The effect of Na vapor on the Na content of chondrules

Abstract— Chondrules contain higher concentrations of volatiles (Na) than expected for melt droplets in the solar nebula. Recent studies have proposed that chondrules may have formed under non-canonical nebular conditions such as in particle/gas-rich clumps. Such chondrule formation areas may have contained significant Na vapor. To test the hypothesis of whether a Na-rich vapor would minimize Na volatilization reaction rates in a chondrule analog and maintain the Na value of the melt, experiments were designed where a Na-rich vapor could be maintained around the sample. A starting material with a melting point lower that typical chondrules was required to keep the logistics of working with Na volatilization from NaCl within the realm of feasiblity. The Knippa basalt, a MgO-rich alkali olivine basalt with a melting temperature of 1325°± 5 °C and a Na₂O content of 3.05 wt%, was used as the chondrule analog. Experiments were conducted in a 1 atm, gas-mixing furnace with the fO₂ controlled by a CO/CO₂ gas mixture and fixed at the I-W buffer curve. To determine the extent of Na loss from the sample, initial experiments were conducted at high temperatures (1300 °C–1350 °C) for duration of up to 72 h without a Na-rich vapor present. Almost all (up to 98%) Na was volatilized in runs of 72 h. Subsequent trials were conducted at 1330 °C for 16 h in the presence of a Na-rich vapor, supplied by a NaCl-filled crucible placed in the bottom of the furnace. Succeeding Knudsen cell weight-loss mass-spectrometry analysis of NaCl determined the P_Na for these experimental conditions to be in the 10^?6 atm range. This value is considered high for nebula conditions but is still plausible for non-canonical environments. In these trials the Na₂O content of the glass was maintained or in some cases increased; Na₂O values ranged from 2.62% wt to 4.37% wt. The Na content of chondrules may be controlled by the Na vapor pressure in the chondrule formation region. Most heating events capable of producing chondrules are sufficient to volatilize Na. Sodium volatilization reaction rates will be reduced to varying degrees from melt droplets, depending on the magnitude of the P_Na generated. A combination of Na vapor during, and Na diffusion back into chondrules after, formation could maintain and/or enrich Na concentrations in chondrules.     

Reconstructing riverine paleo-flow regimes using subfossil insects (Coleoptera and Trichoptera): the application of the LIFE methodology to paleochannel sediments

Sub-fossil insect remains have the potential to characterise changing environmental conditions in both lentic and lotic water systems, however, relatively few studies have been undertaken in riverine environments. This paper uses sub-fossil caddisfly larvae (Trichoptera) and aquatic beetles (Coleoptera) to reconstruct river flow conditions for a large paleochannel (from multiple monoliths) using the Lotic invertebrate Index for Flow Evaluation (LIFE). Examination of the larval Trichoptera and Coleoptera remains indicated a marked change in the community and flow environment, as suggested by paleoLIFE scores within the profile of three of the monoliths examined. At the base of the channel the community was characterised by taxa indicative of high energy lotic habitats with predominantly mineral substrates (e.g. Trichoptera: Hydropsyche contubernalis and Brachycentrus subnubilis, Coleoptera: Elmis aenea and Esolus parallelepipedus). Within three of the monoliths there was a change in community composition to one indicative of a low energy backwater/lentic environment with abundant submerged and emergent vegetation (e.g. Trichoptera: Phryganea bipunctata and Limnephilus flavicornis, Coleoptera: Colymbetes fuscus and Hydrobius fuscipes). Detrended Correspondence Analysis (DCA) and loss of mass on ignition (LOI) indicated the presence of a strong environmental gradient within the data, associated with river flow. The utilisation of two aquatic insect orders provides clear evidence of temporal changes within the instream community and when combined with knowledge of ecological and habitat associations, allows differences between the two groups to be interpreted more clearly.     

Vector magnetic fields in sunspots

Observations of a round, unipolar sunspot in the Zeeman triplet Fe i 6302.5 with the High Altitude Observatory Stokes Polarimeter are used to derive the vector magnetic field in the spot. The behavior of the magnitude, inclination, and azimuth of the field vector B across the spot is discussed. A linear relation is found between the continuum intensity I _c and the field magnitude B. Time series obtained in the umbra show significant power in the magnitude of the field at a period of t 180 s but the other components of the field vector do not display this behavior.The National Center for Atmospheric Research is sponsored by the National Science Foundation.     

