Origin,distribution, and alteration of asphalts at Chapopote Knoll,Southern Gulf of Mexico

Following the discovery of asphalt volcanism in the Campeche Knolls a research cruise was carried out in 2006 to unravel the nature of the asphalt deposits at Chapopote. The novel results support the concept that the asphalt deposits at the seafloor in 3000 m of water depth originate from the seepage of heavy petroleum with a density slightly greater than water. The released petroleum forms characteristic flow structures at the seafloor with surfaces that are ‘ropy’ or ‘rough’ similar to magmatic lava flows. The surface structures indicate that the viscosity of the heavy petroleum rapidly increases after extrusion due to loss of volatiles. Consequently, the heavy petroleum forms the observed asphalt deposit and solidifies. Detailed survey with a remotely operated vehicle revealed that the asphalts are subject to sequential alterations: e.g. volume reduction leading to the formation of visible cracks in the asphalt surface, followed by fragmentation of the entire deposit. While relatively fresh asphalt samples were gooey and sticky, older, fragmented pieces were found to be brittle without residual stickiness. Furthermore, there is evidence for petroleum seepage from below the asphalt deposits, leading to local up-doming and, sometimes, to whip-shaped extrusions. Extensive mapping by TV-guided tools of Chapopote Asphalt Volcano indicates that the main asphalt deposits occur at the south-western rim that borders a central, crater-like depression. The most recent asphalt deposit at Chapopote is the main asphalt field covering an area of ∼2000 m². Asphalt volcanism is distinct from oil and gas seepage previously described in the Gulf of Mexico and elsewhere because it is characterized by episodic intrusions of semi-solid hydrocarbons that spread laterally over a substantial area and produce structures with significant vertical relief. As Chapopote occurs at the crest of a salt structure it is inferred that asphalt volcanism is a secondary result of salt tectonism.     

Environmental Governance Meets Reality: A Micro-Scale Perspective on Sustainability Certification Schemes for Oil Palm Smallholders in Jambi,Sumatra

Abstract

Multi-stakeholder sustainability certification schemes have become a favorite instrument for applying good governance, though studies indicate their inefficiency at the producer level. In this study, we used a mixed-method approach to first, map the institutional context of independent oil-palm smallholders in rural Sumatra while, second, reflecting upon the impact of the Smallholder Standard proposed by the Roundtable on Sustainable Palm Oil on smallholder management practices. We hold that non-recognition of micro-scale perspectives within governance processes may partially explain noncompliance with certification principles among smallholders. The Smallholder Standard appears unable to mitigate challenges important for smallholders, who in turn cannot properly comply with it, due to problems including weather instability and high management costs. We suggest that certification schemes need to work on some overlooked but essential preconditions of good governance, namely gaining micro-level visibility and acceptance.     

Neotectonic basin and landscape evolution in the Eastern Cordillera of NW Argentina,Humahuaca Basin (~24°S)

The intermontane Quebrada de Humahuaca Basin (Humahuaca Basin) in the Eastern Cordillera of the southern Central Andes of NW Argentina (23°–24°S) records the evolution of a formerly contiguous foreland‐basin setting to an intermontane depositional environment during the late stages of Cenozoic Andean mountain building. This basin has been and continues to be subject to shortening and surface uplift, which has resulted in the establishment of an orographic barrier for easterly sourced moisture‐bearing winds along its eastern margin, followed by leeward aridification. We present new U–Pb zircon ages and palaeocurrent reconstructions suggesting that from at least 6 Ma until 4.2 Ma, the Humahuaca Basin was an integral part of a largely contiguous depositional system that became progressively decoupled from the foreland as deformation migrated eastward. The Humahuaca Basin experienced multiple cycles of severed hydrological conditions and subsequent re‐captured drainage, fluvial connectivity with the foreland and sediment evacuation. Depositional and structural relationships among faults, regional unconformities and deformed landforms reveal a general pattern of intrabasin deformation that appears to be associated with different cycles of alluviation and basin excavation in which deformation is focused on basin‐internal structures during or subsequent to phases of large‐scale sediment removal.     

Differential exhumation in response to episodic thrusting along the eastern margin of the Tibetan Plateau

Thermochronological data from the Songpan-Ganze˛Fold Belt and Longmen Mountains Thrust-Nappe Belt, on the eastern margin of the Tibetan Plateau in central China, reveal several phases of differential cooling across major listric thrust faults since Early Cretaceous times. Differential cooling, indicated by distinct breaks in age data across discrete compressional structures, was superimposed upon a regional cooling pattern following the Late Triassic Indosinian Orogeny. ⁴⁰Ar/³⁹Ar data from muscovite from the central and southern Longmen Mountains Thrust-Nappe Belt suggest a phase of differential cooling across the Wenchuan-Maouwen Shear Zone during the Early Cretaceous. The zircon fission track data also indicate differential cooling across a zone of brittle re-activation on the eastern margin of the Wenchuan-Maouwen Shear Zone during the mid-Tertiary, between 38 and 10 Ma. Apatite fission track data from the central and southern Longmen Mountains Thrust-Nappe Belt reveal differential cooling across the Yingxiu-Beichuan and Erwangmiao faults during the Miocene. Forward modelling of apatite fission track data from the northern Longmen Mountains Thrust-Nappe Belt suggests relatively slow regional cooling through the Mesozoic and early Tertiary, followed by accelerated cooling during the Miocene, beginning at ca. 20 Ma, to present day.

