Trace metals in Choromytilus meridionalis

Concentrations of metals in mature females of the mussel Choromytilus meridionalis are approximately twice those in males and some other trace elements also differ according to sex. If this species is to be used as an indicator of trace-metal pollution, comparative data should relate to individuals of similar size and care must be taken to determine whether differences in trace-metal content are the result of seasonal variations or reflect abnormal metal uptake.     

A finite-element study of fold propagation in a viscous layer

A finite-element model of a viscous layer contained in a viscous matrix and undergoing layer-parallel compression is used to examine the hypothesis that a long chain of folds, as found in real rocks, can originate from one initial perturbation to the layer geometry. This hypothesis is tested by determining the velocity with which a perturbation spreads along layers of various viscosities.An insight is gained into the roles played by local strain and local layer strength in the folding mechanism. The results show that for layers with viscosity ratios comparable with those of real rocks it is impossible for long chains of folds to originate from one perturbation. The authors conclude that rock layers contain many initial perturbations and folding originates at all perturbation sites simultaneously. The growth of such folds depends on the amplitude and shape of the initial perturbation and on subsequent interference between folds.     

The use of 210Pb as a heavy metal tracer in the Susquehanna River system

Analysis of soil profiles and shallow ground water in the Susquehanna River basin, northeastern U.S.A., indicates that the atmospheric flux of ²¹⁰Pb is efficiently scavenged by the organic-rich horizons of the soils. This atmospherically supplied ²¹⁰Pb in soil profiles can only be lost from the system by soil erosion. Based on the annual sediment yield of the Susquehanna River and the excess ²¹⁰Pb concentration in particulate matter, a mean residence time of 2000 yr is calculated for metals similar to Pb in soil profiles.The West Branch of the Susquehanna River (WBSR) is strongly affected by acid mine drainage and is low in pH and high in dissolved ( <0.4 μm) ²¹⁰Pb, Fe and Mn. Along its course iron hydroxide is precipitating at a pH of between 4 and 4.5 and the ²¹⁰Pb supplied by the acid mine water is diminished by about 25% as a result of dilution. As the WBSR enters the Valley and Ridge Province of the Appalachians it has a ²¹⁰Pb concentration of ~ 0.2 dpm/l. At this juncture it receives a considerable influx of alkalinity from tributaries draining carbonate terranes, resulting in neutralization of the sulfuric acid and increase of the river pH to around 6.5–7. This pH adjustment is accompanied by the precipitation of Fe and Mn. Due to the slow rate of Mn removal from solution, the Mn precipitation extends a considerable distance down river from the point of acid neutralization. Analyses for ²¹⁰Pb in the river at points in or below the region of Mn precipitation show that ²¹⁰Pb is rapidly scavenged from solution onto suspended particles. From the data it is possible to calculate the removal rate of Pb from water in the presence of Fe and Mn hydroxides and other particles. At a pH of 4–4.5 Pb removal is nonexistent relative to the river flow rate, but at a pH of 6.5–7 the ²¹⁰Pb data indicate a residence time of <0.7 day for dissolved Pb.     

TRANSIENT EM RESPONSE OF A LARGE LOOP ON A LAYERED GROUND *

The voltage induced in a horizontal loop on a layered ground has been calculated for the case where the loop is excited by a step current and measurements are made during the off-cycle. The expressions derived for a uniform ground show that for large time t the induced voltage E(t) is approximately given by E(t)?— (Ibαμ/20t) (σμ²/t)^3/2 where σ is the conductivity of the ground, μ the permeability, b the loop radius, and I the amplitude of the current step. For small times the corresponding result is E(t)?—Ibμ/2t. When the ground is composed of a number of layers a numerical procedure for calculating the induced voltage is described. The calculated responses of various multilayered structures show that at short times the induced voltage is asymptotic to that produced in the case of a uniform ground of conductivity equal to the top layer. Interference effects in the top layer can lead to anomalous decay curves which may result in the underestimation of the conductivity of a buried layer.     

Distribution of gold and rhenium between nickel-iron and silicate melts: implications for the abundance of siderophile elements on the Earth and Moon

The distribution equilibrium of Au and Re between nickel-iron and basaltic melts was studied at 1400–1600°C, using radioactive tracers. Metal/silicate distribution coefficients were 1–3 orders of magnitude higher than earlier estimates, as follows. Mauna Loa basalt—Fe₁₀Ni₉₀: D_Au = 3.3 × 10⁴, D_Re = (2.4?89) × 10⁴. Gorda Ridge basalt—Fe₁₀Ni₉₀: D_Au = (18?75) × 10⁴. Synthetic lunar basalt—Fe₇₀ Ni₃₀: D_Au≥ 2 × 10⁴, D_Re ≥ 2 × 10³. The experimental ΔG₁₈₀₀^° for the distribution of Au between nickel-iron and Mauna Loa basalt is ?40 kcal/mole, compared to a calculated value of about ?110 kcal/mole for a reaction involving simple Au³⁺ ions. Presumably the difference represents stabilization of Au(III) by complex formation with ligands such as Cl^?, H₂O, etc.Gold abundances in lunar basalts are roughly consistent with the measured D_Au, but those in terrestrial basalts are two orders of magnitude too high. This discrepancy may reflect complexing by volatiles in the Earth's upper lithosphere, as well as oxidative destruction of metal in the final stages of accretion. In the absence of a metal phase, siderophile trace elements would remain trapped in the upper mantle and crust.     

Carbon and sulfur in the Swaziland sequence

Sedimentary and igneous rocks of the Swaziland Sequence of South Africa (>3,200 my. old) contain total carbon (0.09–8.28%), organic carbon (0.04–1.95%) and sulfur (9–53,000 ppm). Amounts of organic carbon are generally high in the lower part of the Sequence (based on two samples from the Theespruit Formation). Sulfur content varies widely with no obvious correlations or trends. These rocks may contain clues to the early carbon and sulfur cycles on earth.     

A multiproxy climate record from a raised bog in County Fermanagh,Northern Ireland: a critical examination of the link between bog surface wetness and solar variability

A proxy climate record from a raised bog in County Fermanagh, Northern Ireland, is presented. The record spans the interval between 2850 cal. yr BC and cal. yr AD 1000 and chronological control is achieved through the use of tephrochronology and ¹⁴C dating, including a wiggle‐match on one section of the record. Palaeoclimatic inferences are based on a combination of a testate amoebae‐derived water table reconstruction, peat humification and plant macrofossil analyses. This multiproxy approach enables proxy‐specific effects to be identified. Major wet shifts are registered in the proxies at ca. 1510 cal. yr BC, 750 cal. yr BC and cal. yr AD 470. Smaller magnitude shifts to wetter conditions are also recorded at ca. 380 cal. yr BC, 150 cal. yr BC, cal. yr AD 180, and cal. yr AD 690. It is hypothesised that the wet shifts are not merely local events as they appear to be linked to wider climate deteriorations in northwest Europe. Harmonic analysis of the proxies illustrates statistically significant periodicities of 580, 423–373, 307 and 265 years that may be related to wider Holocene climate cycles. This paper illustrates how the timing of climate changes registered in peat profiles records can be precisely constrained using tephrochronology to examine possible climatic responses to solar forcing. Relying on interpolated chronologies with considerable dating uncertainty must be avoided if the climatic responses to forcing mechanisms are to be fully understood. Copyright © 2007 John Wiley & Sons, Ltd.