Evaluating methods for quantifying cation exchange in mildly calcareous sediments in Northern Alberta

Cation exchange capacity (CEC) and exchangeable cation composition are important properties in defining water–sediment interactions in contaminant transport scenarios, such as the seepage of process-affected water from oil sands tailings impoundments. At present, detailed characterization of these properties has been overlooked in the surficial Pleistocene sediments of the Athabasca Oil Sands region in Canada. Although a great variety of methods for determining CEC exist and continue to be developed, there is a deficiency in detailed comparisons amongst these methods in the literature, and consequently uncertainty still remains as to which extractants/methods are most suitable for use with sediments containing partially soluble carbonate salts. The present study (1) conducts an up-to-date evaluation of several distinct methods for their suitability in characterizing cation exchange properties in mildly calcareous sediments; using them to (2) evaluate the sorptive capacity and easily displaceable cations of mildly calcareous, surficial sediments near Fort McMurray, Alberta. Four conceptually different CEC methods were chosen: (a) a summation method (Lithium Chloride extractant); (b) a method that displaces an index cation after intermediary washes (Sodium Acetate–Ammonium Acetate); (c) a method using a high affinity cation complex (Silver Thiourea); and (d) a titration method using an organic cationic dye (Methylene Blue). Exchangeable cations were characterized using the Lithium Chloride and Silver Thiourea methods. Analysis suggests that the Methylene Blue test is least impacted by the presence of carbonate mineral phases. Results from field sediments suggest that the exchangeable cations, in decreasing abundance, consist of Ca > Mg > K > NH₄ > Na; while the CEC was found to be 4.7 ± 2.7 meq 100 g⁻¹ in the clay-rich glacial till, 0.7 ± 0.0 meq 100 g⁻¹ in the underlying sand and 4.1 ± 2.3 meq 100 g⁻¹ in the till-sand transition zone.     

Revisiting effect of ocean diapycnal mixing on Atlantic meridional overturning circulation recovery in a freshwater perturbation simulation

The effects of ocean density vertical stratification and related ocean mixing on the transient response of the Atlantic meridional overturning circulation （AMOC） are examined in a freshwater perturbation simulation using the Bergen Climate Model （BCM）. The results presented here are based on the model outputs of a previous freshwater experiment： a 300-year control integration （CTRL）, a freshwater integration （FW1） which started after 100 years of running the CTRL with an artificially and continuously threefold increase in the freshwater flux to the Greenland-Iceland-Norwegian （GIN） Seas and the Arctic Ocean throughout the following 150-year simulation. In FW1, the transient response of the AMOC exhibits an initial decreasing of about 6 Sv （1 Sv=106 m3 s^-1） over the first 50-year integration and followed a gradual recovery during the last 100-year integration. Our results show that the vertical density stratification as the crucial property of the interior ocean plays an important role for the transient responses of AMOC by regulating the convective and diapycnal mixings under the enhanced freshwater input to northern high latitudes in BCM in which the ocean diapycnal mixing is stratification-dependent. The possible mechanism is also investigated in this paper.     

Modelling impacts of agricultural practice on flood peaks in upland catchments: An application of the distributed TOPMODEL

Upland agricultural land management activities such as grazing, vegetation burning, and bare ground restoration impact hydrological elements of headwater catchments, many of which may be important for downstream flood peaks (e.g., overland flow and soil water storage). However, there is poor understanding of how these management practices affect river flow peaks during high magnitude rainfall events. Using the distributed TOPMODEL, spatial configurations of land management were modelled to predict flood response in an upland catchment, which contains different regions operating subsidized agricultural stewardship schemes. Heavy grazing leading to soil compaction and loss of vegetation cover in stewardship regions covering 79.8% of the catchment gave a 42‐min earlier flow peak, which was 82.2% higher (under a 1‐hr 15‐mm storm) than the current simulated hydrograph. Light grazing over the same regions of the catchment had much less influence on river flow peaks (18 min earlier and 32.9% increase). Rotational burning (covering 8.8% of the catchment), most of which is located in the headwater areas, increased the peak by 3.2% in the same rainfall event. Vegetation restoration with either Eriophorum or Sphagnum (higher density) in bare areas (5.8%) of the catchment provided a reduction of flood peak (3.9% and 5.2% in the 15‐mm storm event), whereas the same total area revegetated with Sphagnum in riparian regions delivered a much larger decrease (15.0%) in river flow peaks. We show that changes of vegetation cover in highly sensitive areas (e.g., near‐stream zones) generate large impacts on flood peaks. Thus, it is possible to design spatially distributed management systems for upland catchments, which reduce flood peaks while at the same time ensuring economic viability for upland farmers.     

