Bounce Rock—A shergottite‐like basalt encountered at Meridiani Planum,Mars

Abstract– The Opportunity rover of the Mars Exploration Rover mission encountered an isolated rock fragment with textural, mineralogical, and chemical properties similar to basaltic shergottites. This finding was confirmed by all rover instruments, and a comprehensive study of these results is reported here. Spectra from the miniature thermal emission spectrometer and the Panoramic Camera reveal a pyroxene‐rich mineralogy, which is also evident in Mössbauer spectra and in normative mineralogy derived from bulk chemistry measured by the alpha particle X‐ray spectrometer. The correspondence of Bounce Rock’s chemical composition with the composition of certain basaltic shergottites, especially Elephant Moraine (EET) 79001 lithology B and Queen Alexandra Range (QUE) 94201, is very close, with only Cl, Fe, and Ti exhibiting deviations. Chemical analyses further demonstrate characteristics typical of Mars such as the Fe/Mn ratio and P concentrations. Possible shock features support the idea that Bounce Rock was ejected from an impact crater, most likely in the Meridiani Planum region. Bopolu crater, 19.3 km in diameter, located 75 km to the southwest could be the source crater. To date, no other rocks of this composition have been encountered by any of the rovers on Mars. The finding of Bounce Rock by the Opportunity rover provides further direct evidence for an origin of basaltic shergottite meteorites from Mars.     

Inversion for Range-Dependent Sediment Compressional-Wave-Speed Profiles From Modal Dispersion Data

A perturbative inversion method for estimating sediment compressional-wave-speed profiles from modal travel-time data is extended to include range-dependent environments. The procedure entails dividing a region into range-independent sections and obtaining estimates of the sediment properties for each region. Inversion results obtained using synthetic data show that range-dependent properties can be obtained if an experiment is designed to include multiple source/receiver combinations. This approach is applied to field data collected during the 2006 Shallow Water Experiment (SW06). The sediment compressional-wave-speed profiles resulting from analysis of the field data are evaluated by comparing acoustic fields predicted based on the inversion to acoustic fields measured during a different experiment conducted in the same region. The model is also compared to seismic reflection survey data collected during SW06. Resolution and variance estimated for the inversion results are also presented.      

Petrologic and textural diversity among the PCA 02 howardite group,one of the largest pieces of the Vestan surface

Abstract— Nine howardites and two diogenites were recovered from the Pecora Escarpment Icefield (PCA) in 2002. Cosmogenic radionuclide abundances indicate that the samples are paired and that they constituted an approximately 1 m (diameter) meteoroid prior to atmospheric entry. At about 1 m in diameter, the PCA 02 HED group represents one of the largest single pre‐atmospheric pieces of the Vestan surface yet described. Mineral and textural variations were measured in six of the PCA 02 howardites to investigate meter‐scale diversity of the Vestan surface. Mineral compositions span the range of known eucrite and diogenite compositions. Additional non‐diogenitic groups of Mg‐ and Fe‐rich olivine are observed, and are interpreted to have been formed by exogenic contamination and impact melting, respectively. These howardites contain olivine‐rich impact melts that likely formed from dunite‐ and harzburgite‐rich target rocks. Containing the first recognized olivine‐rich HED impact melts, these samples provide meteoritic evidence that olivine‐rich lithologies have been exposed on the surface of Vesta. Finally, we present a new method for mapping distributions of lithologies in howardites using 8 elemental X‐ray maps. Proportions of diogenite and eucrite vary considerably among the PCA 02 howardites, suggesting they originated from a heterogeneous portion of the Vestan surface. While whole sample modes are dominated by diogenite, the finer grain size fractions are consistently more eucritic. This discrepancy has implications for near‐infrared spectral observations of portions of Vesta’s surface that are similar to the PCA 02 howardites, as the finer grained eucritic material will disproportionately dominate the spectra.     

Deuterium on Venus: Model comparisons with pioneer Venus observations of the predawn bulge ionosphere

A model of the predawn bulge ionosphere composition and structure is constructed and compared with the ion mass spectrometer measurements from the Pioneer Venus Orbiter during orbits 117 and 120. Particular emphasis is given to the identification of the mass-2 ion which we find unequivocally due to D⁺ (and not H₂⁺). The atmospheric D/H ratio of 1.4% and 2.5% is obtained at the homopause (～ 130 km) for the two orbits. The H₂⁺ contribution to the mass-2 ion density is less than 10%, and the H₂ mixing ratio must be <0.1 ppm at 130 km altitude. The He⁺ data require a downward He⁺ flux of ～2 × 10⁷ cm^?2 sec^?1 in the predawn region which suggest that the light ions also flow across the terminator from day to night along with the observed O⁺ ion flow.     

Frictional sliding in serpentine at very high pressure

Using a new four-channel system for detecting acoustic emissions in a multianvil apparatus, we have assessed the pressure–temperature range for such emissions, as well as the role of dehydration, by deforming samples of extensively serpentinized peridotite. We show that in the absence of dehydration and for samples initially faulted at low pressure, acoustic emissions occurred well outside the expected pressure–temperature field of unassisted brittle failure. Emissions were also detected during and after dehydration of serpentine. Microstructures of post-run specimens revealed fault slip with offsets up to ~ 500 μm, regardless of whether or not dehydration took place. Dehydration appears to effectively stop slip on pre-existing faults and create new ones. Analysis of P-wave travel times from the four sensors confirmed that the acoustic emissions originated within the specimen during fault slip. These observations suggest that earthquakes can be triggered by slip along an existing fault containing serpentine under significantly higher pressure and temperature conditions than previously thought possible without dehydration.     

