Hydrogeochemical Analysis of Processes Through Modeling of Seawater Intrusion Impacts in Biscayne Aquifer Water Quality,USA

Hydrogeochemical processes that accompany seawater intrusion in coastal aquifers can alter the resulting water quality and are important ingredients in coastal aquifer management. The presence of dissolution–precipitation reactions and ion exchange in the mixing zone of the Biscayne aquifer (FL, USA) are suggested based on changes in major ion concentrations and mineral saturation indices (SI). Major ion concentrations from 11 groundwater samples are compared with theoretical mixing between freshwater and seawater. PHREEQC code was used to calculate saturation indices of the samples with respect to common phases in the Biscayne aquifer. High Ca²⁺ and HCO₃ ^? content of the samples is typical of waters in contact with carbonate aquifers. Water quality of the samples is mainly attributed to mixing and precipitation–dissolution reactions with calcite and dolomite. The samples were saturated with calcite (SI ~ 0) and undersaturated for dolomite (SI < 0), while a few samples showed dolomite saturation. Because gypsum and halite SI could be predicted by theoretical mixing, reactions with those minerals, if present, are thought to be insignificant. In the active intrusion areas, cation exchange also appears to modify water quality leading to excess Ca²⁺, but depleted Na⁺, Mg²⁺ and K⁺ concentrations. On the other hand, samples from previous intrusion areas plotted very close to the theoretical mixing line and approached equilibrium with the seawater.     

What do biphasic flow experiments reveal on the variability of exposure on alluvial fans and which implications for risk assessment result from this?

Sudden avulsions, unexpected channel migrations and backfilling phenomena are autogenic phenomena that can considerably change the propagation patterns of sediment-laden flows on alluvial fans. Once the initial and boundary conditions of the hazard scenario with a given return period are determined, the assessment of the associated exposed areas is based on one numerical, essentially deterministic, process simulation which may not adequately capture the underlying process variability. We generated sediment-laden flows on an experimental alluvial fan by following a “similarity-of-process concept”. Specifically, we considered a convexly shaped alluvial fan model layout featuring a curved guiding channel. As loading conditions, we defined a reference, an increased and a reduced level for the released water volume and the predisposed solid fraction, respectively. Further, we imposed two different stream power regimes and accomplished, for each factor combination, eight experimental runs. The associated exposure areas were recorded by video and mapped in a GIS. We then analysed exposure data and determined exposure probability maps superposing the footprints of the eight repetitions associated with each experimental loading condition. The patterns of exposure referred to the specific loading conditions showed a noticeable variability related to the main effects of the total event volume, the solid fraction, the interactions between them, and the imposed stream power in the feeding channel. Our research suggests that adopting a probabilistic notion of exposure in risk assessment and mitigation is advisable. Further, a major challenge consists in adapting numerical codes to better reflect the stochastics of process propagation for more reliable flood hazard assessments.

     

A hierarchical approach measures the aerial extent and concentration levels of PAH-contaminated shoreline sediments at historic industrial sites in Prince William Sound, Alaska

