Metamorphism of the Permo-Triassic Cape Fold Belt and its basement, South Africa

Summary  The Permo-Triassic Cape Fold Belt around the southern tip of Africa consists of a thick sequence of Palaezoic siliciclastic sedimentary and pre-Cape basement rocks believed to be of Pan-African age. Both the basement rocks and the supracrustal rocks of the Cape Supergroup display only low metamorphic grades. Application of chlorite, chlorite-chloritoid Fe-Mg exchange, and calcite-graphite carbon isotope geothermometry to rocks from the unconformable contact between pre-Cape basement and the Cape Supergroup made it possible to distinguish pre-Cape and syn-Cape metamorphic overprints. During Pan-African metamorphism temperatures of up to middle greenschist facies conditions (around 400 °C) were reached, whereas lowermost greenschist facies conditions (around 300 °C) were not exceeded during the 220–290 Ma Cape orogeny. In the past, most if not all of the pre-Cape basement rocks, which form the Pan-African Saldania Belt, were considered to be of Neoproterozoic age. A hiatus of about 100 °C observed between two adjacent limestone horizons that previously had been grouped together into a single formation at the bottom of the allegedly Neoproterozoic Kango Group indicates that almost all of this group is syn- to post-orogenic with respect to the Pan-African orogeny. A revision of the stratigraphy of the Kango Group is therefore suggested. Only its lowermost member is truly Pan-African and probably related to about 620–740 Ma post-Sturtian cap carbonates in other Pan-African belts of southern Africa. The remainder of the Kango Group reflects the successive development of two stages of orogen-related intra-continental basins: The older stage led to a typical syn-orogenic foreland basin related to tectonic loading in the Gariep and Damara orogenic belts further north(west) between 570 and 540 Ma; the younger is believed to have formed either a further foreland basin or an intra-orogen pull-apart basin caused by later tectonic loading in the Ross orogenic belt and its continuation into the southern Saldania Belt between 510 and 480 Ma. Received May 7, 2000;/revised version accepted January 15, 2001     

Zielvorgaben für Pflanzenschutzmittelwirkstoffe und andere Schadstoffe in Oberflächengewässern

Quality Targets for Pesticides and Other Pollutants in Surface Waters Surface waters are not only adversely affected by industrial and municipal wastewaters but also by diffuse sources. For the control of the ecological water quality, so‐called quality targets are set. The quality targets are threshold concentrations for hazardous substances related to the protected goods like water ecosystems, drinking water supply, sediments, or fishing. In this paper, quality targets for the protection of aquatic life in surface waters were derived on the basis of a concept developed by the International Commission for the Protection of the Rhine (Internationale Kommission zum Schutze des Rheins – IKSR). The quality targets for the selected hazardous substances, which mainly belong to the chemical class of pesticides, were calculated using ecotoxicological results for species of bacteria, algae, fish, and small crustaceans, as the four trophic standards of the water ecosystem. In cooperation with the Federal Environmental Agency (Umweltbundesamt – UBA) the effect data were taken from ecotoxicological data bases. According to the concept of the IKSR, the lowest test result for the most sensitive species was multiplied by an assessment factor. This proceeding concerns the difficulty in describing the complex interactions in water ecosystems with toxicity data of single laboratory experiments for a few organisms. For seven pesticides quality targets below 0.1 μg/L were proposed. These results show that the ecotoxicologically based quality targets might be even lower than the limit values for pesticides in drinking water of 0.1 μg/L. But for most of the substances the determined values are significantly higher. The great concentration range of quality targets demonstrates distinctly that one standard concentration for all pesticides could not be given with regard to the different effects on aquatic organisms.     

Characterization of AOX by Fractionation Analysis and Size‐exclusion Chromatography

A characterization method for AOX in surface water samples was developed and tested. The method involves fractionation using a hydrophobic C18 resin and a weak anionic exchange resin and allows the fractionation of the AOX pool of surface water samples into four fractions: (1) hydrophilic acidic, (2) hydrophilic non‐acidic, (3) hydrophobic acidic, and (4) hydrophobic non‐acidic. The adsorption analysis was verified with AOX‐relevant model compounds and was applied to characterize the AOX pool of a stream sample from the Moskva river (Russia). In addition to the fractionation analysis, size‐exclusion chromatography was used to characterize the AOX pool of the sample studied. Hydrophilic acids made up the major fraction of the AOX pool (55 %). Among this fraction chlorinated high‐molecular acids (humic substances) made up the main fraction (35 %).     

Geometallurgical Approach for Implications of Ore Blending on Cyanide Leaching and Adsorption Behavior of Witwatersrand Gold Ores,South Africa

