Development of a Default Vapor Intrusion Attenuation Factor for Industrial Buildings

An investigation at a major industrial facility in the Midwestern United States provides insights regarding the amount of attenuation of sub-surface vapors occurring at industrial buildings. The buildings at the facility were ranked in terms of vapor intrusion potential and testing began in October 2016 and is ongoing. Results have been evaluated for data collected at 718 unique locations across 77 buildings. A total of 1646 sample pairs (sub-slab and indoor air) have been collected and analyzed for 65 analytes, resulting in a total of 106,990 data pairs. As many as 49 sample pairs were collected within a given building during a single sampling event and up to 11 rounds of seasonal testing have been performed at selected buildings. Seasonal variability in sub-slab soil-gas concentrations was found to be negligible. Data analysis was performed to look for data trends across the entire data set and identify inter-building comparisons. This data evaluation focused on individual volatile organic compounds (e.g., tetrachloroethylene, trichloroethylene) present in the sub-slab soil gas at concentrations exceeding 1000 μg/m³. A total of 157 building-specific attenuation coefficients (α) were evaluated. This evaluation demonstrated that large industrial buildings have a much greater attenuation than that assumed for single-family residential buildings. All attenuation coefficient values were lower than 0.03, which is the standard regulatory default for non-residential buildings. The median value was 9.3E-05 and the 95% upper confidence limit was 2.7E-04. There is some evidence of lower attenuation under wintertime conditions. The data suggests that the default attenuation factor of 0.03 over-predicts indoor air impacts at this industrial facility by at least two orders of magnitude.     

Exhumation and incision history of the Lahul Himalaya, northern India, based on (U–Th)/He thermochronometry and terrestrial cosmogenic nuclide methods

Low-temperature apatite (U–Th)/He (AHe) thermochronology on vertical transects of leucogranite stocks and ¹⁰Be terrestrial cosmogenic nuclide (TCN) surface exposure dating on strath terraces in the Lahul Himalaya provide a first approximation of long-term (10⁴–10⁶ years) exhumation rates for the High Himalayan Crystalline Series (HHCS) for northern India. The AHe ages show that exhumation of the HHCS in Lahul from shallow crustal levels to the surface was ~ 1–2 mm/a and occurred during the past ~ 2.5 Ma. Bedrock exhumation in Lahul fits into a regional pattern in the HHCS of low-temperature thermochronometers yielding Plio-Pleistocene ages. Surface exposure ages of strath terraces along the Chandra River range from ~ 3.5 to 0.2 ka. Two sites along the Chandra River show a correlation between TCN age and height above the river level yielding maximum incision rates of 12 and 5.5 mm/a. Comparison of our AHe and surface exposure ages from Lahul with thermochronometry data from the fastest uplifting region at the western end of the Himalaya, the Nanga Parbat syntaxis, illustrates that there are contrasting regions in the High Himalaya where longer term (10⁵–10⁷ years) erosion and exhumation of bedrock substantially differ even though Holocene rates of fluvial incision are comparable. These data imply that the orogen's indenting corners are regions where focused denudation has been stable since the mid-Pliocene. However, away from these localized areas where there is a potent coupling of tectonic and surface processes that produce rapid uplift and denudation, Plio-Pleistocene erosion and exhumation can be characterized by disequilibrium, where longer term rates are relatively slower and shorter term fluvial erosion is highly variable over time and distance. The surface exposure age data reflect differential incision along the length of the Chandra River over millennial time frames, illustrate the variances that are possible in Himalayan river incision, and highlight the complexity of Himalayan environments.     

