Seabirds in the North Sea Demobilized and Killed by Polyisobutylene (C4H8)n (PIB)

This paper reports on a mass stranding of seabirds in the North Sea in December 1998. Hundreds of birds were washed ashore alive in Zeeland (SW Netherlands), covered in a whitish, sticky substance, and were transported to a rehabilitation centre. About 10 days later, more (dead) casualties washed ashore further to the north on Texel and along the mainland coast, again covered in a glue-like substance. Common guillemots Uria aalge, northern fulmars Fulmarus glacialis and common scoters Melanitta nigra were the most numerous birds affected in this incident. Both strandings were temporarily (10 days) and geographically separated (ca. 120 km apart), but were apparently caused by a single source of pollution. The meteorology at the time was consistent with the course of a single incident. At least 1100 seabirds were affected by this substance, soon identified as polyisobutylene (C₄H₈)_n. PIB is known as a non-toxic, non-aggressive substance. Volunteers cleaning the birds in the rehabilitation centre reported serious discomfort and dizziness and the soft parts of the PIB-affected birds found dead (bill, eye, throat, feet, webs) appeared to dissolve in a few days time. Both effects cannot be attributed to PIB, and are therefore unexplained. Although the dumping of PIB in the marine environment is not explicitly prohibited under MARPOL, the effects on wildlife observed are enough to plead for counter-measures.     

Interaction of atmospheric chemistry and climate and its impact on stratospheric ozone

The interactively coupled chemistry-climate model ECHAM4.L39(DLR)/CHEM is employed in sensitivity calculations to investigate feedback mechanisms of dynamic, chemical, and radiative processes. Two multi-year model simulations are carried out, which represent recent atmospheric conditions. It is shown that the model is able to reproduce observed features and trends with respect to dynamics and chemistry of the troposphere and lower stratosphere. In polar regions it is demonstrated that an increased persistence of the winter vortices is mainly due to enhanced greenhouse gas mixing ratios and to reduced ozone concentration in the lower stratosphere. An additional sensitivity simulation is investigated, concerning a possible future development of the chemical composition of the atmosphere and climate. The model results in the Southern Hemisphere indicate that the adopted further increase of greenhouse gas mixing ratios leads to an intensified radiative cooling in the lower stratosphere. Therefore, Antarctic ozone depletion slightly increases due to a larger PSC activity, although stratospheric chlorine is reduced. Interestingly, the behavior in the Northern Hemisphere is different. During winter, an enhanced activity of planetary waves yields a more disturbed stratospheric vortex. This "dynamical heating" compensates the additional radiative cooling due to enhanced greenhouse gas concentrations in the polar region. In connection with reduced stratospheric chlorine loading, the ozone layer clearly recovers.     

Local habitat drivers of macrobenthos in the northern,central and southern KwaZulu-Natal Bight,South Africa

The relatively wide KwaZulu-Natal Bight between St Lucia and Durban on the north-east shelf of South Africa is characterised by several circulation features driven by the Agulhas Current, wind and coastal inputs. A large multidisciplinary programme investigated the sources and relative influences of nutrients on the shelf. Within this, and to address a critical knowledge gap, this study describes macrobenthic (<1 mm) composition and frequency from 16 stations, assigned amongst four oceanographic focus areas. The areas were predetermined across the disciplines to represent upwelling, outwelling and a semi-persistent eddy, with nutrients and primary productivity being measured at each. Environmental variables such as sediment distribution, sediment TOC and bottom water physico-chemistry were determined at a significantly larger spatial scale. Our study postulated that oceanographic focus areas support significantly different macrobenthic assemblages, and that composition and relative distribution is due to measurable habitat attributes at each. Macrofauna were relatively abundant and particularly rich at >1 000 taxa. Annelida, Arthropoda, Mollusca, Echinodermata, Sipuncula and Cnidaria (>50 taxa each) were the dominant macrobenthic groups in the bight. Annelida were dominated by the polychaete families Spionidae, Terrebelidae and Cirratullidae, which were generally associated with outwelling and a mud depocentre off the Thukela River. Two unique and distinctive assemblages were found, one in the Thukela Mouth focus area and another on the midshelf between Thukela and Durban. The latter is influenced by poorly sorted, coarse sand and with probable influences from the Durban Eddy. There assemblages were abundant, rich and specific to this habitat. Correlation, PERMANOVA and CAP analyses showed assemblage fidelity to the focus areas. Medium sand, fine sand, mud and the variance of overall sediment type were the habitat drivers underlying macrofaunal abundance distributions.     

