Initial Characterisation of SK01 Sanidine: A Candidate 40Ar/39Ar Reference Material

The precision and accuracy of ⁴⁰Ar/³⁹Ar dates are ultimately linked to co-irradiated reference materials of known age. Here we provide new data from the SK01 sanidine, which was analysed in three different laboratories to evaluate it as a ⁴⁰Ar/³⁹Ar reference material. Aliquots of 5 mg, incrementally heated in two laboratories, yielded indistinguishable results with a weighted mean age of 27.58 ± 0.06 Ma (95% confidence level). Single-crystal step heating and single-crystal total fusion analyses of SK01 sanidine were undertaken in the third laboratory to further test the intracrystalline homogeneity. For the seven step-heating analyses, six crystals yielded nearly concordant age spectra with ⁴⁰Ar/³⁹Ar ages ranging from 26.853 ± 0.094 Ma to 26.963 ± 0.067 Ma, whereas one crystal gave an older age of 27.774 ± 0.071 Ma with a slightly discordant age spectrum. Twenty-three single-crystal total fusion analyses yielded ⁴⁰Ar/³⁹Ar ages ranging from 27.070 ± 0.108 Ma to 27.736 ± 0.062 Ma with a dispersion of ~ 3.8%. The older ages from single-crystal total fusion dates are interpreted to reflect an inherited or excess argon component in some crystals. This is an initial characterisation of the SK01 sanidine, and additional work needs to be conducted to further evaluate the age dispersion so that it can be utilised as a ⁴⁰Ar/³⁹Ar reference material.     

Organochlorine pesticides in soil and air at and around a compound contaminated site: vertical distribution,soil–air exchange and risk evaluation

The control of soil pollution in China has become an issue, and in this study, a compound contaminated site was selected and focus on the site and its nearby environment, organochlorine pesticides (OCPs) were investigated in both soil (top and deep soil) and air samples. The main pollutants in top soils at site are dichlorodiphenyltrichloroethane (DDTs, 0.05–104 mg/kg d.w., avg: 14.5 mg/kg d.w.) and hexachlorobenzene (HCB, 0.02–4.85 mg/kg d.w., avg: 0.72 mg/kg d.w.) which is in accordance with its production history. As for the deep soils, ΣOCPs at site were found concentrated at workshops especially the technical pesticide workshop (5.29–22.1 mg/kg d.w., avg: 9.15 mg/kg d.w.) and the history DDTs’ workshop (4.00–64.8 mg/kg d.w., avg: 20.4 mg/kg d.w). Around site, OCPs were mainly concentrated at layers of −20 cm and the −40 cm and decreased with distance being far away, at 5000 m, the ΣOCPs was comparable with normal agriculture soil (22.1−91.4 ng/g d.w., avg: 55.4 ng/g d.w.). ΣOCPs in the air samples ranged 64.6–823 ng/m³ (avg: 459 ng/m³) at site and 9.93–176 ng/m³ (avg: 50.8 ng/m³) around site which are all dominated with DDTs and HCHs. Soil–air exchange fugacity was calculated to judge the transportation of the OCPs and the results showed soils at the site and its nearby areas (within 5000 m) are releasing most of the OCPs into air, and accordingly through evaluation, inhalation was found to be the major source for human health risk, which is a great threat to the workers at site and the nearby residents.

     

有毒铜绿微囊藻对鱼和溞的毒性

用有毒铜绿微囊藻细胞及其从毒细胞中提取的毒素喂养和腹腔注射鱼类，结果表明：（1）微囊藻毒素MCYST－LR对所有实验过的鱼有毒害作用（LD_(50)为110－500μg／kg）．注射毒素24h后，鱼肝电镜超微结构观察均表现出肝损伤．（2）在受控条件下，当用有毒铜绿微囊藻作为食物喂养日鲢和罗非鱼时，鱼类能在以毒藻为唯一食物的环境中生活20d以上．白鲢和罗非鱼粪便的毒性比喂食藻类的毒性分别降低约2—4．5倍，其肝的超微结构现察仍有轻度损伤．（3）在培养液中加入15μg／mLMCYST－LR和用实验室纯培养的铜绿微囊藻作为食物培养枝角类时，均可使它们在48h死亡．以无毒微囊藻培养时则生长不良亦不怀卵，表明它不是枝角类合适的食物．     

塔里木克拉通北缘阔克塔格西富碱侵入岩成因及其构造意义——锆石U-Pb年代学、岩石地球化学及Sr-Nd-Hf-O同位素制约

富碱侵入岩具有深源浅成的属性,是示踪地幔组成的窗口。位于东天山与塔里木克拉通北缘交界处的阔克塔格以西出露一处以正长岩为主体、包含少量中—基性岩石单元的富碱侵入岩。LA- ICP- MS锆石U- Pb测年显示其侵位于227~224 Ma之间,为印支期岩浆作用产物。该岩体具有富碱（Na2O+K2O=7. 93%~ 12. 28%）、富铝（Al2O3=15. 62%~18. 67%）、贫镁（MgO=0. 12%~4. 01%）、贫钛（TiO2=0. 14%~1. 63%）的特征,属于准铝质的（A/CNK=0. 78~1. 00）高钾钙碱性—钾玄岩系列。微量元素表现出高场强元素Nb、Ta、Th、U、Zr、Hf的富集,不相容元素Sr、P、Ti的亏损特征;轻重稀土分馏明显（（La/Yb）N=15. 09~34. 90）,表现为轻稀土强烈富集的右倾型曲线,Eu异常变化较大（δEu=0. 12~1. 72）。在同位素组成上,富碱侵入岩呈现相对宽泛但总体富集的全岩Sr- Nd和锆石Hf同位素特征,(87Sr/86Sr)i=0. 70489~0. 70581,εNd(t)=14. 56~6. 74,εHf(t)=11. 48~+3. 06,锆石δ18O值（5. 49‰~6. 87‰）略高于地幔值（5. 3‰±0. 6‰）。阔克塔格西富碱侵入岩具A1型花岗岩特征,形成于板内伸展构造环境中。基于主、微量元素及Sr- Nd- Hf- O同位素特征,笔者认为该杂岩体为同源岩浆演化产物,源于富集岩石圈地幔的原始岩浆上升并经历AFC（同化混染- 分离结晶）过程。晚三叠世塔里木克拉通北缘—东天山—北山地区处于板内构造体制,A1型花岗岩和正长岩差异化的时空分布特征很可能记录了古亚洲洋自西到东 “剪刀式”的闭合过程。     

