The formation of porphyry copper deposits

Copper is a moderately incompatible chalcophile element. Its behavior is strongly controlled by sulfides. The speciation of sulfur is controlled by oxygen fugacity. Therefore, porphyry Cu deposits are usually oxidized (with oxygen fugacities > ΔFMQ +2) (Mungall 2002; Sun et al. 2015). The problem is that while most of the magmas at convergent margins are highly oxidized, porphyry Cu deposits are very rare, suggesting that high oxygen fugacity alone is not sufficient. Partial melting of mantle peridotite even at very high oxygen fugacities forms arc magmas with initial Cu contents too low to form porphyry Cu deposits directly (Lee et al. 2012; Wilkinson 2013). Here we show that partial melting of subducted young oceanic slabs at high oxygen fugacity (>ΔFMQ +2) may form magmas with initial Cu contents up to >500 ppm, favorable for porphyry mineralization. Pre-enrichment of Cu through sulfide saturation and accumulation is not necessarily beneficial to porphyry Cu mineralization. In contrast, re-melting of porphyritic hydrothermal sulfide associated with iron oxides may have major contributions to porphyry deposits. Thick overriding continental crust reduces the “leakage” of hydrothermal fluids, thereby promoting porphyry mineralization. Nevertheless, it is also more difficult for ore forming fluids to penetrate the thick continental crust to reach the depths of 2–4 km where porphyry deposits form.     

Maastrichtian Charophyte Flora from the Jiankou Section of the Jiaolai Basin

The latest Cretaceous strata of the Jiaolai Basin were studied in two scientific cores,including LK-1 drilled by the Institute of Geology,Chinese Academy of Geological Sciences(Li et al.,2018;Li et al.,2020),and JK-1 drilled by the Shandong Institute of the Geological Survey and Institute of Geology,Chinese Academy of Geological Sciences(Xu et al.,2017).However,outcrop sections were poorly studied,and the latest Cretaceous charophyte flora in particular had not previously been adequately documented from outcrops in the Jiaolai area.     

山东郭城牧牛山二长花岗岩的岩石成因:地球化学和锆石U—Pb年代学制约

山东胶莱盆地东北缘郭城牧牛山二长花岗岩的锆石LA--ICP--MS U--Pb年代学及岩石地球化学特征表明,牧牛山花岗岩为古元古代(2 138±15 Ma)岩浆侵入产物,是一套钾玄岩系列岩石,A/CNK为1.07~1.13。稀土配分曲线表现为右倾模式,轻稀土和重稀土分异明显,Eu/Eu*值为0.59~0.71。蛛网图表明明显富集大离子亲石元素(Rb、K),相对亏损高场强元素(Th、U、Nb、Ta、Ti、P)。岩石10 000 Ga/Al值(2.73~2.85),为A型花岗岩。岩石的Mg~#值为12~28,Nd/Th值为1.62~1.96,Rb/Sr值为4.70~9.71,显示壳源特征。综合分析认为,古元古代胶辽地块向西俯冲引发幔源岩浆底侵,导致地壳物质部分熔融形成牧牛山花岗岩。     

鄂尔多斯盆地及周缘地区下二叠统沉积特征*

通过大量的野外剖面观察和盆地内钻井岩心的详细描述,综合测井资料,从岩石类型、结构、沉积构造、古生物化石及测井曲线响应特征等方面对鄂尔多斯盆地及周缘地区下二叠统太原组和山西组沉积相特征进行了全面分析研究。结果表明,太原组主要发育陆棚、海岸、冲积扇和三角洲等沉积相,海岸沉积相包括障壁岛、潟湖和潮坪沉积,三角洲沉积相可划分为三角洲平原、三角洲前缘和前三角洲沉积。山西组主要发育冲积扇、河流、曲流河三角洲、湖泊和海岸沉积相,其中河流沉积相包括辫状河和曲流河沉积,曲流河三角洲沉积相可划分为曲流河三角洲平原、曲流河三角洲前缘和前三角洲沉积,而湖泊沉积相以浅湖沉积为主,海岸沉积主要为潟湖沉积。太原期,海相沉积占主导,主要分布于银川—榆林北部一线以南广大地区,并且从东西两侧至中部地区由浅海陆棚沉积和滨浅海过渡为潟湖沉积和潮坪沉积,其间发育障壁岛。盆地西北缘发育冲积扇和扇三角洲沉积,北部广大地区以三角洲沉积为主,自北向南依次为三角洲平原和三角洲前缘沉积。山西期,海水从盆地东南部退却,整体演变为海陆过渡相沉积,盆地北部乌达—杭锦旗—鄂尔多斯一线发育冲积扇沉积,向南至靖边一带依次发育辫状河和曲流河沉积,靖边以南至延安以北地区以三角洲平原沉积为主,向南至同心—庆阳一线发育三角洲前缘沉积,盆地南部彭阳—泾阳地区主要为浅湖沉积,再向南发育物源来自南部的三角洲沉积,在东南部武乡—义马一带为潟湖沉积。     

