The provenance of Australian uranium ore concentrates by elemental and isotopic analysis

Elemental and isotopic ratio analyses of U ore concentrate samples, from the 3 operating U mining facilities in Australia, were carried out to determine if significant variations exist between their products, thereby allowing the U ore concentrate’s origin to be identified. Elemental analyses were conducted using inductively coupled plasma mass spectrometry (ICP-MS) and X-ray fluorescence spectrometry (XRF). Lead isotope ratios were measured using ICP-MS and U isotope analyses were conducted using thermal ionisation mass spectrometry (TIMS). Minute quantities of sample, such as that obtained from a swipe, were also examined for elemental concentrations using secondary ion mass spectrometry (SIMS). The results of multivariate statistical analysis show clear patterns in the trace elemental composition of the processed U ores, indicating that it is possible to use this feature as a unique identifier of an Australian U ore concentrate’s source. Secondary ion mass spectrometry analyses also allow individual particles to be differentiated using this ‘fingerprinting’ technique. Isotope ratios determined using TIMS reveal that there is a significant difference in the n(²³⁴U)/n(²³⁸U) isotope ratio between the U ore concentrate from each mine.     

Environmental changes and carbon cycle perturbations at the Triassic–Jurassic boundary in northern Switzerland

The Triassic–Jurassic boundary is characterized by strong perturbations of the global carbon cycle, triggered by massive volcanic eruptions related to the onset of the Central Atlantic Magmatic Province. These perturbations are recorded by negative carbon isotope excursions (CIEs) which have been reported worldwide. In this study, Triassic–Jurassic boundary sections from the southern margin of the Central European Basin (CEB) located in northern Switzerland are analyzed for organic carbon and nitrogen isotopes in combination with particulate organic matter (POM) analyses. We reconstruct the evolution of the depositional environment from Late Triassic to Early Jurassic in northern Switzerland and show that observed negative shifts in δ¹³C of the total organic carbon (δ¹³C_TOC) in the sediment are only subordinately influenced by varying organic matter (OM) composition and primarily reflect global changes in the carbon cycle. Based on palynology and the stratigraphic positions of isotopic shifts, the δ¹³C_TOC record of the studied sections is correlated with the GSSP section at Kuhjoch (Tethyan realm) in Austria and with the St. Audrie’s Bay section (CEB realm) in southwest England. We also show that in contrast to POM analyses the applicability of organic carbon/total nitrogen (OC/TN) atomic ratios and stable isotopes of total nitrogen (δ¹⁵N_TN) for detecting changes in source of OM is limited in marginal depositional environments with frequent changes in lithology and OM contents.     

Solare Einflüsse auf das Verhalten des atmosphärischen Funkstörpegels bei Kurzwellen

Zusammenfassung Der zeitliche Gang der atmosph?tischen St?rungen ist zwei Einflüssen unterworfen: 1) Der zeitlichen und r?umlichen Verteilung der St?rquellen, 2) Den jeweiligen Ausbreitungsbedingungen des zu empfangenden Frequenzbandes. Die bei 5,5 MHz durchgeführten Messungen des atmosph?rischen St?rpegels zeigen den erwarteten Zusammenhang zwischen dem t?glichen Gang und dem Sonnenstand entsprechend den normalen Ausbreitungsbedingungen im 50 m Band. W?hrend M?gel-Dellinger Effekte nicht festgestellt werden konnten, ist die Nordlichtst?rung als Folge einer Korpuskularstrahlung der Sonne klar zu erkennen.

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Summary The temporal variation of atmospherics is subjected to two facts: 1) The temporal and local distribution of sources of atmospherics, 2) The present conditions of propagation with regard to the just received short-wave band. Measurements of atmospherics in 50 m-band proved the connection between atmospherics and solar-radiation corresponding to the normal conditions of short-wave propagation, showing a minimum at day and a maximum at night. Whilst the Dellinger-effect did not happen, atmospherics disappeard on account of aurora borealis and strong disturbance of the earth's magnetic field, in consequence of corpusculare-radiation of the sun. Monthly distribution of atmospherics in 50 m-band for 2 years measurements are given.

     

Effect of artificial maturation on carbazole distributions, as revealed by the hydrous pyrolysis of an organic-sulphur-rich source rock (Ghareb Formation, Jordan)

Hydrous pyrolysis experiments were performed on the Ghareb Formation (Upper Cretaceous, Jordan), a carbonate- and organic-rich (TOC 19.6%) source rock, using a temperature range of 200 to 360°C (72 h). The original sediment contains only low amounts of carbazoles, (maximum 2.2 μg/g bitumen for 1-methylcarbazole). With increasing thermal maturation, intense generation begins at temperatures only in excess of 300°C, reaching a maximum at 360°C. Likewise, during natural maturation, generation occurs at later stages of maturity (e.g. for Tithonian source rocks at >0.81% R_r and for Posidonia Shale at >0.88% R_r). Some isomeric changes during hydrous pyrolysis do not resemble those in nature whereas others do. The relative abundances of selected C₁- and C₂-alkylcarbazoles on ternary diagrams reveal differences, whereas the benzo[a]carbazole/benzo[a]carbazole+benzo[c]carbazole ratio is closely similar. The latter result supports the contention that maturation plays a key role in controlling carbazole distributions in source rocks. However, the results for alkylcarbazoles, especially the C₂-carbazoles, are not easy to interpret.     