Regional cooling is attributed to erosion during exhumation of the evolving Longmen Mountains Thrust-Nappe Belt (LMTNB) following the Indosinian Orogeny. Differential cooling across the Wenchuan-Maouwen Shear Zone and the Yingxiu-Beichuan and Erwangmiao faults is attributed to exhumation of the hanging walls of active listric thrust faults. Thermochronological data from the Longmen Mountains Thrust-Nappe Belt reveal a greater amount of differential exhumation across thrust faults from north to south. This observation is in accord with the prevalence of Proterozoic and Sinian basement in the hanging walls of thrust faults in the central and southern Longmen Mountains. The two most recent phases of reactivation occurred following the initial collision of India with Eurasia, suggesting that lateral extrusion of crustal material in response to this collision was focused along discrete structures in the LMTNB.     

Geo-/Object-Coding for Local-Change Assessment

Missing availability of reliable and specific landscape data may pose substantial restrictions to successful exploitation of remote sensing data and fast implementation of GIS (Geo-Information Systems). The possibilities to document conditions with high spacial resolution at a given time and to review changing aspects by different disciplines represent opportunities for complex environmental programs.The article covers: geodata acquisition and processing, research, execution, and ergonomical/cognitive aspects. Application in inpenetrable terrain for research, landuse, and engineering requirements proved the feasibility especially in areas with high demand for timely, accurate, and comprehensive surveys.Airborne close-range sensing was developed to survey localities and regions. It is no competition to global-change monitoring and large area are mapping programs possible with remote sensing. Substituting only the bulk of field-work, leaving time for in-depth review in the field or in the office, the system provides a possibility to restudy points of interest.Exploitation of advanced metric cameras, specialized airborne platforms, and spatial overlay, recognition, and discrimination techniques form the backbone of the TOPOGRAMM approach. Multi-sectoral, multi-temporal, multi-spectral survey and processing methods rely basically on enlarged image scales additional to conventional aero-photogrammetry and analytic plotting. Measurements and identification, not primarily interpretation, allow to establish high-fidelity and high resolution geo-frameworks. Focussing on micro- and mesoscales, no emphasis is given to highest geometric accuracy used for geodetic surveys. Drawing near to the object allows extraction of thematical and semantical information, dimensions, and phenomelogy of objects hitherto only singularily available.

---

     

Distribution patterns and stable carbon isotopic composition of alkanes and alkan-1-ols from plant waxes of African rain forest and savanna C3 species

Leaf wax components of terrestrial plants are an important source of biomass in the geological records of soils, lakes and marine sediments. Relevant to the emerging use of plant wax derived biomarkers as proxies for past vegetation composition this study provides key data for C₃ plants of tropical and subtropical Africa. We present analytical results for 45 savanna species and 24 rain forest plants sampled in their natural habitats. Contents and distribution patterns of long chain n-alkanes (n-C₂₅ to n-C₃₅) and n-alkan-1-ols (n-C₂₄ to n-C₃₄) as well as bulk and molecular carbon isotopic data are presented. The variations of the analysed parameters among different growth forms (herb, shrub, liana and tree) are small within the vegetation zones, whereas characteristic differences occur between the signatures of rain forest and savanna plants. Therefore, we provide averaged histogram representations for rain forest and savanna C₃ plants.The findings were compared to previously published data of typical C₄ grass waxes of tropical and subtropical Africa. Generally, trends to longer n-alkane chains and less negative carbon isotopic values are evident from rain forest over C₃ savanna to C₄ vegetation. For n-alkanols of rain forest plants the maximum of the averaged distribution pattern is between those of C₃ savanna plants and C₄ grasses. The averaged presentations for tropical and subtropical vegetation and their characteristics may constitute useful biomarker proxies for studies analysing the expansion and contraction of African vegetation zones.     

The application of caesium‐137 measurements to investigate floodplain deposition in a large semi‐arid catchment in Queensland,Australia: a low‐fallout environment

