The migration of fluid-filled grain boundaries in recrystallizing synthetic bischofite: first results of in-situ high-pressure, high-temperature deformation experiments in transmitted light

The effect of fluids on recrystallization behaviour is well known; however, the detailed microscale distribution of fluid in grain boundaries and the influence of fluid on grain boundary migration are still unresolved. In this study, in‐situ deformation experiments in transmitted light microscopy were undertaken, as this allows continuous and direct observation of the whole range of processes involved in fluid‐assisted grain boundary migration. A new see‐through deformation apparatus was developed to enable the control of fluid pressure. Bischofite containing small amounts of aqueous fluid was deformed at temperatures between 50 and 90 °C, over a range of fluid pressure from 0.5 to 1 MPa, and strain rates of 5 × 10^?6 to 1 × 10^?4 s^?1. The rates of grain boundary migration were measured at different temperatures and strain rates. Detailed observations during and after the deformation illustrate the evolution of migrating fluid‐filled grain boundaries and show that the incorporation of fluids from inclusions as well as their pinch‐off is dependent on the grain boundary velocity, the thickness of the grain boundary and the size and shape of the inclusions. Direct evidence is presented for the contraction of the grain boundary fluids into isolated inclusions after equilibrium conditions are attained.     

Aqueous uptake of uranium onto pyrite surfaces; reactivity of fresh versus weathered material

In order to better understand the interaction between aqueous uranium and pyrite (FeS₂) the uptake of uranium onto the surfaces of both weathered and freshly generated pyrite surfaces was examined using batch sorption experiments. Analysis was performed using X-ray photoelectron spectroscopy (XPS). The results clearly indicate that freshly polished pyrite surfaces are efficient scavengers of uranium from solution, while weathered surfaces exhibit only limited uptake. Results also indicate partial reduction of uranium at the pyrite surfaces, with a heterogeneous distribution of U(IV) and U(VI) species.     

Nature of polymerization and properties of silicate melts and glasses at high pressure

The structures of sodium silicate and aluminosilicate glasses quenched from melts at high pressure (6-10 GPa) with varying degrees of polymerization (fractions of nonbridging oxygen) were explored using solid-state NMR [¹⁷O and ²⁷Al triple-quantum magic-angle spinning (3QMAS) NMR]. The bond connectivity in melts among four and highly coordinated network polyhedra, such as ^[4]Al, ^[5,6]Al, ^[4]Si, and ^[5,6]Si, at high pressure is shown to be significantly different from that at ambient pressure. In particular, in the silicate and aluminosilicate melts, the proportion of nonbridging oxygen (NBO) generally decreases with increasing pressure, leading to the formation of new oxygen clusters that include 5- and 6-coordinated Si and Al in addition to 4-coordinated Al and Si, such as ^[4]Si-O-^[5,6]Si, ^[4]Si-O-^[5,6]Al and Na-O-^[5,6]Si. While the fractions of ^[5,6]Al increase with pressure, the magnitude of this increase diminishes with increasing degrees of ambient-pressure polymerization under isobaric conditions. Incorporating the above structural information into models of melt properties reproduces the anomalous pressure-dependence of O²⁻ diffusivity and viscosity often observed in silicate melts.     

Mineralogy of morphogenetic types of ferromanganese deposits in the world ocean

The mineralogy and structural features of the main types of ferromanganese deposits—nodules, micronodules, Co-bearing crusts, crustlike nodules, and low-temperature hydrothermal manganese crusts and ferruginous ochers—are considered. The correlation between their mineral composition and structure is shown. The proposed classification of mineral types is based on characteristic assemblages of Fe and Mn minerals.     

Scandium,chromium, iron,cobalt and nickel in some basic and ultrabasic rocks from west Norway

Sixteen eclogites and ultrabasic rock samples from west Norway have been analyzed for Sc, Cr, Fe, Co and Ni by instrumental neutron-activation analysis.In gneiss-eclogites, Sc and Co give values from about 30 to 60 ppm and Cr and Ni from 180 to 700 ppm. An eclogite surrounded by a peridotite body shows nearly the same content of Sc and Co as do the gneiss-eclogites, but up to 20 times more Cr. Ni is only slightly more enriched in this particular eclogite than in the others.The ultrabasites have only a few ppm Sc, Co concentrates around 100 ppm while the Cr and Ni values are mainly found between 2 and 3,000 ppm.Fe shows an average value of nearly 10%.     

