Spatio‐temporal patterns of major ions in urban stormwater under cold climate

Multiple natural and anthropogenic factors affect urban water chemistry. However, little is known about the abundance or temporal variation of major ions in urban runoff. This study explores the spatio‐temporal variation of major dissolved ions (Na, K, Ca, Mg, Cl, NO₃, and SO₄) and total dissolved solids (TDS) in cold climate urban stormwater. Three watersheds with varying degrees of urban land use intensity and imperviousness (from 36% to 66%) in Helsinki, Finland, were continuously monitored for 5 years using an automated sampling procedure to obtain stormwater discharge and ion concentrations and, thus, loadings. High‐resolution datasets, including long‐term continuous discharge, both measured and simulated (using Storm Water Management Model), and automatic water quality sampling enabled the accurate calculation of loads of ions and TDS. Water quality was related to explanatory watershed characteristics (e.g., watershed physiography and sampling time) using hierarchical clustering, nonmetric multidimensional scaling, and hierarchical partitioning methods. Urban land use contributed to increased ion concentrations and loads year‐round. This study highlights how stormwater ion concentrations are elevated across seasons, indicating chronic pollution phenomena. The greatest loads occurred during summer (except for Na and Cl), while the highest variation in loads was observed in autumn. Significant clusters among ions were found in the hierarchical cluster analysis, suggesting similar temporal patterns and sources for the ions in each cluster. The importance of land use was evident, though in the most urbanized watershed, concentrations were not linked to any of the investigated watershed characteristics. Based on our results, only Na and Cl are manageable by alternative winter road antiskid practices, whereas other ions resulted from diffuse pollution sources, being therefore more difficult to control. Finally, this study contributes to an increased understanding of the temporal and spatial patterns of ions in stormwater and highlights the need for consistent time series data for ion monitoring under cold climatic conditions in order to enable reliable estimates of their loads to adjacent water bodies. Finally, year‐round stormwater treatment is highly recommended.     

Differential stemflow yield from European beech saplings: the role of individual canopy structure metrics

Stemflow production is affected by a suite of biotic and abiotic factors. It has proven difficult to determine the importance of individual canopy structure metrics on stemflow production. The disentanglement of the role and importance of individual canopy structure metrics would advance our understanding of the dynamics of stemflow production. This work employed ten isolated (i.e. no overlapping crowns) experimental European beech (Fagus sylvatica L.) saplings to examine the effects of various canopy structural metrics on stemflow production in east‐central Germany. The following canopy structural metrics were utilized in a hierarchical cluster analysis using Ward's method to separate the saplings into groups: primary branch count per unit projected crown area, secondary branch count per unit projected crown area, total branch count per unit projected crown area, mean branch inclination angle, minimum branch inclination angle, maximum branch inclination angle, total dry woody biomass per unit projected crown area, total foliar dry biomass per unit projected crown area and total dry biomass per unit projected crown area. Cluster group means revealed that saplings, which generate the largest stemflow yields, once controlled for sapling size, have straighter boles (but some trunk lean), more steeply inclined branches, a larger number of branches, more woody surface area and fewer numbers of leaves. Our results may prove valuable as a guide to researchers wishing to couple LiDAR and fine‐scale architectural models with the canopy metrics that govern stemflow to provide a better understanding of the canopy on the hydrology and biogeochemistry of forests. Copyright © 2013 John Wiley & Sons, Ltd.     

Separating the effects of changes in land management and climatic conditions on long‐term streamflow trends analyzed for a small catchment in the Loess Plateau region,NW China

As an integrated result of many driving factors, significant declines in streamflow were observed in many rivers of the Loess Plateau (NW China). This can aggravate the inherent severe water shortages and threatens the regional development. Therefore, it is urgent to develop adaptive measures to regulate the water yield to ensure water security. A key step for successful implementation of such measures is to separate the response of water yield to the main driving factors of land management and climate change. In this study, the variation of annual streamflow, precipitation, potential evapotranspiration, and climatic water balance in a small catchment in the Loess Plateau (near Pingliang, Gansu province) was examined for over five decades, although the relative contribution of changes in land management and climate on the streamflow reduction were estimated. A statistically significant decreasing trend of ‐1.14 mm y^‐1 in annual streamflow was detected. Furthermore, an abrupt streamflow reduction because of construction of terraces and check‐dams was identified around 1980. Remarkably, 74% of the total reduction in mean annual streamflow can be attributed to the soil conservation measures. Based on a literature review across the Loess Plateau, we found that the impact of changes in land management and climate on annual streamflow diminished with increasing catchment size. This means that there is a dependency on catchment size for the hydrological response to environmental change. This indicates that at least at the local scale well‐considered land management may help ensure the water security at the Loess Plateau. Copyright © 2012 John Wiley & Sons, Ltd.     

