine steel moment resisting frame structures subjected to sets of ground motions representative of different hazard levels. The roof drift demand is related to the storey drift demands, with the results being strongly dependent on the number of stories and the ground motion characteristics. The relationships proposed in this paper should prove useful in the conceptual design phase, in estimating deformation demands for performance assessment, and in improving basic understanding of seismic behaviour. Copyright © 2000 John Wiley & Sons, Ltd.     

Application of210Pb in soils

The spectroscopic measurement of soil samples is described.²¹⁰Pb data from a soil survey in western-Europe are briefly reviewed. The average²¹⁰Pb flux from the atmosphere, as determined from²¹⁰Pb _exc soil inventories, is 90 Bq m^–2a^–1. A simple one-dimensional box-chain model is described. The model simulates the vertical, post depositional transport of natural and fall-out radionuclides in the soil. Simulation of measured²¹⁰Pb _exc ,¹³⁴Cs,¹³⁷Cs, and²⁴¹Am soil profiles shows that mixing (bioturbation) is a very efficient transport mechanism. Lead seems to be strongly fixed to organic and clay particles. It is transported by the displacement of the organic and clay carrier substances. The mean residence time of lead, caesium, plutonium and americium in organic rich forest soils is in the order of 250–1000 years. An applicability study in investigate the use of²¹⁰Pb in erosion problems showed erosion rates from 60–180 g m^–2a^–1 on organic rich forest and meadow sites with 10°–25° slopes.This is the eighth of a series of papers to be published by this journal following the 20 ^th anniversary of the first application of²¹⁰Pb dating of lake sediments. Dr P. G. Appleby is guest editing this series.     

Cyclostratigraphic calibration of cretaceous magnetic polarity events (Cismon, Southern Alps, Italy)

In an introductory section the problems of constructing a geologic time scale and the role of magnetic reversals and Milankovitch cycles in geochronology are outlined. Results of a detailed cyclostratigraphic and magnetostratigraphic study of the Valanginian/Hauterivian part of the pelagic limestone section at Cismon in the Southern Alps are presented and used in conjunction to estimate the duration of magnetic subchrons between CM10N and CM8. The new estimates are shorter than in most published time scales by a factor of two to three. More research along these lines may make a revision of the Early Cretaceous time scale necessary.     

A simple spectral model for the modification of turbulence in flow over gentle hills

A model is presented which calculates the changes of the velocity variances and stress uw in flow over gentle isolated hills. At intermediate frequencies spectra of the velocity components are modified according to rapid distortion theory. At low frequencies spectral densities change in proportion to the square of the mean wind. The inner and outer layer of the flow are distinguished. Streamline curvature effects are accounted for in the vertical velocity variance and the covariance.The sensitivity of the model to several parameters is investigated. Then, its results are compared with measurements of turbulent flow over various hills and an escarpment. The model is able to simulate the structure of the modified variance and covariance fields although larger differences occur at individual positions. The calculated modified spectra compare well with observed spectra.     

1997年电子出版物(英)

科学期刊的出版和发行技术正在迅速变化．主要对Ap.J.如何使用电子投稿方式及该杂志的网上版作了介绍．同时也叙述了较快的审稿及非常快速的出版等方面的进展。     

Magnetostratigraphy of Early Cretaceous Maiolica sections of the Southern Alps (Cismon and Pra da Stua, Italy)

The bottom part of the Cretaceous Cismon section in the Southern Alps was sampled for high-resolution magnetostratigraphy. Although the almost pure pelagic nannofossil limestones ( c. 90 per cent CaCO₃) of the Maiolica/Biancone Formation are extremely weakly magnetized, stepwise thermal and alternating-field demagnetization removed overprints and isolated a characteristic remanent magnetization which is interpreted as a primary magnetization. The dominant magnetic carrier mineral is magnetite; a small fraction of haematite may be present. A clear reversal pattern can be correlated unambiguously with Mesozoic polarity chrons CM10N to CM8. A less well-constrained magnetostratigraphy from the Pra da Stua section could not be directly correlated with the global polarity scale, but biostratigraphic information allows its assignment to the interval CM10-CM5. A counterclockwise rotation of 56 and a northward translation of 28 latitude for the Cismon locality since the Early Cretaceous are derived from the palaeomagnetic data, consistent with previous results from the Southern Alps. The high-resolution magnetostratigraphy of the Cismon section is used in an effort to refine the Cretaceous timescale by the combination of magnetostratigraphic and cyclostratigraphic results from the same section. The cyclostratigraphic duration estimates of chrons CM10N to CM8 are compared to their equivalents in a number of traditional timescales and found to be shorter by a factor of 1.26-2.58.