On the wavelength dependency of solar limb darkening (λλ303 to 1099 nm)

The limb-darkening data published by Neckel and Labs (1994) (5th-order polynomials P ₅(), = cos ) are used to represent the limb darkening by the functions L _n(), proposed first by Kourganoff (1949a). When plotted against wavelength, the coefficients of these functions show a rather low scatter and appear to be linear functions of either ^–1 or ^#x2212;5.     

Improved data of solar spectral irradiance from 0.33 to 1.25μ

The conversion of our centre of disk intensities published in 1968/70 into mean disk intensities has been repeated, using more accurate data for the centre-to-limb variation of both continuous radiation and strong absorption lines.The random observational mean error of the new irradiance data very likely is not larger than 1.5% in the UV and not larger than 1% in the visible and infrared. Comparison with the fluxes of Sun-like stars observed by Hardorp (1980) confirms these errors and seems to exclude the possibility of a systematic, wavelength-dependent scale error which would correspond to a temperature difference larger than 50 K.The resulting integral value of the irradiance between 0.33 and 1.25 is 1.060, the corresponding value of the solar constant lies between 1.368 and 1.377 kWm^-2.Proceedings of the 14th ESLAB Symposium on Physics of Solar Variations, 16–19 September 1980, Scheveningen, The Netherlands.     

A borehole investigation of zircon radiation damage annealing

This contribution reports Raman radiation damage measurements of zircons from the Kontinentale Tiefbohrung, on the western border of the Bohemian Massif. The mean wavenumbers (ω₃) and widths (Γ₃) of the ν₃(SiO₄) Raman band are constant down to 3 km, decrease (ω₃) resp. increase (Γ₃) between 3 and 5 km, and are again constant between 5 and 7 km. Uniform high Γ₃ values associated with ω₃ values close to those of undamaged zircon between 5 and 7 km are interpreted as due to residual damage predating the exhumation of the Bohemian Massif. A superimposed post‐exhumation signal indicates full damage retention down to 3 km depth, partial annealing between 3 and 5 km, and zero retention at greater depth. An attempt to calculate radiation damage ages gives results of a meaningful order of magnitude but also exposes difficulties associated with dating basement samples with complex damage accumulation and annealing histories.     

Halogenation processes linked to red wood ant nests (<Emphasis Type="Italic">Formica</Emphasis> spp.) and tectonics

We investigated and evaluated the occurrence of fault zone tracer gases (CO₂, He, Rn), volatile organohalogens (CH₃Cl, CHCl₃, CHBr₃), alkanes and limonene in soil and nest gases of red wood ants (RWA) in comparison to ambient air, in a seismically active area. In this new approach, we compared RWA-free areas to RWA-areas by combining different investigation and analytical methods. In soil gas, the fault zone tracer gas Rn was surprisingly highly correlated to limonene, suggesting a combination of biotic production of limonene and abiotic degassing of Rn in a seismically active area; moderate correlations were found with trihalomethanes and other halocarbons. In RWA nests a variety of elevated concentrations of haloforms were found, while remaining below the atmospheric background values in RWA-free areas. The evidence of CHCl₃ in RWA nests is the first record. Its average concentrations in nests of F. rufa and F. polyctena were up to 3 fold higher than atmospheric background and up to 28–70 fold higher compared to e.g. volcanic emissions being considered as one of its main geogenic sources. Thus, RWA nests could possibly be an additional source for CHCl₃ liberation. Consequently, apart from RWA being bioindicators for seismically active degassing faults, they might also be used as bioindicators for CHCl₃ formation in forest soils. Although we cannot yet differentiate between a geogenic/abiotic and a biotic formation. RWA nests will have to be reconsidered for halocarbon formation in future quantifications of geochemical cycles at global scale, since they impact organic soil chemistry through biotic and/or abiotic pathways. Therefore, further larger-scale research in different tectonic settings but also in well-known CHCl₃ “hot spot” study areas such as the Klosterhede area (Denmark) should focus directly on gas sampling from confirmed active fault systems. Nests of other ant species should be addressed to compare seasonal, diurnal and nocturnal variations of degassing procedures in relation to earth tides, different geologic settings, and tectonic events such as earthquakes and on quantifying the fluxes to the atmosphere.     

Neue Mineralvorkommen aus den Ostalpen

Zusammenfassung Bei den hier beschriebenen Mineralfunden handelt es sich teils um Neubearbeitungen alter Stücke aus Museums- oder Privatsammlungen, teils um neue Aufsammlungen.Cölestin von Kreuth bei Bleiberg.Slavikit undFibroferrit bei Rennweg.Pyrargyrit von Ruden bei Völkermarkt. Ein auffallend schönerZinnoberkristall vom steir. Erzberg.- und-Schwefel aus dem Köflach-Voitsberger Braunkohlengebiet. NetteRealgarkristalle vom Mischlinggraben im Lavanttal.Lansfordit undNesquehonit aus dem Serpentingebiet von Kraubat.Valentinit- undArsenolitkristalle, Symplesit undFerrisymplesit vom Hüttenberger Erzberg (Österreichs mineralartenreichster Lagerstätte). Insgesamt eine kleine Auswahl mineralogischer Neuentdeckungen (1947/49) aus dem Ostalpenraum, die zeigen, daß die mineralogische Durchforschung auch hier noch lange nicht abgeschlossen ist. Weitere Mitteilungen sollen folgen.