Extraterrestrial amino acids identified in metal‐rich CH and CB carbonaceous chondrites from Antarctica

Carbonaceous chondrites contain numerous indigenous organic compounds and could have been an important source of prebiotic compounds required for the origin of life on Earth or elsewhere. Extraterrestrial amino acids have been reported in five of the eight groups of carbonaceous chondrites and are most abundant in CI, CM, and CR chondrites but are also present in the more thermally altered CV and CO chondrites. We report the abundance, distribution, and enantiomeric and isotopic compositions of simple primary amino acids in six metal‐rich CH and CB carbonaceous chondrites that have not previously been investigated for amino acids: Allan Hills (ALH) 85085 (CH3), Pecora Escarpment (PCA) 91467 (CH3), Patuxent Range (PAT) 91546 (CH3), MacAlpine Hills (MAC) 02675 (CBb), Miller Range (MIL) 05082 (CB), and Miller Range (MIL) 07411 (CB). Amino acid abundances and carbon isotopic values were obtained by using both liquid chromatography time‐of‐flight mass spectrometry and fluorescence, and gas chromatography isotope ratio mass spectrometry. The δ¹³C/¹²C ratios of multiple amino acids fall outside of the terrestrial range and support their extraterrestrial origin. Extracts of CH chondrites were found to be particularly rich in amino acids (13–16 parts per million, ppm) while CB chondrite extracts had much lower abundances (0.2–2 ppm). The amino acid distributions of the CH and CB chondrites were distinct from the distributions observed in type 2 and 3 CM and CR chondrites and contained elevated levels of β‐, γ‐, and δ‐amino acids compared to the corresponding α‐amino acids, providing evidence that multiple amino acid formation mechanisms were important in CH and CB chondrites.     

The Markoye Shear Zone in NE Burkina Faso

Birimian supracrustal sequences in NE Burkina Faso are dominated by meta-volcaniclastic greywacke, intercalated meta-conglomerate, siltstone and shale. The sequences where subjected to two phases of deformation and contact metamorphosed to hornblende–hornfels facies during emplacement of pyroxenite–gabbro–norite (Yacouba Mafic complex), granodiorite–tonalite (Tin Taradat granodiorite–tonalite) and dolerite dykes.Structural studies indicated that the NE-trending, first-order crustal-scale Markoye Shear Zone (MSZ; Markoye Fault of [Jeambrun, M., Delfour, J., Gravost, M., 1970. Carte géologique de L’Oudalan. Bureau De Recherches Geologiques et Miniéres, Burkina Faso.]) has undergone at least two phases of reactivation concomitant to two phases of regional deformation. The first phase of deformation, D1, resulted in the formation of NNW-NW trending folds and thrusts during dextral-reverse displacement on the MSZ. The deformation is termed the Tangaean Event and predates the Eburnean Orogeny. D2 phase involved a period of SE–NW crustal shortening and sinistral-reverse displacement on the MSZ, and is correlated to the Eburnean Orogeny 2.1 Ga. Deformation in D2 is characterised by NE-trending regional folds (F2) and a pervasive NE-trending foliation (S2-C to S2). Within the MSZ, deformation is characterised by NNE-trending zones of mylonite that are bordered in the hangingwall and footwall by pseudotachylite veins. Buck quartz-carbonate veins and quartz cataclasite veins crosscut the mylonite zones and are, in turn, crosscut by quartz–chlorite–(muscovite) shears that formed during reactivation of the MSZ late in D2. Several generations of veins are recognised at the Essakane main deposit (EMZ): Arsenopyrite–pyrite–gold mineralization in quartz veins formed in D1 during metasomatic alteration of the host rocks; Vein-stockwork gold mineralization is interpreted to have formed late in D2.     

The zeolite deposits of Greece

Zeolites are present in altered pyroclastic rocks at many localities in Greece, and large deposits of potential economic interest are present in three areas: (1) the Evros region of the province of Thrace in the north-eastern part of the Greek mainland; (2) the islands of Kimolos and Poliegos in the western Aegean; and (3) the island of Samos in the eastern Aegean Sea. The deposits in Thrace are of Eocene-Oligocene age and are rich in heulandite and/or clinoptilolite. Those of Kimolos and Poliegos are mainly Quaternary and are rich in mordenite. Those of Samos are Miocene, and are rich in clinoptilolite and/or analcime. The deposits in Thrace are believed to have formed in an open hydrological system by the action of meteoric water, and those of the western Aegean islands in a similar way but under conditions of high heat flow, whereas the deposits in Samos were formed in a saline-alkaline lake.     

Analysis of magnetic data over part of the Younger Granite Province of Nigeria

The results of a magnetic study of part of the Younger Granite Province of Nigeria are presented here. Spectral analysis of the magnetic anomalies over the area has been carried out in an effort to estimate the depth to magnetic sources. Average magnetic source depth of 286 m has been obtained for the area and this is thought to be related to the depth to the top of the main anomalous structures in the area. Observed magnetic anomaly profiels taken across the area have been interpreted in terms of arbitrarily shaped bodies—whose existence was confirmed by 3-D Hilbert transformation-using nonlinear optimization techniques. The modelled bodies occur at depths of 200–760 m and have magnetizations of 0.29–0.47 A/m. The results from the analysis of the magnetic field are discussed in relation to the results from previous gravity studies over the area and the mode of emplacement of the Younger Granites.