River ice cover influence on sediment transportation at present and under projected hydroclimatic conditions

A large number of rivers are frozen annually, and the river ice cover has an influence on the geomorphological processes. These processes in cohesive sediment rivers are not fully understood. Therefore, this paper demonstrates the impact of river ice cover on sediment transport, i.e. turbidity, suspended sediment loads and erosion potential, compared with a river with ice‐free flow conditions. The present sediment transportation conditions during the annual cycle are analysed, and the implications of climate change on wintertime geomorphological processes are estimated. A one‐dimensional hydrodynamic model has been applied to the Kokemäenjoki River in Southwest Finland. The shear stress forces directed to the river bed are simulated with present and projected hydroclimatic conditions. The results of shear stress simulations indicate that a thermally formed smooth ice cover diminishes river bed erosion, compared with an ice‐free river with similar discharges. Based on long‐term field data, the river ice cover reduces turbidity statistically significantly. Furthermore, suspended sediment concentrations measured in ice‐free and ice‐covered river water reveal a diminishing effect of ice cover on riverine sediment load. The hydrodynamic simulations suggest that the influence of rippled ice cover on shear stress is varying. Climate change is projected to increase the winter discharges by 27–77% on average by 2070–2099. Thus, the increasing winter discharges and possible diminishing ice cover periods both increase the erosion potential of the river bed. Hence, the wintertime sediment load of the river is expected to become larger in the future. Copyright © 2015 John Wiley & Sons, Ltd.     

Lithostratigraphy and Optically Stimulated Luminescence age determinations of pre‐Late Weichselian deposits in the Suupohja area,western Finland

The lithostratigraphy of pre‐Late Weichselian sediments and OSL‐dating results from four localities in the Suupohja area of western Finland, adjacent to the centre of the former Scandinavian glaciations, are presented. The studied sections expose glacifluvial, quiet‐water, littoral and aeolian deposits overlain by Middle and/or Late Weichselian tills. Litho‐ and biostratigraphical results together with seven OSL age determinations on buried glacifluvial sediment at Rävåsen (94±15 ka) and on till‐covered littoral and aeolian sediments at Risåsen, Rävåsen, Jätinmäki and Kiviharju (79±10 to 54±8 ka), accompanied by previous datings and interpretations, suggest that the glacifluvial sediments at Risåsen were deposited at the end of the Saalian Stage (MIS 6) and those at Risåsen were deposited possibly in the Early Weichselian Substage (MIS 5d?). Palaeosol horizons and ice‐wedge casts together with the dated littoral and aeolian sediments between the Harrinkangas Formation (Saalian) and the overlying till(s) indicate that western Finland was ice‐free during most of the Weichselian time. Littoral deposits, dated to the Middle Weichselian (MIS 4–3), occur at altitudes of 50–90 m a.s.l., which indicates significant glacio‐isostatic depression. The depression resulted from expansion of the ice sheet in the west of Finland at that time.     

Two‐dimensional and three‐dimensional computational models in hydrodynamic and morphodynamic reconstructions of a river bend: sensitivity and functionality

This study assesses hydrodynamic and morphodynamic model sensitivity and functionality in a curved channel. The sensitivity of a depth‐averaged model to user‐defined parameters (grain size, roughness, transverse bed slope effect, transport relations and secondary flow) is tested. According to the sensitivity analysis, grain size, transverse bed slope effect and sediment transport relations are critical to simulated meander bend morphodynamics. The parametrization of grain size has the most remarkable effect: field‐based grain size parametrization is necessary in a successful morphodynamic reconstruction of a meander bend. The roughness parametrization method affects the distribution of flow velocities and therefore also morphodynamics. The combined effect of various parameters needs further research. Two‐dimensional (2D) and three‐dimensional (3D) reconstructions of a natural meander bend during a flood event are assessed against field measurements of acoustic Doppler current profiler and multi‐temporal mobile laser scanning data. The depth‐averaged velocities are simulated satisfactorily (differences from acoustic Doppler current profiler velocities 5–14%) in both 2D and 3D simulations, but the advantage of the 3D hydrodynamic model is unquestionable because of its ability to model vertical and near‐bed flows. The measured and modelled near‐bed flow, however, differed notably from each other's, the reason of which was left open for future research. It was challenging to model flow direction beyond the apex. The 3D flow features, which also affected the distribution of the bed shear stress, seem not to have much effect on the predicted morphodynamics: the 2D and 3D morphodynamic reconstructions over the point bar resembled each other closely. Although common features between the modelled and measured morphological changes were also found, some specific changes that occurred were not evident in the simulation results. Our results show that short‐term, sub‐bend scale morphodynamic processes of a natural meander bend are challenging to model, which implies that they are affected by factors that have been neglected in the simulations. The modelling of short‐term morphodynamics in natural curved channel is a challenge that requires further study. Copyright © 2014 John Wiley & Sons, Ltd.     

