Pore water testing and analysis: the good,the bad,and the ugly

The increasingly common practice of collecting and assessing sediment pore water as a primary measure of sediment quality is reviewed. Good features of this practice include: pore water is a key exposure route for some organisms associated with sediments; pore water testing eliminates particle size effects; pore water analyses and tests can provide useful information regarding contamination and pollution. Bad features include: pore water is not the only exposure route; pore water tests lack chemical or biological realism: their "sensitivity" relative to other tests may be meaningless due to manipulation and laboratory artifacts; many sediment and surface dwelling organisms are not directly influenced by pore water. Bad features can become ugly if: other exposure pathways are not considered (for toxicity or bioaccumulation); manipulation techniques are not appropriate; pore water tests are inappropriately linked to population-level effects. Pore water testing and analyses can be effective tools provided their limitations are well understood by researchers and managers.     

Acute toxicity of mine tailings to four marine species

Acute toxicity bioassays were conducted on mine tailings produced by pilot plant testing for the proposed Quartz Hill molybdenum mine, which will be situated near Ketchikan, Alaska. Tailings bioassays were conducted in seawater with juvenile coho salmon (Oncorhynchus kisutch), mussel larvae (Mytilus edulis), infaunal amphipods (Rhepoxynius abronius), and euphausiids (Euphausia pacifica). The same general range of mine tailings concentrations was acutely toxic to all four test species with acute effects observed between 61 000 to 277 000 mg l^?1 (wet wt) tailings solids (range of 95% confidence limits for LC₅₀ and EC₅₀ values). Chemical analyses of bioassay test solutions and leaching test solutions were conducted for metals (including Cd, Cu, Pb, Zn, Mn and Mo), EPA Priority Pollutant base/neutral organics, and more general parameters such as sulphate, nitrate/nitrite, cyanides, phosphate and ammonia. Parameters possibly contributing to the observed toxicity were complex contaminant mixtures including total suspended solids and heavy metals. The present study provides information related to the marine disposal of mine tailings and shows that these mine tailings present a relatively low level of acutely toxic effects.     

Late-quaternary vegetational dynamics and community stability reconsidered

Defining the spatial and temporal limits of vegetational processes such as migration and invasion of established communities is a prerequisite to evaluating the degree of stability in plant communities through the late Quaternary. The interpretation of changes in boundaries of major vegetation types over the past 20,000 yr offers a complementary view to that provided by migration maps for particular plant taxa. North of approximately 43°N in eastern North America, continual vegetational disequilibrium has resulted from climatic change, soil development, and species migrations during postglacial times. Between 33° and 39°N, stable full-glacial vegetation was replaced by a relatively unstable vegetation during late-glacial climatic amelioration; stable interglacial vegetation developed there after about 9000 yr B.P. Late-Quaternary vegetation has been in dynamic equilibrium, with a relatively constant flora, south of 33°N on upland interfluves along the northern Gulf Coastal Plain, peninsular Florida, and west-central Mexico.     

Climate change, powerlessness and the commons dilemma: Assessing New Zealanders’ preparedness to act

Mitigating climate change is recognized as an increasingly urgent task that requires understanding a range of different strategies, including voluntary behavior change. Among the psychological barriers to behavior change are perceptions of powerlessness and the commons dilemma. This paper examines the association between these factors in a sample of New Zealand citizens and clarifies their importance in relation to other barriers to action to mitigate climate change, including uncertainty and perceived risk. Stronger perceptions of powerlessness and the commons dilemma were related to lower levels of action to mitigate climate change and lesser importance being placed upon climate change as an influence on individual actions. The perceived risk of climate change and the perception that humans influence climate change were the strongest predictors of mitigation action.     

Long wavelength thermal convection between non-conducting boundaries

Non-linear Rayleigh-Bénard convection in a fluid layer is considered as a model of convection in the Earth's upper mantle. Previous studies have shown that when the temperature is held fixed at one of the boundaries of the layer, convection takes place in cells of width of the order of the layer depth or less. We investigate the effects of a different thermal boundary condition, in which the flux of heat is held fixed on both layer boundaries; then if this flux is just greater than that required for the onset of convection, motion takes place on horizontal scales much greater than the layer depth. An analytical treatment of the equations, based on an expansion in the depth-to-width ratio of the cells, shows that cells of a definite horizontal scale are the fastest growing according to linearised theory, but that these cells are unstable to ones of larger wavelength than themselves. Thus the dominant wavelength lengthens with time. The results hold whether the heat flux is generated internally of comes from beneath the layer. These results produce flow patterns similar to those found when the heat flux is much greater than the critical value. The results have important consequences for the understanding of mantle convection.     

