The effect of bulk rock composition on the stability of amphibole in the upper mantle: Implications for solidus positions and mantle metasomatism

Summary The stability of pargasitic amphibole in the upper mantle is a function of water content and bulk rock composition, and under water-undersaturated conditions, the stability of amphibole controls the solidus position. Experiments in the system Tinaquillo peridotite +0.2% H₂O, a refractory peridotite under water-undersaturated conditions, show that amphibole is stable to 1030°C and 26 kb. In contrast, pargasitic amphibole is stable to 1150°C and 30 kb in Hawaiian pyrolite, a more fertile peridotite composition. This indicates that under water-undersaturated conditions, the most fertile part of a crystallizing mantle diapir with an inhomogeneous composition will solidify first while a more refractory component will contain an alkali-rich melt which will have the ability to metasomatize adjacent regions. The relative stabilities of amphibole in refractory and fertile bulk compositions may result in increasing rather than diminishing chemical contrasts in high temperature lherzolite, i.e. a process of metamorphic differentiation. Ti, Fe, Al and Na metasomatism can therefore be considered a normal occurrence associated with the upward migration and solidification of an H₂O-bearing mantle diapir.

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Der Einfluß der Gesamtgesteins-Zusammensetzung auf die Stabilität von Amphibol im oberen Mantel: Bedeutung für Solidus-Positionen und Mantel-Metasomatose

Zusammenfassung Die Stabilität pargasitischer Amphibole im oberen Mantel ist eine Funktion von Wassergehalt und Gesamtgesteins-Zusammensetzung. Unter wasser-untersättigten Bedingungen, kontrolliert die Stabilität von Amphibol die Solidus-Position. Experimente in dem System Tinaquillo Peridotit +0,2% H₂O, einem refraktären Peridotit unter wasser-untersättigten Bedingungen, zeigen daß Amphibol bis 1030°C und 26 Kb stabil ist. Im Gegensatz dazu ist pargasitische Hornblende in einem Hawaii-Pyrolit, von mehr fertiler Peridotit-Zuammensetzung, bis 1150°C und 30 Kb stabil. Das zeigt, daß bei wasser-untersättigten Bedingungen der am meisten produktive Teil eines kristallisierenden Mantel-Diapirs mit inhomogener Zusammensetzung sich zuerst verfestigen wird, während eine mehr refraktäre Komponente eine alkali-reiche Schmelze enthalten wird, die wiederum die Fähigkeit hat, umliegende Bereiche metasomatisch zu beeinflussen. Die relativen Stabilitäten von Amphibol in refraktären und fertilen Gesamtzusammensetzungen können dazu führen, daß die chemischen Gegensätze in Hochtemperaturlherzoliten eher zunehmen als abnehmen, d. h. ein Prozeß metamorpher Differentiation. Ti, Fe, Al und Na Metasomatose können deshalb als ein verbreiteter Vorgang, der mit der Aufwärtsbewegung und Verfestigung eines H₂O-führenden Mantel-Diapirs assoziiert ist, betrachtet werden.

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With 4 Figures     

Modeling long-period noise in kinematic GPS applications

We develop and test an algorithm for modeling and removing elevation error in kinematic GPS trajectories in the context of a kinematic GPS survey of the salar de Uyuni, Bolivia. Noise in the kinematic trajectory ranges over 15 cm and is highly autocorrelated, resulting in significant contamination of the topographic signal. We solve for a noise model using crossover differences at trajectory intersections as constraints in a least-squares inversion. Validation of the model using multiple realizations of synthetic/simulated noise shows an average decrease in root-mean-square-error (RMSE) by a factor of four. Applying the model to data from the salar de Uyuni survey, we find that crossover differences drop by a factor of eight (from an RMSE of 5.6 to 0.7 cm), and previously obscured topographic features are revealed in a plan view of the corrected trajectory. We believe that this algorithm can be successfully adapted to other survey methods that employ kinematic GPS for positioning.     

Europrobe seismic reflection profiling across the eastern Middle Urals and West Siberian Basin

New deep seismic reflection data provide images of the crust and uppermost mantle underlying the eastern Middle Urals and adjacent West Siberian Basin. Distinct truncations of reflections delineate the late-orogenic strike-slip Sisert Fault extending vertically to ∼28 km depth, and two gently E-dipping reflection zones, traceable to 15–18 km depth, probably represent normal faults associated with the opening of the West Siberian Basin. A possible remnant Palaeozoic subduction zone in the lower crust under the West Siberian Basin is visible as a gently SW-dipping zone of pronounced reflectivity truncated by the Moho. Continuity of shallow to intermediate-depth reflections suggest that Palaeozoic accreted island-arc terranes and overlying molasse sequences exposed in the hinterland of the Urals form the basement for Triassic and younger deposits in the West Siberian Basin. A highly reflective lower crust overlies a transparent mantle at about 43 km depth along the entire 100 km long seismic reflection section, suggesting that the lower crust and Moho below the eastern Middle Urals and West Siberian Basin have the same origin.     

A power spectrum description of Galactic neutral hydrogen

Angular power spectra for neutral hydrogen towardsl = 140°,b = 0° on scales from ≈ 1° to 1/10° are presented. The spectra are generally well fitted by a power-law dependence on radius in theuv-plane, with an index between ≈ -2.2 and ≈ -3.0. The more distant hydrogen, which corresponds to larger physical scales, tends to have a more negative index than does the nearer material. There is no preferred angular scale apparent at any velocity. For the distant hydrogen there is no obvious difference between the slope of power spectra for emission aligned perpendicular compared with that parallel to the Galactic plane.     

Phytochemical changes in leaves of subtropical grasses and fynbos shrubs at elevated atmospheric CO2 concentrations

The effects of elevated atmospheric CO₂ concentrations on plant polyphenolic, tannin, nitrogen, phosphorus and total nonstructural carbohydrate concentrations were investigated in leaves of subtropical grass and fynbos shrub species. The hypothesis tested was that carbon-based secondary compounds would increase when carbon gain is in excess of growth requirements. This premise was tested in two ecosystems involving plants with different photosynthetic mechanisms and growth strategies. The first ecosystem comprised grasses from a C₄-dominated, subtropical grassland, where three plots were subjected to three different free air CO₂ enrichment treatments, i.e., elevated (600 to 800 μmol mol⁻¹), intermediate (400 μmol mol⁻¹) and ambient atmospheric CO₂. One of the seven grass species, Alloteropsis semialata, had a C₃ photosynthetic pathway while the other grasses were all C₄. The second ecosystem was simulated in a microcosm experiment where three fynbos species were grown in open-top chambers at ambient and 700 μmol mol⁻¹ atmospheric CO₂ in low nutrient acid sands typical of south western coastal and mountain fynbos ecosystems. Results showed that polyphenolics and tannins did not increase in the grass species under elevated CO₂ and only in Leucadendron laureolum among the fynbos species. Similarly, foliar nitrogen content of grasses was largely unaffected by elevated CO₂, and among the fynbos species, only L. laureolum and Leucadendron xanthoconus showed changes in foliar nitrogen content under elevated CO₂, but these were of different magnitude. The overall decrease in nitrogen and phosphorus and consequent increase in C:N and C:P ratio in both ecosystems, along with the increase in polyphenolics and tannins in L. laureolum in the fynbos ecosystem, may negatively affect forage quality and decomposition rates. It is concluded that fast growing grasses do not experience sink limitation and invest extra carbon into growth rather than polyphenolics and tannins and show small species-specific chemical changes at elevated atmospheric CO₂ concentrations. Responses of fynbos species are varied and were species-specific.