Insights from trace element geochemistry as to the roles of subduction zone geometry and subduction input on the chemistry of arc magmas

Subduction zones of continental, transitional, and oceanic settings, relative to the nature of the overriding plate, are compared in terms of trace element compositions of mafic to intermediate arc rocks, in order to evaluate the relationship between subduction parameters and the presence of subduction fluids. The continental Chilean Southern Volcanic Zone (SVZ) and the transitional to oceanic Central American Volcanic Arc (CAVA) show increasing degrees of melting with increasing involvement of slab fluids, as is typical for hydrous flux melting beneath arc volcanoes. At the SVZ, the central segment with the thinnest continental crust/lithosphere erupted the highest-degree melts from the most depleted sources, similar to the oceanic-like Nicaraguan segment of the CAVA. The northern part of the SVZ, located on the thickest continental crust/lithosphere, exhibits features more similar to Costa Rica situated on the Caribbean Large Igneous Province, with lower degrees of melting from more enriched source materials. The composition of the slab fluids is characteristic for each arc system, with a particularly pronounced enrichment in Pb at the SVZ and in Ba at the CAVA. A direct compositional relationship between the arc rocks and the corresponding marine sediments that are subducted at the trenches clearly shows that the compositional signature of the lavas erupted in the different arcs carries an inherited signal from the subducted sediments.     

Evaluating Light Availability,Seagrass Biomass,and Productivity Using Hyperspectral Airborne Remote Sensing in Saint Joseph’s Bay,Florida

Seagrasses provide a number of critical ecosystem services, including habitat for numerous species, sediment stabilization, and shoreline protection. Ariel photography is a useful tool to estimate the areal extent of seagrasses, but recent innovations in radiometrically calibrated sensors and algorithm development have allowed identification of benthic types and retrieval of absolute density. This study demonstrates the quantitative ability of a high spatial resolution (1 m) airborne hyperspectral sensor (3.2 nm bandwidth) in the complex coastal waters of Saint Joseph’s Bay (SJB). Several benthic types were distinguished, including submerged and floating aquatic vegetation, benthic red algae, bare sand, and optically deep water. A total of 23.6 km² of benthic vegetation was detected, indicating no dramatic change in vegetation area over the past 30 years. SJB supported high seagrass density at depths shallower than 2 m with an average leaf area index of 2.0?±?0.6 m² m^?2. Annual seagrass production in the bay was 13,570 t C year^?1 and represented 41 % of total marine primary production. The effects of coarser spatial resolution were investigated and found to reduce biomass retrievals, underestimate productivity, and alter patch size statistics. Although data requirements for this approach are considerable, water column optical modeling may reduce the in situ requirements and facilitate the transition of this technique to routine monitoring efforts. The ability to quantify not just areal extent but also productivity of a seagrass meadow in optically complex coastal waters can provide information on the capacity of these environments to support marine food webs.     

Referees for volume 8

Acknowledgement

Referees for volume 8     

Weighted Pivot Coordinates for Compositional Data and Their Application to Geochemical Mapping

The log ratio methodology converts compositional data, such as concentrations of chemical elements in a rock, from their original Aitchison geometry to interpretable real orthonormal coordinates, thereby allowing meaningful statistical processing and visualization. However, it must be taken into account that the original concentrations can be flawed by detection limit or imprecision problems that can severely affect the resulting coordinates. This paper aims to construct such orthonormal log ratio coordinates, called weighted pivot coordinates, that capture the relevant relative information about an original component and treat the redundant information in a controlled manner. Theoretical developments are supported by a thorough simulation study. Weighted pivot coordinates are then applied to the geochemical mapping of catchment outlet sediments from the National Geochemical Survey of Australia illustrating their advantage over possible alternatives.     

Constraining input and output fluxes of the southern-central Chile subduction zone: water,chlorine and sulfur

In this paper, we constrain the input and output fluxes of H₂O, Cl and S into the southern-central Chilean subduction zone (31°S–46°S). We determine the input flux by calculating the amounts of water, chlorine and sulfur that are carried into the subduction zone in subducted sediments, igneous crust and hydrated lithospheric mantle. The applied models take into account that latitudinal variations in the subducting Nazca plate impact the crustal porosity and the degree of upper mantle serpentinization and thus water storage in the crust and mantle. In another step, we constrain the output fluxes of the subduction zone both to the subcontinental lithospheric mantle and to the atmosphere–geosphere–ocean by the combined use of gas flux determinations at the volcanic arc, volume calculations of volcanic rocks and the combination of mineralogical and geothermal models of the subduction zone. The calculations indicate that about 68 Tg/m/Ma of water enters the subduction zone, as averaged over its total length of 1,480 km. The volcanic output on the other hand accounts for 2 Tg/m/Ma or 3 % of that input. We presume that a large fraction of the volatiles that are captured within the subducting sediments (which accounts for roughly one-third of the input) are cycled back into the ocean through the forearc. This assumption is however questioned by the present lack of evidence for major venting systems of the submarine forearc. The largest part of the water that is carried into the subduction zone in the crust and hydrated mantle (accounting for two-thirds of the input) appears to be transported beyond the volcanic arc.     

Holocene landscape reconstruction in the surroundings of the Temple of Pepi I at ancient Bubastis,southeastern Nile Delta (Egypt)

In ancient Egypt, lakes, canals, and other water bodies were an essential part of the sacred landscape in which temples were embedded. In recent years, geoarchaeological research at the site of the Temple of Bastet at Bubastis in the southeastern Nile Delta has proven the existence of two water canals surrounding the temple. It has now been investigated whether these canals were connected to the Temple of Pepi I (2300–2250 B.C.E.), located approximately 100 m to the west of the Temple of Bastet. To explore the Holocene landscape genesis of the Temple of Pepi I, 15 drillings and six geoelectrical profile lines were performed in the surroundings of the temple in spring 2022. The results show loamy to clayey sediments in deeper sections of all drillings with a maximum thickness of 1.70 m, indicating a marshy or swampy depositional environment. Based on the recovered sediment sequences and archaeological remains in the vicinity of the Temple of Pepi I, the marshy or swampy area existed before the Fourth Dynasty. During the Old Kingdom (ca. 2850–2180 B.C.E.), the former marshland either dried up through natural processes or was intentionally drained and filled with sediments for subsequent use for occupation. Regarding the original research question, there is as yet no evidence for a direct connection to the canals of the Temple of Bastet.