High resolution re-analysis for the Baltic Sea region during 1965–2005 period

Regional reanalysis database BaltAn65+ comprising meteorological data for Baltic Sea region for the time period 1965–2005 is described. For data assimilation and hindcasts, the numerical weather prediction model HIRLAM 7.1.4 is applied, with 11 km horizontal and 60-layer vertical resolution. Reanalysis includes three-dimensional weather analysis data. Standard surface observations and meteorological soundings together with ship and buoy measurements from WMO observational network are used in analysis. Boundary fields are obtained from ECMWF ERA-40 global re-analysis. The BaltAn65+ can be considered as a regional refinement of ERA-40 for Baltic Sea region, providing the historical weather and climate data with enhanced spatial resolution, which is main motivation for creation of this novel reanalysis database.     

A Bayesian network for analyzing biological acute and long-term impacts of an oil spill in the Gulf of Finland

Knowledge of oil-induced impacts from the literature and experts were used to develop a Bayesian network to evaluate the biological consequences of an oil accident in the low-saline Gulf of Finland (GOF). Analysis was carried out for selected groups of organisms. Subnetworks were divided into subgroups according to a predicted response to oil exposure. Two scenario analyses are presented: the most probable and the worst-case accident.The impact of the most probable accident in the GOF is rather small. In most of the groups studied oil-induced long-term effects are evaluated to be minor at least from the perspective of the whole GOF. After the worst-case accident negative effects are more likely. The model predicts that the most vulnerable groups are auks and ducks. Amphipods, gulls and to a lesser extend littoral fishes and seals may show delayed recovery after an accident. Also annual plant species may be susceptible to oil-induced disturbances.     

Nb–Ta fractionation by partial melting at the titanite–rutile transition

During the evolution of the Earth, distinct geochemical reservoirs with different Nb/Ta ratios have developed. Archean granitoids of the tonalite–trondhjemite–granodiorite (TTG) suite, which represent the Earth’s early continental crust, show larger Nb/Ta variations than any other Earth reservoir. This implies that significant Nb–Ta fractionation must have occurred during early crust formation, while the underlying mechanism behind is still unclear. Here, we present a new model on how Nb may be fractionated from Ta during partial melting of subducted oceanic crust. Our data show that Nb/Ta ratios in melts derived from rutile- and titanite-bearing eclogite are largely controlled by the modal relative abundances of rutile and titanite in the source. High modal ratios of titanite over rutile generate melts with very high Nb/Ta (>60), whereas low modal titanite/rutile produces melts with much lower Nb/Ta (≤30). Very low Nb/Ta (<16) occur when all Ti-phases are consumed at very high degrees of melting. As the modal ratio of titanite to rutile is a function of pressure, the Nb/Ta of melts is a function of melting depth. Our new model helps to explain the extreme variation of Nb/Ta observed in many TTGs and thus how Nb and Ta were fractionated during the early evolution of the Earth. Furthermore, the model also indicates that simple one-stage melting models for mafic crust are not sufficient to explain the formation of TTGs.     

Review and revision of Cenozoic tropical planktonic foraminiferal biostratigraphy and calibration to the geomagnetic polarity and astronomical time scale

Planktonic foraminifera are widely utilized for the biostratigraphy of Cretaceous and Cenozoic marine sediments and are a fundamental component of Cenozoic chronostratigraphy. The recent enhancements in deep sea drilling recovery, multiple coring and high resolution sampling both offshore and onshore, has improved the planktonic foraminiferal calibrations to magnetostratigraphy and/or modified species ranges. This accumulated new information has allowed many of the planktonic foraminiferal bioevents of the Cenozoic to be revised and the planktonic foraminiferal calibrations to be reassessed. We incorporate these developments and amendments into the existing biostratigraphic zonal scheme.In this paper we present an amended low-latitude (tropical and subtropical) Cenozoic planktonic foraminiferal zonation. We compile 187 revised calibrations of planktonic foraminiferal bioevents from multiple sources for the Cenozoic and have incorporated these recalibrations into a revised Cenozoic planktonic foraminiferal biochronology. We review and synthesize these calibrations to both the geomagnetic polarity time scale (GPTS) of the Cenozoic and astronomical time scale (ATS) of the Neogene and late Paleogene. On the whole, these recalibrations are consistent with the previous work; however, in some cases, they have led to major adjustments to the duration of biochrons. Recalibrations of the early–middle Eocene first appearance datums of Globigerinatheka kugleri, Hantkenina singanoae, Guembelitrioides nuttalli and Turborotalia frontosa have resulted in large changes in the durations of Biochrons E7, E8 and E9. We have introduced (upper Oligocene) Zone O7 utilizing the biostratigraphic utility of ‘Paragloborotalia’ pseudokugleri. For the Neogene Period, major revisions are applied to the fohsellid lineage of the middle Miocene and we have modified the criteria for recognition of Zones M7, M8 and M9, with additional adjustments regarding the Globigerinatella lineage to Zones M2 and M3. The revised and recalibrated datums provide a major advance in biochronologic resolution and a template for future progress of the Cenozoic time scale.