A comprehensive study on the surface chemistry of particulate matter collected from Jeddah,Saudi Arabia

In this work, the X-ray Photoelectron Spectroscopy (XPS) technique is utilized to analyze the surface chemical composition of particulate matter (PM) which was collected from various locations at Jeddah, Saudi Arabia. The main elements found on the surface of PM are carbon (C), oxygen (O) and silicon (Si) with combined percentage of 89.4–94.9 while traces of nitrogen (N), calcium (Ca), aluminum (Al), sodium (Na), chlorine (Cl), manganese (Mg), and sulfur (S) were also present. The analyzed XPS chemical state of C, O and Si was further used to determine their bonding with other elements occurring over the surface of PM. Carbon was found in the form of carbides (18.86%), fluorides (2.39%) and carbonates (78.75%); oxygen was observed as oxides (21.05%) and hydroxides (73.42%) of other metals; and silicon was detected as silicones (12.16%), nitrides (82.53%) and silicates (5.25%). The particle size of a PM is also of great concern for health issues, and thus has been investigated by the Field Emission Scanning Electron Microscope (FESEM). The Energy Dispersive X-ray Spectroscopy (EDS) was employed for cross verification of detected elements by XPS.     

Behavioral of sediment transport at lowland and mountainous rivers: a special reference to selected Malaysian rivers

Mountain rivers and lowland rivers differ in many ways. Some of the many elements that distinguish both river systems apart are the rivers’ geomorphological appearances, hydraulic geometry, pollution transport, sediment transport, and its own roughness and coarseness. In this particular study, the element of sediment transport is given distinctive attention too. This study employs the deterministic approach for bed load prediction entailing the use of the parameterization concept where particle size and flow variation is taken into full consideration. Apart from that, the classical approach of Shields number is also used to determine the transport rates at the fluvial system. However, due to some limitation and range of applicability, the Shields number approach was re-modified to suit the range of applicability. Changes were made to the alleviating critical stress term and formulating exponential approach. For this research, it was important to deduce the underlying principles which are universal and common to all river systems, due to obvious and distinct differences between the mountain and lowland rivers. A special attribute was given to the Malaysian natural rivers because of the limited recorded data available. All datasets were compiled and tested with the bed load predictors to observe the commonality pattern between the lowland and mountain river systems. Most of the bed load transport equations limit the range of applicability by isolating the flow regime or bed roughness individually. Thus, it was vital for researchers to find the commonality pattern between these two river systems which needed to be statistically sound in its form. It was postulated that the particle densimetric Froude number is graphically and statistically fit for both river systems. Hence, this predictor is used as it has a high potential to be included in the sediment transport parameterization for Malaysian natural rivers.     

Noise Reduction Technique Applied to the Multichannel Analysis of Surface Waves

This paper shows the presence of noises and technique to reduce these noises during the surface wave analysis. The frequency-dependent properties of Rayleigh-type surface waves can be used for imaging and characterizing the shallow subsurface. Interference by coherent source-generated noise inhibits the reliability of shear-wave velocities determined through inversion of the phase velocities of Rayleigh waves. Among these interferences by non-planar, non-fundamental mode Rayleigh waves (noise) are body waves, scattered and non-source-generated surface waves, and higher-mode surface waves. For the reduction of noise, the filtering technique is implemented in this paper for the multichannel analysis of surface wave method (MASW). With the de-noising technique during the MASW method, more robust and reliable outcome is achieved. The significance of this paper is to obtain pre-awareness about noises during surface wave analysis and take better outcomes with de-noising performance in near surface soil investigations.     

Arsenite removal from water by electro-coagulation on zinc–zinc and copper–copper electrodes

Removal of arsenite from aqueous solution was carried out using electro-coagulation method. The experiments were conducted using copper–copper and zinc–zinc electrodes. The optimized experimental parameters were 2.0 mg/L initial concentration, 16.0-min processing time, 6.0 pH, 3.0-V applied voltage and 30 °C temperature for zinc–zinc electrodes while these values for copper–copper electrodes were 2.0 mg/L initial concentration, 20.0-min processing time, 7.0 pH, 5.0-V applied voltage and 30 °C temperature. The results demonstrated that zinc–zinc and copper–copper electrodes removed arsenite up to 99.89 and 99.56 %, respectively. The treated water was clear, colorless and odorless without any secondary contamination. There was no change in water quality after the removal of arsenite. The reported method is capable to remove arsenite from water at 6–7 pH range, which is a pH range of natural water. Therefore, this method may be the choice of arsenite removal from natural ground water.     

Analytic network process for criteria selection in sustainable coastal land use planning

The coastal lands are very important boundaries in the natural system. But these areas are under pressure that has threatened their health by short-sighted planning policies. The management options have focused on economic production and human benefits rather than the natural systems that guaranty sustainability of them. Evaluation of sustainability in coastal lands needs some critical criteria and indicators. The purpose of this paper is to demonstrate an innovative reliable method for identification of the most important criteria and indicators using multi criteria techniques, especially the Analytic Network Process (ANP). Analytic Network Process as a new approach has potential to be applied into the field of coastal land use development. This is the first time ANP has been used for criteria selection to ensure sustainability in coastal land use planning. The integration of social, economic and environmental criteria within the planning framework in this paper has provided a holistic approach for integrated coastal land use development.     