Quaternary drainage network reorganization in the Colombian Eastern Cordillera plateau

Dramatic drainage reorganization from initial longitudinal to transversal domains has occurred in the Eastern Cordillera of Colombia. We perform a regional analysis of drainage basin geometry and transformed river profiles based on the integral form of the slope-area scaling, to investigate the dynamic state of drainage networks and to predict the degree of drainage reorganization in this region. We propose a new model of drainage rearrangement for the Eastern Cordillera, based on the analyses of knickpoint distribution, normalized river profiles, landforms characteristic of river capture, erosion rates and palaeodrainage data. We establish that the oldest longitudinal basin captured by the Magdalena River network was the Suárez Basin at ≈409 ka, inferring the timing of abandonment of a river terrace using in situ produced cosmogenic beryllium-10 (¹⁰Be) depth profiles and providing a first estimation of incision rate of 0.07 mm/yr. We integrate published geochronologic data and interpret the last capture of the Sabana de Bogotá, providing a minimum age of the basin opening to the Magdalena drainage at ≈38 ka. Our results suggest that the Magdalena basin Increased its drainage area by integrating the closed basins from the western flank of the Eastern Cordillera. Our study also suggests that the Magdalena basin is an aggressor compared to the basins located in the eastern flank of the orogen and provides a framework for examining drainage reorganization within the Eastern Cordillera and in similar orogenic settings. The results improve our understanding of headward integration of closed basins across orogenic plateaux. © 2020 John Wiley & Sons, Ltd.     

Atmospheric river orientation determines flood occurrence

Atmospheric Rivers (ARs) have been linked to many of the largest recorded UK winter floods. These large-scale features can be 500–800 km in width but produce markedly different flood responses in adjacent catchments. Here we combine meteorological and hydrological data to examine why two impermeable catchments on the west coast of Britain respond differently to landfalling ARs. This is important to help better understand flood generation associated with ARs and improve flood forecasting and climate-change impact assessment. Analysis of 32 years of a newly available ERA5 high-resolution atmospheric reanalysis and corresponding 15-min river flow data show that the most impactful ARs arise through a combination of the orientation and magnitude of their water vapour flux. At the Dyfi catchment, AR orientations of between 238–258° result in the strongest hydrological responses, whereas at the Teifi the range is 224–243°. We believe this differential flood response is the result of catchment orientation and topography enhancing or suppressing orographic rainfall totals, even in relatively low-relief coastal catchments. Further to the AR orientation, ARs must have an average water vapour flux of 400–450 kg m⁻¹ s⁻¹ across their lifetime. Understanding the preferential properties of impactful ARs at catchments allows for the linking of large-scale synoptic features, such as ARs, directly to winter flood impacts. These results using two test catchments suggest a novel approach to flood forecasts through the inclusion of AR activity.     

GLOBAL IGNORANCE

ABSTRACT. Stories exposing the lack of global knowledge among American high school and college students are ubiquitous. But it is not just students who have difficulty navigating a world map. Global ignorance, in fact, is appallingly prevalent even among scholars, journalists, and public intellectuals who write about globalization and world history. Otherwise erudite and insightful authors commit such basic geographical errors that they can only mystify the public. The present article focuses on, but is not limited to, the misconceptions of Benjamin Barber, Thomas L. Friedman, John Gray, David Landes, and Paul Krugman. It further explores the reasons why the debate over globalization, in particular, generates so much nonsense, and it concludes with a call for the revitalization of world geography.     

Probing pulsar winds using inverse Compton scattering

We investigate the effects of inverse Compton scattering by electrons and positrons in the unshocked winds of rotationally-powered binary pulsars. This process can scatter low energy target photons to produce gamma rays with energies from MeV to TeV. The binary radio pulsars PSR B1259−63 and PSR J0045−73 are both in close eccentric orbits around bright main sequence stars which provide a huge density of low energy target photons. The inverse Compton scattering process transfers momentum from the pulsar wind to the scattered photons, and therefore provides a drag which tends to decelerate the pulsar wind. We present detailed calculations of the dynamics of a pulsar wind which is undergoing inverse Compton scattering, showing that the deceleration of the wind of PSR B1259−63 due to ‘inverse Compton drag' is small, but that this process may confine the wind of PSR J0045−73 before it attains pressure balance with the outflow of its companion star. We calculate the spectra and light curves of the resulting inverse Compton emission from PSR B1259−63 and show that if the size of the pulsar wind nebula is comparable to the binary separation, then the γ-ray emission from the unshocked wind may be detectable by atmospheric Cherenkov detectors or by the new generation of satellite-borne γ-ray detectors such as INTEGRAL and GLAST. This mechanism may therefore provide a direct probe of the freely-expanding regions of pulsar winds, previously thought to be invisible.     

