Distribution and their pollution assessment of heavy metals in the sediments of the Yalu River Estuary and its adjacent coastal waters

The present paper deals with the distribution patterns of heavy metals and the associated influencing factors in the Yalu River Estuary and its adjacent coastal waters.Based upon the analysis of the surficial and core sediments measurements,the pollution of heavy metal and potential ecological risk were evaluated.The burial flux and contents of heavy metals(except for copper) have been continuously increasing since the 1920s.Therefore,the gross potential ecological risk for the sedi-ments was high or very high,and the study area was endangered by heavy metals contamination.Heavy metals originated mainly from upstream pollutant input,correlation analysis showed that chromium,nickel,zinc,cadmium,lead,arsenic,and mercury in the sediments of the middle and west channels as well as the sea area of the western Yalu River Estuary concentrations were most probably derived from similar sources.In contrast,the metal of copper most probably originated from sources different from the other metals.Preliminary studies indicate that copper contamination was most likely the result of emission from mining activities situated at the upstream of the river.The contents of heavy metals in the sediments of estuarine turbidity maximum zone of Yalu River were larger than those of any other areas in the middle channel.With large portion of fine sediments,weaker hydrodynamics,and richer sources of heavy metals,the sediments of the west channel,were even more enriched with heavy metals than those of the middle channel.     

墨西哥湾布什山冷泉碳酸盐岩沉积岩石学及地球化学

对墨西哥湾布什山采集的7块冷泉碳酸盐岩样品进行了沉积岩石学及地球化学研究,结果表明:冷泉碳酸盐岩以结壳的形式产出,结壳中双壳类和管状蠕虫等冷泉生物碎屑发育,结壳主要由泥晶、微晶和亮晶文石组成(含量89%～99%,平均94%)。碳酸盐岩13C中等亏损(δ13C最负值为-29.4‰,PDB),表明碳的来源主要是非甲烷的碳烃化合物,18O相对富集(δ18O为+2.4‰～+5.0‰,PDB),可能与原地水合物分解形成富集18O的孔隙水有关。碳酸盐矿物相(5%硝酸可溶部分)的稀土元素总量较低(0.40×10-6～20.85×10-6),稀土元素Ce异常特征和页岩标准化配分模式在不同样品、甚至同一样品结晶程度不同的碳酸盐矿物相(泥晶、微晶和亮晶)中变化显著,表明布什山冷泉碳酸盐岩形成过程中氧化还原条件复杂多变,控制氧化环境变化的主要因素可能是流体的渗漏速率。     

Climate Change,Geopolitics, and Human Settlements in the Hexi Corridor over the Last 5,000 Years

Social responses to climate change over human history have been widely discussed in academia over the last two decades. However, the transformation of the human–environment nexus crossing prehistoric and historic periods and the processes associated with it are not yet clearly understood. In this study, based on published works on radiocarbon dating, archaeobotany, zooarchaeology, and archaeological sites, together with a synthesis of historical documents and highresolution paleoclimatic records, we trace the extent to which human settlement patterns in the Hexi Corridor in northwestern China evolved in conjunction with climate change over the last 5,000 years. A total of 129 Neolithic, 126 Bronze Age, and 1,378 historical sites in the Hexi Corridor(n=1,633) were surveyed. Our results show that, in the Late Neolithic and Bronze Age periods(～2800–100 BC), climate change contributed to the transformation of subsistence strategies and the subsequent changes in human settlement patterns in the Hexi Corridor. The warm-humid climate in ～2800–2000 BC promoted millet agriculture and helped the Majiayao, Banshan, and Machang Cultures to flourish. The cold-dry climate in ～2000–100 BC resulted in the divergence and transformation of subsistence strategies in the Xichengyi–Qijia–Siba and Shajing–Shanma Cultures and in a shift in their settlement patterns. However, in the historical period(121 BC–AD 1911), human settlement patterns were primarily determined by geopolitics related to the alternating rule of regimes and frequent wars, especially in the Sui–Tang dynasties. We also find that trans-Eurasian cultural exchange since ～2000 BC improved social resilience to climate change in the Hexi Corridor, mediating the human–environment nexus there. Our findings may provide insights into how human societies reacted to climate change in arid and semi-arid environments over the long term.     