2021年、2022年中国大陆地震灾害损失述评

基于2021年、2022年中国5.0级及以上地震目录,结合应急管理部、有关省(自治区、直辖市)地震局的地震灾害评估报告和相关资料,对中国大陆地震灾害情况、主要地震灾害事件及其特点进行了总结和分析。此外,按省份总结了各省地震灾害事件及地震灾害特点。其中,云南省中强震多、强震少,震区房屋抗震能力较高,人员伤亡较小; 四川省中强震少、强震多,次生灾害较为发育,造成严重人员伤亡; 青海省虽然震级高、破坏性强、致灾范围广,但震区地广人稀,房屋抗震设防等级较高,人员伤亡少。最后,结合历史震害统计数据,分析对比近2年中国大陆地震灾害致灾特点。     

三倍体合浦珠母贝不育性研究

对三倍体合浦珠母贝Ｐｉｎｃｔａｄａｍａｒｔｅｎｓｉｉ（Ｄ．）春、秋两繁殖盛期的生殖腺进行了组织学观察，并对其配子形成及受精、发育进行了研究。结果表明：合浦珠母贝三倍体的生殖腺发育差，生殖细胞数量少，极少个体能见到成熟卵母细胞和精子；三倍体的配子能完成受精作用，能发育至直线铰合期。配子多为非整倍体，其染色体数目多为１４—２８，胚胎染色体数目主要为２８—４２，故胚胎不能正常发育。因此，三倍体合浦珠母贝是不育的．     

河南范县及邻区地震精定位及震源机制解分析

选取河南范县及邻区2008年1月~2015年9月M_L≥2.0地震78个,用双差定位法进行重新定位。结果显示,重定位的震中主要沿聊城-兰考断裂带呈NE向分布,较此前更集中。重定位后的震源深度82%位于7~8km,也比此前更集中。在此基础上,用CAP方法研究了该地区2008年以来M_L≥3.0地震的震源机制解。结果显示,节面Ⅰ的14个地震中有11个地震震中分布呈NE向,这与用双差法重新定位后的震中分布方向一致。此外,这14个地震中有9个地震的P轴方位在50°~100°,均值为75°,这与华北地区主压应力方向基本一致。综合分析认为,该区域的地震活动与聊城-兰考断裂有关。     

A Lagrangian study of the near-surface intrusion of Pacific water into the South China Sea

Satellite-tracked Lagrangian drifters are used to investigate the transport pathways of near-surface water around the Luzon Strait. Particular attention is paid to the intrusion of Pacific water into the South China Sea(SCS).Results from drifter observations suggest that except for the Kuroshio water, other Pacific water that carried by zonal jets, Ekman currents or eddies, can also intrude into the SCS. Motivated by this origin problem of the intrusion water, numerous simulated trajectories are constructed by altimeter-based velocities. Quantitative estimates from simulated trajectories suggest that the contribution of other Pacific water to the total intrusion flux in the Luzon Strait is approximately 13% on average, much smaller than that of Kuroshio water. Even so, over multiple years and many individual intrusion events, the contribution from other Pacific water is quite considerable. The interannual signal in the intrusion flux of these Pacific water might be closely related to variations in a wintertime westward current and eddy activities east of the Luzon Strait. We also found that Ekman drift could significantly contribute to the intrusion of Pacific water and could affect the spreading of intrusion water in the SCS. A case study of an eddy-related intrusion is presented to show the detailed processes of the intrusion of Pacific water and the eddy-Kuroshio interaction.     

塔中地区奥陶系喜马拉雅山期S干气充注的证据

塔中地区奥陶系天然气成因多样;Ⅰ号坡折带中东部奥陶系天然气以高干燥系数、 甲烷同位素值重为特征;与塔深1井寒武系原油裂解气接近;应主要来自寒武系原油裂解气成因。寒武系贫H2S、 高成熟原油裂解气在喜马拉雅山期时;气侵奥陶系油气藏;得到了以下主要证据的支持: 1）天然气甲烷δ13C值大多比Chung et al.（1988）天然气模式甲烷δ13C值计算值高3‰以上;2）干燥系数与甲烷δ13C值大体上具有正相关关系;3）天然气干燥系数与H2S含量大体上具有负相关关系。这些特征表明;存在贫H2S、 相对富13C甲烷为主的干气与富H2S、 相对贫13C甲烷的湿气混合作用。奥陶系中H2S-δ34S 值为14‰～20‰;远低于中深1井寒武系原地热化学硫酸盐还原作用（TSR）成因的H2S（33‰）;支持了奥陶系中H2S并不是来源于寒武系古油气藏。于是提出;来自寒武系贫H2S的干气在喜马拉雅山期对良里塔格组和鹰山组油气藏发生了气洗;油气藏的气/油比值增大、 导致了原油蜡含量增高、 甲烷δ13C值发生正偏移。