Gold production in South Africa is projected to continue its decline in future, and prospects for discovery of new high-grade deposits are limited. Many of the mining companies have resorted to mining and processing low-grade and complex gold ores. Such ores are technically challenging to process, which results in low recovery rates, excessive reagent consumption and high operating costs when compared to free-milling gold ores. In the Witwatersrand mines, options of blending low-grade gold ores with high-grade ores exist. Although it is well known that most of the Witwatersrand gold ores are highly amenable to gold cyanidation, not much is known on the leachability of blended ores, especially the effects of mineralogical and metallurgical variability between different gold ores. In this study, we apply a geometallurgical approach to investigate mineralogical and metallurgical factors that influence the leaching of blended ores in a set of bottle shaker and reactor column tests. Three gold-bearing conglomerate units, so-called reefs, i.e., Carbon Leader Reef, Ventersdorp Contact Reef and the Black Reef, all in the Carletonville goldfield, were sampled. The ores were prepared using a terminator jaw crusher followed by vertical spindle pulverizer (20 kg aliquot) and high-pressure grinding rolls (80 kg aliquot). Mineralogical analysis was conducted using a range of complementary tools such as optical microscopy, QEMSCAN and micro–XCT. The results show that Witwatersrand gold ores are amenable to the process of ore blending. Some of the ores, however, contain impervious inert gangue and reactive ore minerals. Leach solution can only access gold locked in impervious gangue minerals through HPGR-induced pores and/or cracks. The optimum ore blending ratio of the bottle shaker experiments (p80?=???75 μm) comprises 60% Carbon Leader Reef, 20% Ventersdorp Contact Reef and 20% Black Reef and yields 92% recovered Au over a leach period of 40 h. Blended ores with high carbonaceous material (>?1 wt% carbonaceous material, (Black Reef?=?36–60%) yield lower recoveries of 60–69% Au). Ore leaching at the mixed-bed reactor column (??75 μm and ??5.6/+?4 mm) yields about 70% over a leach period of two weeks. We therefore suggest that the feasibility of ore blending is strongly controlled by the mineralogy of the constituent ores and that a mixed-bed reactor may be a viable alternative method for leaching of the low-grade Witwatersrand gold ores. Material from certain reefs, such as the Black Reef, has synergistic/antagonistic (nonadditive) blending effects. The overall implication of this study is that ore blending ratios, effects of comminution on mineral liberation, an association of gold with other minerals, and gold adsorption behavior will greatly inform future technology choices in the area of geometallurgy.

     

Suspended sediments in the Kharaa River catchment (Mongolia) and its impact on hyporheic zone functions

A previous study investigating the ecological status of the Kharaa River in Northern Mongolia reported fine-grained sediments as being a major stress factor causing adverse impacts on the benthic ecology. However, the source of these sediments within the catchment as well as the specific impact on hyporheic zone functions in the Kharaa River remained unclear. Therefore, the objective of the current study was to investigate the underlying source–receptor system and implement an integrated monitoring approach. Suspended sediment sources within the Kharaa catchment were identified by using extensive spatially distributed sediment sampling and geochemical and isotope fingerprinting methods. On the receptor side, the ecological implications across a gradient of fine-grained sediment influx were analyzed using a distinct hyporheic zone monitoring scheme at three representative river reaches along the Kharaa River. Results of suspended sediment source monitoring show that during snowmelt runoff, riverbank and gully erosion were the dominant sources. During the summer period, upland erosion contributed a substantial share of suspended sediment. Fine-grained sediment influx proved to be the cause of habitat loss in the hyporheic zone and benthic oxygen production limitation. This combined catchment and in-stream monitoring approach will allow for a better understanding and spatially explicit analysis of the interactions of suspended sediment transport and hyporheic zone functioning. This information has built the basis for a coupled modeling framework that will help to develop efficient management measures within the Kharaa River basin with special emphasis on rapidly changing land-use and climatic conditions.     

Spatiotemporal analysis of photo contribution patterns to Panoramio and Flickr

ABSTRACT

Photo-sharing services provide a rich resource of crowdsourced spatial data consisting of georeferenced imagery and metadata. Shared photos can provide valuable information for a variety of applications and geospatial analysis tasks, such as identifying tourist hot spots or traveled routes. Understanding the spatiotemporal patterns of photo contributions will allow analysts to assess the suitability of these data for related analysis tasks. Using California as a study area, this paper analyzes various aspects of photo contribution patterns of Panoramio and Flickr. It identifies areas where annual photo contributions are still growing and areas that undergo a decline in annual contributions. Multiple regression is used to identify which environmental correlates are associated with an increase in photo-sharing activities. Furthermore, panel data of annual contributions between 2006 and 2013 for California subcounties will be used in a regression model to demonstrate that there is a positive feedback effect between Panoramio and Flickr photo contributions, but no neighborhood effect. The results of this paper provide insight into the data quality of crowdsourced image collections. These collections are commonly used for geospatial applications, including tourist information services and the computation of scenic routes.     

Trace element distribution in Neoproterozoic carbonates as palaeoenvironmental indicator

A first study of REE + Y distribution in a variety of Neoproterozoic (Cryogenian and Ediacaran) carbonates from different settings in the Saldania, Gariep, Damara and West Congo Belts in southwestern and central Africa revealed systematic differences that can be explained by varying palaeoenvironmental factors. The majority of samples display relatively unfractionated, flat shale-normalised REE + Y patterns that cannot be ascribed solely to shale contamination but are interpreted as resulting from the incorporation of near-shore colloids, possibly related to Fe-oxihydroxide scavenging. Only few carbonate units yielded trace element distributions that conform to a typical seawater composition. Those carbonates that were affected by stratiform, syn-sedimentary hydrothermal mineralisation are distinguished by Eu anomalies. Considering the similarity in residence time between REE and carbon, the strong influence of river-born particles on the REE + Y distribution in the analysed carbonates casts considerable doubt over the usefulness of these carbonates for stratigraphic correlation of Neoproterozoic sediment successions based on carbon isotopes.