Causes and predictability of the record wet east Australian spring 2010

In 2010 eastern Australia received its highest springtime (September–November) rainfall since 1900. Based on historical relationships with sea surface temperatures (SST) and other climate indices, this record rainfall in 2010 was shown to be largely commensurate with the occurrence of a very strong La Niña event and an extreme positive excursion of the SAM. The pattern and magnitude of the tropical SST anomalies in austral spring 2010 were diagnosed to be nearly perfect to produce high rainfall across eastern Australia. Key aspects of this SST pattern were the strong cold anomaly in the central equatorial Pacific, and the strong warm anomalies in the eastern Indian Ocean and the far western Pacific to the north of Australia. Although the recent upward trend in SSTs in the western Pacific/eastern Indian Ocean warm pool accounted for about 50 % of the SST anomaly surrounding northern Australia in 2010, the contribution by the warming trend in these SSTs to the Australian rainfall anomaly in 2010 was assessed to be relatively modest. The strong positive swing in SAM was estimated to have accounted for upwards of 40 % of the regional anomaly along the central east coastal region and about 10 % of the area mean anomaly across eastern Australia. This contribution by the SAM suggests that a significant portion of the rainfall in 2010 may not have been seasonally predictable. However, predictability arising from the promotion of high SAM by the extreme La Nina event can not be ruled out.     

Interdecadal change in the Northern Hemisphere seasonal climate prediction skill: part II. predictability and prediction skill

The interdecadal change in seasonal predictability and numerical models’ seasonal forecast skill in the Northern Hemisphere are examined using both observations and the seasonal hindcast from six coupled atmosphere-ocean climate models from the 21 period of 1960–1980 (P1) to that of 1981–2001 (P2). It is shown that the one-month lead seasonal forecast skill of the six models’ multi-model ensemble is significantly increased from P1 to P2 for all four seasons. We identify four possible reasons accounting for the interdecadal change of the seasonal forecast skill. Firstly, the numerical model’s ability to simulate the mean state, the time variability and the spatial structures of the sea surface temperature and precipitation over the tropical Pacific is improved in P2 compared to P1. Secondly, an examination of the potential predictability of the atmosphere, estimated by the ratio of the total variance to the variance due to the internal dynamics of the model atmosphere, reveals that the atmospheric potential predictability is significantly increased after 1980s which is mainly due to an increased influence of El Niño-Southern Oscillation signal over the North Pacific and North American regions. Thirdly, the long-term climate trends in the atmosphere are found to contribute, to some extent, to the increased seasonal forecast skill especially over the Eurasian regions. Finally, the improved ocean observations in P2 may provide better initial conditions for the coupled models’ seasonal forecast.     

Abundances of Sulfur,Selenium, Tellurium,Rhenium and Platinum‐Group Elements in Eighteen Reference Materials by Isotope Dilution Sector‐Field ICP‐MS and Negative TIMS

Geological reference materials (RMs) with variable compositions and NIST SRM 612 were analysed by isotope dilution mass spectrometry for bulk rock concentrations of chalcogen elements (sulfur, selenium and tellurium), rhenium and platinum‐group elements (PGEs: Ru, Pd, Os, Ir and Pt), including the isotope amount ratios of ¹⁸⁷Os/¹⁸⁸Os. All concentrations were obtained from the same aliquot after HCl‐HNO₃ digestion in a high pressure asher at 320 °C. Concentrations were determined after chemical separation by negative TIMS, ICP‐MS and hydride generation ICP‐MS (Se, Te). As in previous studies, concentrations of the PGEs in most RMs were found to be highly variable, which may be ascribed to sample heterogeneity at the < 1 g level. In contrast, S, Se and Te displayed good precision (RSD < 5%) in most RMs, suggesting that part of the PGE budget is controlled by different phases, compared with the chalcogen budget. The method may minimise losses of volatile chalcogens during the closed‐system digestion and indicates the different extent of heterogeneity of chalcogens, Re and PGEs in the same sample aliquot. OKUM, SCo‐1, MRG‐1, DR‐N and MAG‐1 are useful RMs for the chalcogens. NIST SRM 612 displays homogenous distribution of S, Se, Te, Pt and Pd in 30 mg aliquots, in contrast with micro‐scale heterogeneity of Se, Pd and Pt.     