Middle Permian cephalopods from central Peninsular Malaysia: implications for faunal migration through the southern Tethys

A Wordian (Middle Permian) cephalopod fauna consisting of four ammonoid species, Tauroceras aff. scrobiculatum (Gemmellaro), Agathiceras sp., Bamyaniceras orientale n. sp. and Pronoritidae gen. and sp. indet., and two nautiloid species, Tainoceras sp. and Orthocerida fam. indet., were recovered from the Bera South area, southern Pahang, Peninsular Malaysia. The outcrop represents the southernmost extent of the Bera Formation. Bamyaniceras and Tainoceras are recorded in Malaysia for the first time. The presence of T. aff. scrobiculatum suggests a regional correlation with an ammonoid-bearing bed of Sungai Cheroh, western Pahang, and permits global correlations with strata of northeastern Iraq, northern Oman and Sicily (Italy). A possible eastwards faunal migration through the southern Tethys is suggested.     

Observed Trends in Extreme Temperature over the Klang Valley,Malaysia

This study investigates the recent extreme temperature trends across 19 stations in the Klang Valley, Malaysia, over the period 2006-16. Fourteen extreme index trends were analyzed using the Mann-Kendall non-parametric test, with Sen’s slope as a magnitude estimator. Generally, the annual daily mean temperature, daily mean maximum temperature, and daily mean minimum temperature in the Klang Valley increased significantly, by 0.07°C yr~(-1), 0.07°C yr~(-1)and 0.08°C yr~(-1),respectively. For the warm temperature indices, the results indicated a significant upward trend for the annual maximum of maximum temperature, by 0.09°C yr~(-1), and the annual maximum of minimum temperature, by 0.11°C yr~(-1). The results for the total number of warm days and warm nights showed significant increasing trends of 5.02 d yr~(-1)and 6.92 d yr~(-1),respectively. For the cold temperature indices, there were upward trends for the annual minimum of maximum temperature,by 0.09°C yr~(-1), and the annual minimum of minimum temperature, by 0.03°C yr~(-1), concurrent with the decreases in the total number cold days (TX10P), with-3.80 d yr~(-1), and cold nights (TN10P), with-4.33 d yr~(-1). The 34°C and 37°C summer days results showed significant upward trends of 4.10 d yr~(-1) and 0.25 d yr~(-1), respectively. Overall, these findings showed upward warming trends in the Klang Valley, with the minimum temperature rate increasing more than that of the maximum temperature, especially in urban areas.     

Prediction of long-term settlement on soft clay using shear wave velocity and damping characteristics

This paper presents a method of calculating long-term settlement of a loaded pad on soft clay at Klang, Selangor, Malaysia where the soil model is treated as an anelastic material of viscoelastic property. Initially, an elastic shear modulus (G) value from shear wave velocity profiles of the seismic tests from spectral analysis of surface wave (SASW) and continuous surface wave (CSW) tests was obtained. A value of damping (D) at an equivalent elastic strain is then calculated from the hysteresis of the plate load tests corrected to equivalent strain using the Damping–Strain formula. The calculated elastic settlement and its equivalent damping are then used to calculate the long-term settlement by applying the generalised viscoelastic formula. Comparisons to traditional methods of settlement predictions were made and the viscoelastic formula has shown better agreement to the observed settlement. Further modification of the settlement formula is introduced to improve the settlement accuracy to 10%.     

Evaluation of heavy metal contamination in groundwater samples from Kapas Island,Terengganu, Malaysia

An attempt has been made to delineate the hydrochemistry for a small island based on the major ions and heavy metal concentrations. In this investigation, six sampling campaigns were conducted to measure the concentrations of major ions (Ca, Mg, Na, K, HCO₃, Cl, and SO₄) and heavy metals (Zn, Cr, Pb, Mn, As, and Cu) in groundwater samples collected from seven sampling stations (boreholes) located on Kapas Island, Terengganu, Malaysia. The distribution of major ions is illustrated by a piper plot where Ca–HCO₃ is the dominant type. In addition, the concentrations of heavy metals demonstrate that Mn shows as being the highest concentrated heavy metal in the groundwater sampled in the sampling campaigns; the average Mn content in groundwater sampled was 54.05 μg/L. However, a comparison of the heavy metal (Mn, Cr, Zn, As, Pb, and Cu) concentrations in groundwater samples with the Drinking Water Quality Standard prescribed by World Health Organization reveals that none of these heavy metals exceeded the recommended threshold limits. The principal component analyses (PCA) extracted four components that control the groundwater chemistry. Components 1 and 2 from the PCA analyses extracted approximately 52.11 % of the total variance, which represent the heavy metals (As and Mn) and physical parameters (pH, redox potential, electrical conductivity, temperature, and total dissolved solids). Based on the output of the PHREEQC hydrogeochemical software, several species of heavy metals exist, in which the dominant species found are Mn²⁺, PbCO₃, Cu(OH)₂, and Zn⁺.