Hydrogeology,Chemical and Microbial Activity Measurement Through Deep Permafrost

Little is known about hydrogeochemical conditions beneath thick permafrost, particularly in fractured crystalline rock, due to difficulty in accessing this environment. The purpose of this investigation was to develop methods to obtain physical, chemical, and microbial information about the subpermafrost environment from a surface‐drilled borehole. Using a U‐tube, gas and water samples were collected, along with temperature, pressure, and hydraulic conductivity measurements, 420 m below ground surface, within a 535 m long, angled borehole at High Lake, Nunavut, Canada, in an area with 460‐m‐thick permafrost. Piezometric head was well above the base of the permafrost, near land surface. Initial water samples were contaminated with drill fluid, with later samples <40% drill fluid. The salinity of the non‐drill fluid component was <20,000 mg/L, had a Ca/Na ratio above 1, with δ¹⁸O values ～5‰ lower than the local surface water. The fluid isotopic composition was affected by the permafrost‐formation process. Nonbacteriogenic CH₄ was present and the sample location was within methane hydrate stability field. Sampling lines froze before uncontaminated samples from the subpermafrost environment could be obtained, yet the available time to obtain water samples was extended compared to previous studies. Temperature measurements collected from a distributed temperature sensor indicated that this issue can be overcome easily in the future. The lack of methanogenic CH₄ is consistent with the high sulfate concentrations observed in cores. The combined surface‐drilled borehole/U‐tube approach can provide a large amount of physical, chemical, and microbial data from the subpermafrost environment with few, controllable, sources of contamination.     

Changes in the Tropical Cyclone Genesis Potential Index over the Western North Pacific in the SRES A2 Scenario

The Tropical Cyclone Genesis Potential Index (GPI) was employed to investigate possible impacts of global warming on tropical cyclone genesis over the western North Pacific (WNP). The outputs of 20th century climate simulation by eighteen GCMs were used to evaluate the models’ ability to reproduce tropical cyclone genesis via the GPI. The GCMs were found in general to reasonably reproduce the observed spatial distribution of genesis. Some of the models also showed ability in capturing observed temporal vari...     

Holocene sea-surface temperature variability in the Chilean fjord region

Here we provide three new Holocene (11–0 cal ka BP) alkenone-derived sea surface temperature (SST) records from the southernmost Chilean fjord region (50–53°S). SST estimates may be biased towards summer temperature in this region, as revealed by a large set of surface sediments. The Holocene records show consistently warmer than present-day SSTs except for the past ~ 0.6 cal ka BP. However, they do not exhibit an early Holocene temperature optimum as registered further north off Chile and in Antarctica. This may have resulted from a combination of factors including decreased inflow of warmer open marine waters due to lower sea-level stands, enhanced advection of colder and fresher inner fjord waters, and stronger westerly winds. During the mid-Holocene, pronounced short-term variations of up to 2.5°C and a cooling centered at ~ 5 cal ka BP, which coincides with the first Neoglacial glacier advance in the Southern Andes, are recorded. The latest Holocene is characterized by two pronounced cold events centered at ~ 0.6 and 0.25 cal ka BP, i.e., during the Little Ice Age. These cold events have lower amplitudes in the offshore records, suggesting an amplification of the SST signal in the inner fjords.     

Geological modeling and simulation of CO2 injection in the Johansen formation

The Johansen formation is a candidate site for large-scale CO₂ storage offshore of the south-western coast of Norway. An overview of the geology for the Johansen formation and neighboring geological formations is given, together with a discussion of issues for geological and geophysical modelling and integrated fluid flow modelling. We further describe corresponding simulation models. Major issues to consider are capacity estimation and processes that could potentially cause CO₂ to leak out of the Johansen formation and into the formations above. Currently, these issues can only be investigated through numerical simulation. We consider the effect of different boundary conditions, sensitivity with respect to vertical grid refinement and permeability/transmisibility data, and the effect of residual gas saturations, since these strongly affect the CO₂-plume distribution. The geological study of the Johansen formation is performed based on available seismic and well data. Fluid simulations are performed using a commercial simulator capable of modelling CO₂ flow and transport by simple manipulation of input files and data. We provide details for the data and the model, with a particular focus on geology and geometry for the Johansen formation. The data set is made available for download online.