Sulfur cycling in a stratified euxinic lake with moderately high sulfate: Constraints from quadruple S isotopes

We present a 3-year study of concentrations and sulfur isotope values (δ³⁴S, Δ³³S, and Δ³⁶S) of sulfur compounds in the water column of Fayetteville Green Lake (NY, USA), a stratified (meromictic) euxinic lake with moderately high sulfate concentrations (12-16 mM). We utilize our results along with numerical models (including transport within the lake) to identify and quantify the major biological and abiotic processes contributing to sulfur cycling in the system. The isotope values of sulfide and zero-valent sulfur across the redox-interface (chemocline) change seasonally in response to changes in sulfide oxidation processes. In the fall, sulfide oxidation occurs primarily via abiotic reaction with oxygen, as reflected by an increase in sulfide δ³⁴S at the redox interface. Interestingly, S isotope values for zero-valent sulfur sampled at this time still reflect production and recycling by phototrophic S-oxidation. In the spring, sulfide S isotope values suggest an increased input from phototrophic oxidation, consistent with a more pronounced phototroph population at the chemocline. This trend is associated with smaller fractionations between sulfide and zero-valent sulfur, suggesting a metabolic rate control on fractionation similar to that for sulfate reduction. Comparison of our data with previous studies indicates that the S isotope values of sulfate and sulfide in the deep waters are remarkably stable over long periods of time, with consistently large fractionations of up to 58‰ in δ³⁴S. Models of the δ³⁴S and Δ³³S trends in the deep waters (considering mass transport via diffusion and advection along with biological processes) require that these fractionations are a consequence of sulfur compound disproportionation at and below the redox interface in addition to large fractionations during sulfate reduction. The large fractionations during sulfate reduction appear to be a consequence of the high sulfate concentrations and the distribution of organic matter in the water column. The occurrence of disproportionation in the lake is supported by profiles of intermediate sulfur compounds and by lake microbiology, but is not evident from the δ³⁴S trends alone. These results illustrate the utility of including minor S isotopes in sulfur isotope studies to unravel complex sulfur cycling in natural systems.     

Interdecadal change of interannual variability and predictability of two types of ENSO

A significant interdecadal climate shift of interannual variability and predictability of two types of the El Niño-Southern Oscillation (ENSO), namely the canonical or eastern Pacific (EP)-type and Modoki or central Pacific (CP) type, are investigated. Using the retrospective forecasts of six-state-of-the-art coupled models and their multi-model ensemble (MME) for December–January–February during the period of 1972–2005 along with corresponding observed and reanalyzed data, we examine the climate regime shift that occurred in the winter of 1988/1989 and how the shift affected interannual variability and predictability of two types of ENSO for the two periods of 1972–1988 (hereafter PRE) and 1989–2005 (hereafter POST). The result first shows substantial interdecadal changes of observed sea surface temperature (SST) in mean state and variability over the western and central Pacific attributable to the significant warming trend in the POST period. In the POST period, the SST variability increased (decreased) significantly over the western (eastern) Pacific. The MME realistically reproduces the observed interdecadal changes with 1- and 4-month forecast lead time. It is found that the CP-type ENSO was more prominent and predictable during the POST than the PRE period while there was no apparent difference in the variability and predictability of the EP-type ENSO between two periods. Note that the second empirical orthogonal function mode of the Pacific SST during the POST period represents the CP-type ENSO but that during the PRE period captures the ENSO transition phase. The MME better predicts the former than the latter. We also investigate distinctive regional impacts associated with the two types of ENSO during the two periods.     

Structural deformation of the Leoville chondrite

Foliations defined by alignment of elongated chondrules have been noted previously in chondrites, but none displays this effect so well as Leoville (CV3). The shapes of Leoville chondrules were produced by deformation in situ, as indicated by inclusions and clasts with similar shapes and preferred orientations to those of chondrules. Similarities in the aspect ratios of apparent strain ellipses measured for chondrules alone (1.9 and 2.0 by several methods) and for the whole meteorite (2.0) indicate either that Leoville deformed homogeneously or that it deformed as a framework of touching chondrules. This amount of strain corresponds to approximately 33% uniaxial shortening, assuming constant volume. Because the strain ellipse was measured in only one orientation, this strain value is a minimum estimate for the meteorite. Lack of correlation between foliation and either shock or thermal effects argues that impact or metamorphism are unlikely to have produced this deformation. Compaction due to overburden from progressive accretion on the chondrite parent body is suggested to have been its cause.Estimates of maximum deviatoric stresses in the interiors of asteroid-sized bodies and constraints on maximum temperatures for CV3 chondrites are consistent with diffusional flow as the deformation mechanism for olivine in these chondrules. Diffusional flow is also suggested by the scarcity of observed lattice dislocations. Deformation of Leoville olivines by this mechanism at geologically reasonable strain rates appears to require higher temperatures than those believed to have been experienced by this meteorite (< 600°C). However, differences in olivine grain size, the presence of water, or a more complex deformation history might explain this discrepancy.