On the problem of subtropical anticyclone regeneration as a factor of its stabilization (Case study for the summer of 2010)

The detailed investigation of conditions of the durational stabilization of subtropical anticyclone in the unusual region of the temperate zone is carried out and the reasons for its multiple regeneration are revealed. Separated are five periods of the subtropical anticyclone regeneration associated with the entering of active and relatively anticyclones of middle and high latitudes developed at the rear of cyclonic series into its circulation. All invasions were divided into three types depending on the trajectories of the movement of active anticyclones: the polar invasion from the north and northwest, the ultrapolar invasion from the east and northeast, and the western invasion from the Atlantic Ocean and Baltic Sea. The instability index introduced by V.P. Dymnikov was used for the quantitative estimation of the blocking process lifetime. It is demonstrated that this index is informative enough and could be used for the lifetime forecast of concrete quasistationary regimes of atmospheric circulation.     

Estimation of Regional Evapotranspiration by Combining Aircraftand Ground-Based Measurements

Two methods are examined for combining measurements from instrumented aircraftand towers to estimate regional scale evapotranspiration. Aircraft data provided spatially averaged values of properties of the surface, the evaporative fraction and maximum stomatal conductance. These quantities are less sensitive to meteorological conditions than the turbulent fluxes of heat and water vapour themselves. The methods allowed aircraft data collected over several days to be averaged and thus to reduce the random error associated with the temporal under-sampling inherent in aircraft measurements. Evaporative fraction is estimated directly from the aircraft data, while maximum stomatal conductance is estimated by coupling the Penman–Monteith equation to a simple model relating surface conductance to the incoming shortwave radiation and specific humidity saturation deficit. The spatial averages of evaporative fraction and maximum stomatal conductance can then be used with routine tower data to estimate the regional scale evapotranspiration. Data from aircraft flights and six ground based sites during the OASIS field campaign in south–east New South Wales in 1995 have been used to check the methods. Both the evaporative fraction and the maximum stomatal conductance derived from the aircraft data give information on the spatial variability of the surface energy budget at scales from 10 to 100 km. Daily averaged latent heat fluxes estimated using these methods for the OASIS study region agree with the available observations in quasi-stationary conditions or in weakly non-stationary conditions when the data from several aircraft flights are averaged to reduce the impact of short term imbalances in the surface energy budget.     

The effect of sea-ice extent in the North Atlantic on the stability of the thermohaline circulation in global warming experiments

Different climate models simulate different behavior of the Atlantic meridional overturning circulation (MOC) under the same global warming scenario. We propose a plausible explanation for this and argue that a proper simulation of the present-day climate in the subpolar North Atlantic is important. This is illustrated using results from idealized global warming experiments, in which both the radiative forcing scenario and the model employed are the same, with the only major difference being the initial subpolar North Atlantic climate. The initial conditions are made progressively colder, with more extensive sea-ice cover in the northern North Atlantic.The key result is that starting from conditions which are too cold in the North Atlantic and with sea-ice that is too extensive leads to an MOC that is more stable to the radiative forcing. Furthermore, under considerably underestimated sea surface temperatures in subpolar regions, the MOC can even intensify. A reduction of freshwater flux associated with the reduction of sea-ice melt is shown to be important for such unusual behavior of the MOC. Other mechanisms are also considered, but not deemed as important in explaining published inter-model differences.     

Postsedimentation transformation of triassic terrigenous rocks in West Chukotka as an indicator of folding conditions

Postsedimentation alteration and structural assemblies of the Triassic sedimentary complexes of West Chukotka are discussed. Zoning of the alteration is based on examination of newly formed structural and mineral assemblages, the chemical composition, and the polytypes of clay minerals. Three zones of postsedimentation transformation of sandstones are distinguished: (1) the zone of chlorite, illite, and mixed-layer disordered chlorite-smectite; (2) the zone of illite and chlorite; and (3) the zone of phengite and ferroan chlorite. The grade of postsedimentation transformation and the composition of the newly formed micas are correlated with the cleavage type. The development of two-three types of cleavage leads to the highest degree of rock transformation. The assemblages of clay minerals and the crystal chemistry of the authigenic phengite show that the grade of postsedimentation transformation of the Triassic rocks attains the stage of greenschistfacies metamorphism in the zone of development of two cleavage types. Where the second cleavage is not documented or poorly developed, the rocks remain unmetamorphosed. Evidence is given that postsedimentation transformation of terrigenous rocks in the foldbelt is controlled largely by deformation.