Floodplains comprise geomorphologically important sources and sinks for sediments and associated pollutants, yet the sedimentology of large dryland floodplains is not well understood. Processes occurring on such floodplains are often difficult to observe, and techniques used to investigate smaller perennial floodplains are often not practical in these environments. This study assesses the utility of ¹³⁷Cs inventory and depth‐profile techniques for determining relative amounts of floodplain sedimentation in the Fitzroy River, northeastern Australia; a 143 000 km² semi‐arid river system. Caesium‐137 inventories were calculated for floodplain and reference location bulk soil cores collected from four sites. Depth profiles of ¹³⁷Cs concentration from each floodplain site and a reference location were recorded. The areal density of ¹³⁷Cs at reference locations ranged from 13 to 978 Bq m^–2 (0–1367 Bq m^–2 at the 95% confidence interval), and the mean value ± 2 (standard error of the mean) was 436 ± 264 Bq m^–2, similar to published data from other Southern Hemisphere locations. Floodplain inventories ranged from 68 to 1142 Bq m^–2 (0–1692 Bq m^–2 at the 95% confidence interval), essentially falling within the range of reference inventory values, thus preventing calculation of erosion or deposition. Depth‐profiles of ¹³⁷Cs concentration indicate erosion at one site and over 66 cm of deposition at another since 1954. Analysis of ^239+240Pu concentrations in a depositional core substantiated the interpretation made from ¹³⁷Cs data, and depict a more tightly constrained peak in concentration. Average annual deposition rates range from 0 to 15 mm. The similarity between floodplain and reference bulk inventories does not necessarily indicate a lack of erosion or deposition, due to low ¹³⁷Cs fallout in the region and associated high measurement uncertainties, and a likely influence of gully and bank eroded sediments with no or limited adsorbed ¹³⁷Cs. In this low‐fallout environment, detailed depth‐profile data are necessary for investigating sedimentation using ¹³⁷Cs. Copyright © 2009 John Wiley & Sons, Ltd.     

Indoor Air Quality Monitoring Improving Air Quality Perception

Energy‐efficient ventilation strategies relating to good indoor air quality (IAQ) are a major task for building performance according to the requirements set by the energy performance of buildings directive (EPBD) in 2010. Applying demand‐controlled ventilation (DCV) in buildings, using sensors for IAQ control that enables variable airflow rates adapted to the actual indoor load conditions is one possibility to fulfill the requirements of adequate IAQ while reducing the energy consumption at the same time. CO₂ concentrations above outdoors are generally used as an indicator for occupancy generated indoor air pollution and corresponding ventilation rates. The objective of this study is focused on a micromachined metal oxide semiconductor gas sensor module developed for IAQ control, based on volatile organic compound (VOC) detection. The sensor output was correlated with measured CO₂ concentrations and quantified VOCs in 15 field scenarios. Energy demand and IAQ, applying the sensor module for DCV in an office, were compared to natural and time‐scheduled ventilation in the office. The study accentuates the need for DCV and proves the functionality of the sensor module for IAQ control at adequate comfort levels. Compared to time‐scheduled ventilation, 15% heating energy and 70% power consumption were saved with DCV.     

A review of calcareous nannofossil astrobiochronology encompassing the past 25 million years

This paper presents a review of (astrobiochronological) calibration of Recent to late Oligocene calcareous nannofossil datum events. Biohorizons included in the paper are those of the widely used “standard” nannofossil zonations of Martini, E. [1971. Standard Tertiary and Quaternary calcareous nannoplankton zonation. In: Farinacci, A. (Ed.), Proceedings of the Second International Conference on Planktonic Microfossils Roma. Rome, Ed. Tecnosci. vol. 2, pp. 739–785], and Okada, H., and Bukry, D. [1980. Supplementary Modification and Introduction of Code Numbers to the Low-Latitude Coccolith Biostratigraphy Zonation (Bukry, 1973, 1975). Marine Micropaleontology 51, 321–325], as well as supplementary biohorizons proposed in the literature. The biohorizons have been selected on the basis of the unambiguous taxonomy of the index taxa and their biostratigraphic usefulness. We emphasise the application of rigorous methodology in nannofossil studies which permits an evaluation of biohorizons in terms of reliability, and calibrates their potential correlatability. Astrochronological age estimates rely on the Geologic timescale developed by the ICS in 2004, with some new calibrations included. We provide an overview of the relative position of biohorizons versus the astronomically calibrated ages of magnetic reversals and reference isotope stratigraphies. Surprisingly, there are still few high-resolution quantitative biostratigraphic studies of astrochronologically tuned sections in spite of the central role of such studies in addressing fundamental problems such as the tempo and mode of plankton evolution.     

On the relationship between vegetation and climate in tropical and northern Africa

Vegetation cover is a crucial component of the Earth’s climate system but, still, our understanding of the mechanisms governing the reciprocal influence between atmosphere and vegetation is limited. In this study, we investigate the unilateral atmospheric impact on vegetation cover in tropical and northern Africa, differentiated into regions with different circulation regimes and into detailed land-cover classes. In contrast to former studies, climate predictors from a regional climate model are used as input for a multiple regression model. Climate models provide consistent data without gaps at high spatial resolution, a considerably larger set of available climate variables and the perspective to transfer the statistical relationships to future projections, e.g., in the context of anthropogenic climate change. Indeed, robust climate predictors which drive up to 70 % of observed interannual vegetation variability could be extracted from the climate model. Besides precipitation and temperature, global radiation, and relative humidity play an important role. The statistical transfer functions are plausible in terms of the affected regions and land-cover classes and draw a rather complex picture of the atmosphere–vegetation relation in Africa.