A field study was conducted in 2003 to estimate the areal distribution and concentrations of polycyclic aromatic hydrocarbons (PAH) in intertidal sediments at sites of past human and industrial activity (HA sites) in Prince William Sound (PWS), Alaska, the site of the 1989 Exxon Valdez oil spill. More than 50 HA sites, primarily in western PWS, were identified through analysis of historic records and prior field studies, and nine sites were selected for detailed surveys. The areal assessment process consisted of seven steps: (1) identify site from historic records and field surveys; (2) locate visual evidence of surface oil/tar at a site; (3) prepare a site map and lay out a sampling grid over the entire site with 10-m grid spacing; (4) excavate pits to 50 cm depth on the grid; (5) perform a field colorimetric test to estimate total PAH (TPAH) in sediments from the wall of each pit and record the results in the ranges <1 ppm; 1-10 ppm; >10 ppm TPAH; (6) expand grid size if necessary if elevated PAH levels are detected colorimetrically; (7) select 20 samples from each site for same-day shipboard PAH analysis by immunoassay (SDI RaPID PAH) and, based on these results, select sediment samples from each site for full PAH analysis in the laboratory to identify PAH sources. A total of 416 pits were dug at the nine sites. Nine acres of sediments with TPAH >2500 ppb dry wt. were mapped at the nine sites. TPAH concentrations obtained by immunochemical analysis of 181 samples from the nine sites ranged from 20 to 1,320,000 ppb (wet wt.). The contaminants are mixtures of petroleum products (2-3 ring PAH) and combustion products (4-6 ring PAH) unrelated to the 1989 Exxon Valdez oil spill. Mussels and clams collected at these sites have elevated levels of PAH that are compositionally similar to the PAH in the sediments. These findings indicate that at least a portion of the sediment PAH is bioavailable. The PAH sources at these historic industrial sites are chronic. They include relict fuel oil tanks and works located above and within the intertidal zone, with contamination at some locations extending into nearshore sub-tidal sediments. This study shows how a hierarchical approach can be used to quickly and successfully map, quantify, and subsequently, identify sources of PAH in shoreline sediments.     

Climate warming, water storage, and Chinook salmon in California’s Sacramento Valley

The Chinook salmon (Oncorhynchus tshawytscha) spawns and rears in the cold, freshwater rivers and tributaries of California’s Central Valley, with four separate seasonal runs including fall and late-fall runs, a winter run, and a spring run. Dams and reservoirs have blocked access to most of the Chinook’s ancestral spawning areas in the upper reaches and tributaries. Consequently, the fish rely on the mainstem of the Sacramento River for spawning habitat. Future climatic warming could lead to alterations of the river’s temperature regime, which could further reduce the already fragmented Chinook habitat. Specifically, increased water temperatures could result in spawning and rearing temperature exceedences, thereby jeopardizing productivity, particularly in drought years. Paradoxically, water management plays a key role in potential adaptation options by maintaining spawning and rearing habitat now and in the future, as reservoirs such as Shasta provide a cold water supply that will be increasingly needed to counter the effects of climate change. Results suggest that the available cold pool behind Shasta could be maintained throughout the summer assuming median projections of mid-21st century warming of 2°C, but the maintenance of the cold pool with warming on the order of 4°C could be very challenging. The winter and spring runs are shown to be most at risk because of the timing of their reproduction.     

Changing moisture sources over the last 330,000 years in Northern Oman from fluid-inclusion evidence in speleothems

Speleothems from Hoti Cave in northern Oman provide a record of continental pluvial periods over the last 330,000 yr. Periods of rapid speleothem deposition occurred from 6000 to 10,500, 78,000 to 82,000, 120,000 to 135,000, 180,000 to 200,000, and 300,000 to 330,000 yr ago, with little or no growth during the intervening periods. During each of these five pluvial periods, δD values of water extracted from speleothem fluid inclusions (δD_FI) are between −60 and −20‰ (VSMOW) and δ¹⁸O values of speleothem calcite (δ¹⁸O_C) are between −12 and −4‰ to (VPDB). These values are much more negative than modern rainfall (for δD) or modern stalagmites (for δ¹⁸O). Previous work on the isotopic composition of rainfall in Oman has shown that northern and southern moisture sources are isotopically distinct. Combined measurements of the δD values of fluid-inclusion water with calculated δ¹⁸O values from peak interglacial speleothems indicate that groundwater was predominantly recharged by the southern (Indian Ocean) moisture source, when the monsoon rainfall belt moved northward and reached Northern Oman during each of these periods.     