Askival: An altered feldspathic cumulate sample in Gale crater

Askival is a light-toned, coarsely crystalline float rock, which was identified near the base of Vera Rubin Ridge in Gale crater. We have studied Askival, principally with the ChemCam instrument but also using APXS compositional data and MAHLI images. Askival and an earlier identified sample, Bindi, represent two rare examples of feldspathic cumulate float rocks in Gale crater with >65% relict plagioclase. Bindi appears unaltered whereas Askival shows textural and compositional signatures of silicification, along with alkali remobilization and hydration. Askival likely experienced multiple stages of alteration, occurring first through acidic hydrolysis of metal cations, followed by deposition of silica and possible phyllosilicates at low T and neutral-alkaline pH. Through laser-induced breakdown spectroscopy compositional analyses and normative calculations, we suggest that an assemblage of Fe-Mg silicates including amphibole and pyroxene, Fe phases, and possibly Mg-rich phyllosilicate are present. Thermodynamic modeling of the more pristine Bindi composition predicts that amphibole and feldspar are stable within an upper crustal setting. This is consistent with the presence of amphibole in the parent igneous rocks of Askival and suggests that the paucity of amphiboles in other known Martian samples reflects the lack of representative samples of the Martian crust rather than their absence on Mars.     

The sediment and hydrographic characteristics of three horseshoe crab nursery beaches in hong kong

1　Introduction　Thelifecycleofhorseshoecrabsislengthywhencom paredtoothermarinearthropodssuchasbluecrabsandshrimpspecies (Sekiguchietal.,1988) .Thetwospecies,TachypleustridentatusandCarcinoscorpiusrotundicauda,knowntooccurinHongKongrequire ,respectively ,betweenthirteentofourteenandtentoelevenyearstomaturebeforedepartingtheirnurserybeachesfordeeperwaters (ChiuandMorton ,1999a ;Sekiguchietal.,1988) .Thelivingenvironmentofthenurserybeacheswheretheeggsarelaidandincu bated ,andfromwhichtheyoun…     

Nature and timing of large landslides in the Himalaya and Transhimalaya of northern India

Four large landslides, each with a debris volume >10⁶ m³, in the Himalaya and Transhimalaya of northern India were examined, mapped, and dated using ¹⁰Be terrestrial cosmogenic radionuclide surface exposure dating. The landslides date to 7.7±1.0 ka (Darcha), 7.9±0.8 ka (Patseo), 6.6±0.4 ka (Kelang Serai), and 8.5±0.5 ka (Chilam). Comparison of slip surface dips and physically reasonable angles of internal friction suggests that the landslides may have been triggered by increased pore water pressure, seismic shaking, or a combination of these two processes. However, the steepness of discontinuities in the Darcha rock-slope, suggests that it was more likely to have started as a consequence of gravitationally-induced buckling of planar slabs. Deglaciation of the region occurred more than 2000 years before the Darcha, Patseo, and Kelang Serai landslides; it is unlikely that glacial debuttressing was responsible for triggering the landslides. The four landslides, their causes, potential triggers and mechanisms, and their ages are compared to 12 previously dated large landslides in the region. Fourteen of the 16 dated landslides occurred during periods of intensified monsoons. Seismic shaking, however, cannot be ruled out as a mechanism for landslide initiation, because the Himalaya has experienced great earthquakes on centennial to millennial timescales. The average Holocene landscape lowering due to large landslides for the Lahul region, which contains the Darcha, Patseo, and Kelang Serai landslides, is ～0.12 mm/yr. Previously published large-landslide landscape-lowering rates for the Himalaya differ significantly. Furthermore, regional glacial and fluvial denudation rates for the Himalaya are more than an order of magnitude greater. This difference highlights the lack of large-landslide data, lack of chronology, problems associated with single catchment/large landslide-based calculations, and the need for regional landscape-lowering determinations over a standardized time period.