Observation and analysis of frequency-dependent anisotropy from a multicomponent VSP at Bluebell-Altamont field, Utah

In this paper, we present results from the analysis of a multicomponent VSP from a fractured gas reservoir in the Bluebell-Altamont Field, Utah. Our analysis is focused on frequency-dependent anisotropy. The four-component shear-wave data are first band-pass filtered into different frequency bands and then rotated to the natural coordinates so that the fast and slow shear-waves are effectively separated. We find that the polarisations of the fast shear-waves are almost constant over the whole depth interval, and show no apparent variation with frequency. In contrast, the time delays between the split shear-waves decrease as the frequency increases. A linear regression is then applied to fit the time-delay variations in the target and we find that the gradients of linear fits to time delays show a decrease as frequency increases. Finally, we apply a time-frequency analysis method based on the wavelet transform with a Morlet wavelet to the data. The variation of shear-wave time delays with frequency is highlighted in the time-delay and frequency spectra. We also discuss two mechanisms giving rise to dispersion and frequency-dependent anisotropy, which are likely to explain the observation. These are scattering of seismic waves by preferentially aligned inhomogeneneities, such as fractures or fine layers, and fluid flow in porous rocks with micro-cracks and macro-fractures.     

Lamb's problem and comments on the paper ‘on leaking modes’ byUsha Gupta

Summary In a recent paper,Gupta [5]²⁾ re-examined the significance of leaking modes in Lamb's problem (Lamb [7]). In this paper, we present a brief review of the exact Cagniard-de Hoop solution to this problem, and use these results to examine the question of the leaking mode in more detail. The leaking mode may either cause a separate arrival,P, or influence the shape of other arrivals e.g.SpS. We have attempted to clarify and extend previous results and correct misconceptions which have appeared elsewhere and, therefore, most of this discussion is tutorial in nature.     

Benthic fluxes of copper,complexing ligands and thiol compounds in shallow lagoon waters

Benthic fluxes of copper, copper complexing ligands and thiol compounds in the shallow waters of Venice Lagoon (Italy) were determined using benthic chambers and compared to porewater concentrations to confirm their origin. Benthic copper fluxes were small due to small concentration differences between the porewaters and the overlying water, and the equilibrium concentration was the same at both sites, suggesting that the sediments acted to buffer the copper concentration. Thiol fluxes were ～10 × greater at 50–60 pmol cm^?2 h^?1, at the two sites. Porewater measurements demonstrated that the sediments were an important source of the thiols to the overlying waters. The overlying waters were found to contain at least two ligands, a strong one, L1 (log K′_CuL1 = 14.2) and a weaker one, L2 (log K′_CuL2 = 12.5). The concentration of L1 remained relatively constant during the incubation and similar to that of copper, whereas that of L2 was in great excess of copper, its concentration balanced by porewater releases and breakdown, probably due to uptake by microorganisms, similar to that of the thiol compounds. Similarity of the thiol and L2 concentrations and similar complex stability with copper suggest that L2 was dominated by the thiols. The free copper concentration ([Cu´]) in the Lagoon waters was lowered by a factor of 10⁵ as a result of the organic complexation.     

Membrane Interface Probe Protocol for Contaminants in Low‐Permeability Zones

Accurate characterization of contaminant mass in zones of low hydraulic conductivity (low k) is essential for site management because this difficult‐to‐treat mass can be a long‐term secondary source. This study developed a protocol for the membrane interface probe (MIP) as a low‐cost, rapid data‐acquisition tool for qualitatively evaluating the location and relative distribution of mass in low‐k zones. MIP operating parameters were varied systematically at high and low concentration locations at a contaminated site to evaluate the impact of the parameters on data quality relative to a detailed adjacent profile of soil concentrations. Evaluation of the relative location of maximum concentrations and the shape of the MIP vs. soil profiles led to a standard operating procedure (SOP) for the MIP to delineate contamination in low‐k zones. This includes recommendations for: (1) preferred detector (ECD for low concentration zones, PID or ECD for higher concentration zones); (2) combining downlogged and uplogged data to reduce carryover; and (3) higher carrier gas flow rate in high concentration zones. Linear regression indicated scatter in all MIP‐to‐soil comparisons, including R² values using the SOP of 0.32 in the low concentration boring and 0.49 in the high concentration boring. In contrast, a control dataset with soil‐to‐soil correlations from borings 1‐m apart exhibited an R² of ≥0.88, highlighting the uncertainty in predicting soil concentrations using MIP data. This study demonstrates that the MIP provides lower‐precision contaminant distribution and heterogeneity data compared to more intensive high‐resolution characterization methods. This is consistent with its use as a complementary screening tool.