Africa and the global carbon cycle

The African continent has a large and growing role in the global carbon cycle, with potentially important climate change implications. However, the sparse observation network in and around the African continent means that Africa is one of the weakest links in our understanding of the global carbon cycle. Here, we combine data from regional and global inventories as well as forward and inverse model analyses to appraise what is known about Africa's continental-scale carbon dynamics. With low fossil emissions and productivity that largely compensates respiration, land conversion is Africa's primary net carbon release, much of it through burning of forests. Savanna fire emissions, though large, represent a short-term source that is offset by ensuing regrowth. While current data suggest a near zero decadal-scale carbon balance, interannual climate fluctuations (especially drought) induce sizeable variability in net ecosystem productivity and savanna fire emissions such that Africa is a major source of interannual variability in global atmospheric CO₂. Considering the continent's sizeable carbon stocks, their seemingly high vulnerability to anticipated climate and land use change, as well as growing populations and industrialization, Africa's carbon emissions and their interannual variability are likely to undergo substantial increases through the 21st century.     

Estimates of CO2 from fires in the United States: implications for carbon management

Background  

Fires emit significant amounts of CO₂ to the atmosphere. These emissions, however, are highly variable in both space and time. Additionally, CO₂ emissions estimates from fires are very uncertain. The combination of high spatial and temporal variability and substantial uncertainty associated with fire CO₂ emissions can be problematic to efforts to develop remote sensing, monitoring, and inverse modeling techniques to quantify carbon fluxes at the continental scale. Policy and carbon management decisions based on atmospheric sampling/modeling techniques must account for the impact of fire CO₂ emissions; a task that may prove very difficult for the foreseeable future. This paper addresses the variability of CO₂ emissions from fires across the US, how these emissions compare to anthropogenic emissions of CO₂ and Net Primary Productivity, and the potential implications for monitoring programs and policy development.     

Climate change and population history in the Pacific Lowlands of Southern Mesoamerica

Core MAN015 from Pacific coastal Guatemala contains sediments accumulated in a mangrove setting over the past 6500 yr. Chemical, pollen, and phytolith data, which indicate conditions of estuarine deposition and terrigenous inputs from adjacent dry land, document Holocene climate variability that parallels the Maya lowlands and other New World tropical locations. Human population history in this region may be driven partly by climate variation: sedentary human populations spread rapidly through the estuarine zone of the lower coast during a dry and variable 4th millennium B.P. Population growth and cultural florescence during a long, relatively moist period (2800–1200 B.P.) ended around 1200 B.P., a drying event that coincided with the Classic Maya collapse.     

Kilometer-wave type III burst: Harmonic emission revealed by direction and time of arrival

A type III solar burst was observed at seven frequencies between 3.5 MHz and 80 kHz by the Michigan experiment aboard the IMP-6 satellite. From the data we can determine burst direction-of-arrival as well as time-of-arrival. We predict these quantities using simple models whose parameters we vary to obtain a good fit to the observations. We find that between 3.5 MHz and 230 kHz the observed radiation was emitted at the fundamental of the local plasma frequency while below 230 kHz it was emitted at the second harmonic. The exciter particles that produced the burst onset and burst peak have velocities of 0.27 and 0.12, respectively, in units of the velocity of light.     

Meat consumption and climate change: the role of non-governmental organizations

The contribution of livestock production to climate change is now widely acknowledged. Despite this, efforts to reduce meat consumption in light of climate change have been relatively limited. One potential avenue for encouraging consumption changes is via non-governmental organizations (NGOs). This study used a qualitative approach to understand how and to what extent environmental, food-focused, and animal protection NGOs in the U.S., Canada, and Sweden have worked to reduce or alter domestic meat consumption in light of climate change. While almost all of the NGOs examined had mentioned the issue on their websites, few had established formal campaigns to reduce meat consumption. Active public outreach was dominated by animal protection and food-focused groups, particularly in the U.S. and Canada. Animal protection organizations advocated for larger reductions in meat consumption than environmental groups. Few NGOs sought to promote national-level polices to reduce meat consumption. There is a continued need for public education campaigns with clear messages, particularly by environmental NGOs, as well as efforts to build support for policy measures that seek to reduce meat consumption.