Chemical Mechanism Development: Laboratory Studies and Model Applications

Within the German Tropospheric Research Programme (TFS) numerous kinetic and mechanistic studies on the tropospheric reaction/degradation of the following reactants were carried out: oxygenated VOC, aromatic VOC, biogenic VOC, short-lived intermediates, such as alkoxy and alkylperoxy radicals.At the conception of the projects these selected groups were classes of VOC or intermediates for which the atmospheric oxidation mechanisms were either poorly characterised or totally unknown. The motivation for these studies was the attainment of significant improvements in our understanding of the atmospheric chemical oxidation processes of these compounds, particularly with respect to their involvement in photooxidant formation in the troposphere. In the present paper the types of experimental investigations performed and the results obtained within the various projects are briefly summarised. The major achievements are highlighted and discussed in terms of their contribution to improving our understanding of the chemical processes controlling photosmog formation in the troposphere.     

On the importance of initializing the stochastic part of the atmosphere for forecasting the 1997/1998 El Ni?o

The importance of initializing atmospheric intra-seasonal (stochastic) variations for prediction of the onset of the 1997/1998 El Ni?o is examined using the Australian Bureau of Meteorology coupled seasonal forecast model. A suite of 9-month forecasts was initialized on the 1st December 1996. Observed ocean initial conditions were used together with five different atmospheric initial conditions that sample a range of possible initial states of intra-seasonal (stochastic) variability, especially the Madden-Julian Oscillation (MJO), which is considered the primary stochastic variability of relevance to El Ni?o evolution. The atmospheric initial states were generated from a suite of atmosphere-only integrations forced by observed sea surface temperatures (SST). To the extent that low frequency variability of the tropical atmosphere is forced by slow variations in SST, these atmospheric states should all represent realistic low frequency atmospheric variability that was present in December 1996. However, to the extent that intra-seasonal variability is not constrained by SST, they should capture a range of intra-seasonal states, especially variations in the activity, phase and amplitude of the MJO. For each of these five states, a 20-member ensemble of coupled model forecasts was generated by the addition of small random perturbations to the SST field at the initial time. The ensemble mean from all five sets of forecasts resulted in El Ni?o but three of the sets produced substantially greater warming by months 4?C5 in the NINO3.4 region compared to the other two. The warmer group stemmed from stronger intra-seasonal westerly wind anomalies associated with the MJO that propagated eastward into the central Pacific during the first 1?C2?months of the forecast. These were largely absent in the colder group; the weakest of the colder group developed strong easterly wind anomalies, relative to the grand ensemble mean, that propagated into the central Pacific early in the forecast, thereby generating significantly weaker downwelling Kelvin waves in comparison to the warmer group. The strong reduction in downwelling Kelvin waves in the weakest case acted to limit the warming in the eastern Pacific, resulting in a ??Modoki?? type El Ni?o that is more focused in the central Pacific. Our results suggest that the intra-seasonal stochastic component of the atmospheric initial condition has an important and potentially predictable impact on the forecasts of the initial warming and flavour of the 1997/1998 El Ni?o. However, to the extent that atmospheric intra-seasonal variability is not predictable beyond a month or two, these results imply a limit to the accuracy with which the strength and perhaps the spatial distribution of an El Ni?o can ultimately be predicted. These results do not preclude a predictable role of the MJO and other intra-seasonal stochastic variability at longer lead times if some aspects of the stochastic variability are preconditioned by the evolving state of El Ni?o or other low frequency boundary forcing.     

Assessing the simulation and prediction of rainfall associated with the MJO in the POAMA seasonal forecast system

We assess the ability of the Predictive Ocean Atmosphere Model for Australia (POAMA) to simulate and predict weekly rainfall associated with the MJO using a 27-year hindcast dataset. After an initial 2-week atmospheric adjustment, the POAMA model is shown to simulate well, both in pattern and in intensity, the weekly-mean rainfall variation associated with the evolution of the MJO over the tropical Indo-Pacific. The simulation is most realistic in December?CFebruary (austral summer) and least realistic in March?CMay (austral autumn). Regionally, the most problematic area is the Maritime Continent, which is a common problem area in other models. Coupled with our previous demonstration of the ability of POAMA to predict the evolution of the large-scale structure of the MJO for up to about 3?weeks, this ability to simulate the regional rainfall evolution associated with the MJO translates to enhanced predictability of rainfall regionally throughout much of the tropical Indo-Pacific when the MJO is present in the initial conditions during October?CMarch. We also demonstrate enhanced prediction skill of rainfall at up to 3?weeks lead time over the north-east Pacific and north Atlantic, which are areas of pronounced teleconnections excited by the MJO-modulation of tropical Indo-Pacific rainfall. Failure to simulate and predict the modulation of rainfall in such places as the Maritime Continent and tropical Australia by the MJO indicates, however, there is still much room for improvement of the prediction of the MJO and its teleconnections.