Impacts of climate change on the risk of snow-induced forest damage in Finland

This work studied the temporal and spatial variability of the risk of snow-induced forest damage in Finland under current and changing climatic conditions until the end of this century. The study was based on a snow accumulation model in which cumulative precipitation, air temperature and wind speed were used as input variables. The risk was analyzed in terms of the number of days per year when the accumulated amount of snow exceeded 20 kg m^???2. Based on the risk, the forest area and mean carbon stock of seedling, young thinning and advanced thinning stands at risk were calculated. Furthermore, the number of 5-day periods, when the accumulated amount of snow exceeded a risk limit, was calculated for the current and changing climatic conditions in order to study the frequency of damaging snowfalls. Compared to the baseline period 1961–1990, the risk of snow-induced forest damage and the amount of damaging snowfalls were predicted to decrease from the first 30-year period (1991–2020) onwards. Over the whole country, the mean annual number of risk days decreased by 11%, 23% and 56% in the first, second and third 30-year period, respectively, compared to the baseline period. In the most hazardous areas in north-western and north-eastern Finland, the number of risk days decreased from the baseline period of over 30 days to about 8 days per year at the end of the century. Correspondingly, the shares of the forest area at risk were 1.9%, 2.0% and 1.0% in the first, second and third 30-year period, respectively. The highest mean annual carbon stocks of young stands at risk were found in central, north-eastern and north-western Finland in the first and second 30-year period, varying between 0.6 and 1.2 Mg C ha^???1 year^???1, meaning at highest 3% of the mean carbon stock (Mg C stem wood ha^???1) of those areas. This study showed that although the risk of snow-induced forest damage was mainly affected by changes in critical weather events, the development of growing stock under the changing climatic conditions also had an effect on the risk assessment. However, timely management of forest stands in the areas with a high risk of snow-induced damage contributes to the trees’ increased resistance to the damage.     

Acfer 217-A new member of the Rumuruti chondrite group (R)

Abstract— Previously, three meteorites from Australia and Antarctica were described as a new chondritic “grouplet” (Carlisle Lakes, Allan Hills (ALH) 85151, Yamato (Y) ?75302; Rubin and Kallemeyn, 1989). This grouplet was classified as the “Carlisle Lakes-type” chondrites (Weisberg et al., 1991). Recently, one Saharan sample and four more Antarctic meteorites were identified to belong to this group (Acfer 217, Y-793575, Y-82002, PCA91002, PCA91241). The latter two are probably paired. With the meteorite Rumuruti, the first fall of this type of chondrite is known (Schulze et al., 1994). We report here on the Saharan meteorite Acfer 217 which has chemical and mineralogical properties very similar to Rumuruti and Carlisle Lakes. All eight members of this group, Rumuruti, Carlisle Lakes, ALH85151, Y-75302, Y-793575, Y-82002, Acfer 217, and the paired samples PCA91002 and PCA91241 justify the introduction of a new group of chondritic meteorites, the Rumuruti meteorites (R). Acfer 217 is a regolith breccia consisting of up to cm-sized clasts (～33 vol%) embedded in a fine-grained, well-lithified clastic matrix. The most abundant mineral is olivine (～72 vol%), which has a high Fa-content of 37–39 mol%. The major minerals (olivine, low-Ca pyroxene, Ca-pyroxene, and plagioclase) show some compositional variability indicating a slightly unequilibrated nature of the meteorite. Considering the mean olivine composition of Fa_{37.8 ± 5.7}, a classification of Acfer 217 as a R3.8 chondrite would result; however, Acfer 217 is a regolith breccia consisting of clasts of various petrologic types. Therefore, we suggest to classify Acfer 217 as a R3–5 chondrite regolith breccia. The bulk meteorite is very weakly shocked (S2). The bulk composition of Acfer 217 and other R-meteorites show that the R-meteorites are basically chondritic in composition. The pattern of moderately volatile elements is unique in R chondrites; Na and Mn are essentially undepleted, similar to ordinary chondrites, while Zn and Se contents are similar to concentrations in CM chondrites. The oxygen isotopic composition in Acfer 217 is similar to that of Rumuruti, Carlisle Lakes, ALH 85151, and Y-75302. In a δ¹⁷O vs. δ¹⁸O-diagram, the R-meteorites form a group well resolved from other chondrite groups. Acfer 217 was a meteoroid of common size with a radius between 15–65 cm and with a single stage exposure history. Based on ²¹Ne, an exposure age of about 35 Ma was calculated.     