Oscillatory instability of radiative shocks with multiple cooling processes

The stand-off shock formed in the accretion flow on to a stationary wall, such as the surface of a white dwarf, may be thermally unstable, depending on the cooling processes which dominate the post-shock flow. Some processes lead to instability, while others tend to stabilize the shock. We consider competition between the destabilizing influence of thermal bremsstrahlung cooling, and a stabilizing process which is a power law in density and temperature. Cyclotron cooling and processes which are of order 1, 3/2 and 2 in density are considered. The relative efficiency and power-law indices of the second mechanism are varied, and particular effects on the stability properties and frequencies of oscillation modes are examined.     

Dissolved trace metals in the Western Mediterranean Sea: total concentration and fraction isolated by C18 Sep-Pak technique

An investigation of trace metal distributions in the Western Mediterranean Sea was carried out during the RRS Discovery cruise (July 1993) in which a transect from the Strait of Gibraltar to the Strait of Sicily was conducted. Organically complexed dissolved trace metals and their total concentrations were measured to investigate the end-members and to predict the environmental capacity of the Mediterranean for potential toxic metals. The distribution of trace metals can be accounted for by the mixing of several end-members and by some atmospheric inputs to the surface water. For Pb and Fe, the effects of the atmospheric inputs are more pronounced than for the other metals. Due to the rapid exchange of water masses, the Western Mediterranean may have the ability to assimilate the increased external inputs for some trace metals such as Cu, Cd, Ni and Zn. But the external inputs for Pb and Fe exceed the removal capacity of the Western Mediterranean and these elements may accumulate in the water column of the western basin. The C18 Sep-Pak technique and direct determination by DPASV were used to determine the amount of trace metal–organic complexes. The C18 Sep-Pak column isolates only a small fraction of trace metals except for Cu. The maximum hydrophobic fractions for the studied trace metals, except for Cd and Pb, which are not detectable, were found in the subsurface layer at all stations. This maximum may well be linked to picoplankton activity and the picoplankton, prochlorophytes may have an important role in the speciation of dissolved Cu as well as Synechococcus. These organic ligands for Cu were produced at the maximum of biological activity in the Western Mediterranean basin and seem to be accumulated at halocline level by Mediterranean hydrodynamic characteristics. However, direct determination by DPASV showed that the major part of Cu, Cd and Pb, complexed by organic materials, was not isolated by C18 Sep-Pak technique.     

Integral field spectroscopy of the gravitational lens HE1104‐1805

We present integral field spectroscopy of the double imaged quasar HE1104‐1805 taken with the optical fiber system INTEGRAL‐WYFFOS at theWHT telescope. From the spectra of the two components we have measured the continuum and line emission ratios, finding an offset between them that can be related to microlensing. (© 2004 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Using GIS and Dispersion Modelling Tools to Assess the Effect of the Environment on Health

A feasibility study in progress to integrate health and air quality information is presented. The methods of using integrated GIS and air quality dispersion modelling tools to assess the effect of the environment on health are discussed. The main aim is to model human personal exposure to air pollutants and compare the predictions to respiratory health data for asthmatics in a health telematics project. The MEDICATE project develops and tests the feasibility of using a health telematic system for asthmatics. Key to this is the determination of the real-time health (lung function) response to the ambient environment. For this, air quality information is related to respiratory measurements by modelling personal exposure through a GIS. The methods of integrating environmental modelling and assessment tools (GIS) in this case are examined. ESRI's ArcView is used to locate and compile environmental information about the patients' locations and lifestyles in the study areas (London and Barcelona). A dispersion modelling extension to ArcView, ADMS Urban, is used to interrogate the spatial environmental databases (e.g. emission inventories) to model air pollution concentrations. Patients' personal exposure is modelled by time-weighted estimates of their exposure to ambient air quality at each defined location. Lung function data can be compared on a time-wise basis with these air quality indicators to see if there is a relationship on an hourly, daily or lagged-day basis. The aim of this paper is to propose a methodology and discuss the integration and practicalities of using air quality assessment tools (inventories, dispersion modelling and a GIS) in assessing the impacts of the environment on human health.