水热法从钾长石中提取钾、硅、铝的实验研究

通过水热化学反应将钾长石中的钾、硅和铝转变为可溶性组份,具有十分重要的应用价值.本文用单因素实验考察了不同水热反应实验条件对钾长石中钾、硅、铝溶出率的影响,并根据溶出率结果优化了反应条件.单因素实验结果表明:(1)在190℃条件下,随生石灰加入量的逐渐增加,产物中各元素的溶出率有一个先增加后减少的趋势.(2)在相同的生石灰、钾长石比例下,当反应16 h后,产物中各元素的溶出率随反应时间的延长趋于平缓.(3)随反应温度的逐渐增加,产物中各元素的溶出率逐渐增加.     

Zircon U–Pb ages and O–Nd isotopic composition of basement rocks in the North Qinling Terrain, central China: evidence for provenance and evolution

The Qinling Group was previously interpreted as the oldest Precambrian basement unit of the North Qinling Terrain, recording its formation and early crustal evolution. The Qinling Group consists predominantly of gneisses, amphibolites, and marbles, which underwent multi-phase deformation and metamorphism. In order to better constrain the provenance and tectonic setting of this group and the evolution of the North Qinling orogenic belt, in situ U–Pb dating and oxygen isotopic analysis of zircons in combination with whole-rock geochemistry and Sr–Nd isotope analysis was performed on the two dominant rock types, amphibolite and felsic gneiss. Felsic gneisses exhibit enrichment of LREEs and LILEs (Rb, Ba, Th, K, Pb), negative Eu anomalies and depletion of HFSEs (Nb, Ta, P, Ti). The rocks have slightly elevated δ¹⁸O values (6.5–9.3 ‰) and initial ε _Nd values of ?4.6 corresponding to two-stage Nd model age of 1.99 Ga. Amphibolites are also enriched in LILEs and LREEs and depleted in Nb and Ta and have homogeneous δ¹⁸O values (5.0–6.0 ‰), but higher initial ε _Nd values (2.8–3.3) and younger two-stage Nd model ages (1.29–1.24 Ga) compared to the gneisses. The zircon age record indicates that the gneisses and amphibolites were formed in a ~960 Ma volcanic arc environment rather than in a rift setting as previously suggested. A major metamorphic event took place during the Early Paleozoic. Based on the age spectrum of detrital zircons, the Qinling Group is interpreted as an autonomous geological unit, which was mainly derived mostly from 1,000 to 900 Ma old granitoid rocks. The North Qinling Terrain can be regarded as a remnant of the Grenville orogenic belt with an early Neoproterozoic evolution different from that of the North and South China blocks.     

四川银矿床的成因类型及找矿方向

四川已发现银矿床35个，主要与铅、锌、铜共生或者为其伴生组份。笔者将四川银矿床初步划分为5个类型和9个亚类型。成矿时代以晚白垩世和晚三叠世为主。四川银矿的找矿方向主要是三江地区的德格—乡城深大断裂带和扬子地台西缘的攀西裂谷带。     

载金石英的化学成分特征及其意义

利用电子显微镜(EM)及能谱仪(EDS),分析研究了变生热液形成的载金石英的化学成分、离子扩散作用以及金在石英中的赋存状态等问题,探讨了它们的形成和变化机理。研究结果表明:Al~(3+)、Ti~(3+)、TFe、Na~(+)、K~(+)、Ca~(2+)等在石英中为类质同像混入物;石英和黄铁矿之间的离子相互扩散作用,表现为石英中Al离子的带出和Fe离子的带入,黄铁矿中Fe离子的带出和Al离子的带入;石英中呈分散状态分布的金主要为离子金,它们充填在石英结构中,起平衡电价的作用。     

CFG短桩复合地基技术用于高层建筑地基处理的探讨

阐述了ＣＦＧ短桩复事地基技术的特点及应用范围,并列举了２个具体的工程实例,经过实践验证该技术是一项省钱、施工质量容易得到保证且能满足复合地基承载力及最终沉降量要求的新技术。探讨了ＣＦＧ短桩复合地基设计中的几个理论问题,产提出了该项技术的进一步研究方向。     

杨庄朱庄矿矿井水文地质条件综合分析

杨朱两矿受水害威胁严重,采用多种方法进行了水文地质条件勘查,利用其结果,综合分析了矿井水文地质条件,并进行了矿井充水性分区和安全开采的排水量预测,为正确制定矿井防治水措施提供了基础数据。