The crystal chemistry and Fe<Superscript>II</Superscript>–site properties of aluminosilicate garnet solid solutions as revealed by Mössbauer spectroscopy and electronic structure calculations

The three binary garnet solid solutions Fe^II₃Al₂Si₃O₁₂–X^II₃Al₂Si₃O₁₂ (X^II= Mg^II, Mn^II, Ca^II) have been investigated by ⁵⁷Fe Mössbauer spectroscopy at 298 and 77 K and by electronic structure calculations in the local spin density approximation. The spectra yield isomer shifts and quadrupole splittings that are typical for Fe^II in the dodecahedral X-site of 222 point symmetry and are similar for each of the three binaries recorded. Conversely, electronic structure calculations based on the experimental crystal structure of the different end-member garnets exhibit pronounced variations in some of the electronic properties of Fe^II that are not reflected in the spectroscopic data. These results are interpreted as indicating that the different X–O bonds in garnet solid solutions retain to a large degree the intrinsic lengths that they possess in their respective end members, and that the Fe–O bond does not change greatly as a function of composition. This is evidence for the state of alternating bonds and not for the virtual crystal approximation in describing the X–O bond types or lengths in aluminosilicate garnet solid solutions. The observed degree and behavior of the Fe^II doublet asymmetry in the Mössbauer spectra for the three solid solution series do not indicate major variations in the anisotropic recoil-free fraction of Fe^II. Variations in doublet asymmetry are more likely a result of complex next-nearest X-site neighbor interactions and/or some degree of short-range cation ordering, though doublets representing different local X-site cation configurations cannot be resolved or fitted to the experimental spectra.     

A combined temperature dependent57Fe Mössbauer and single crystal X-ray diffraction study of synthetic almandine: evidence for the Gol'danskii-Karyagin effect

Synthetic almandine garnet, Fe₃Al₂Si₃O₁₂, has been studied by temperature — dependent single crystal X-ray diffraction and⁵⁷Fe Mössbauer spectroscopy. The Fe²⁺ doublet in almandine is characterized by a small asymmetry between the high and low-velocity peaks that decreases in magnitude with decreasing temperature from 420 to 15 K. The X-ray results show that the Fe²⁺ cation is dynamically disordered with an anisotropic motion within the eight-coordinated site in garnet. The magnitudes of the X-ray determined mean-square-vibrational amplitudes of this motion parallel,x _∥, and perpendicular,x _⊥, to the principle axes of the electric field gradient give a calculated angular dependence of the electric quadrupole interaction of theI _1/2 toI _3/2 transitions that agree with the experimentally measured peak ratios. This is the first recognition of anisotropic recoil free fraction of⁵⁷Fe in silicates.     

Beobachtungen an künstlichen Forellenlaichgruben

Ohne Zusammenfassung     

Plasma gradient effects on double-probe measurements in the magnetosphere

The effects on double-probe electric field measurements induced by electron density and temperature gradients are investigated. We show that on some occasions such gradients may lead to marked spurious electric fields if the probes are assumed to lie at the same probe potential with respect to the plasma. The use of a proper bias current will decrease the magnitude of such an error. When the probes are near the plasma potential, the magnitude of these error signals, E, can vary as E\simT_e(n_e/n_e)+0.5T_e, where T_e is the electron temperature, n_e/n_e the relative electron density variation between the two sensors, and T_e the electron temperature difference between the two sensors. This not only implies that the error signals will increase linearly with the density variations but also that such signatures grow with T_e, i.e., such effects are 10 times larger in a 10-eV plasma than in a 1-eV plasma. This type of error is independent of the probe separation distance provided the gradient scale length is much larger than this distance. The largest errors occur when the probes are near to the plasma potential. At larger positive probe potentials with respect to the plasma potential, the error becomes smaller if the probes are biased, as is usually the case with spherical double-probe experiments in the tenuous magnetospheric plasmas. The crossing of a plasma boundary (like the plasmapause or magnetopause) yields an error signal of a single peak. During the crossing of a small structure (e.g., a double layer) the error signal appears as a bipolar signature. Our analysis shows that errors in double-probe measurements caused by plasma gradients are not significant at large scale (≫1 km) plasma boundaries, and may only be important in cases where small-scale (<1 km), internal gradient structures exist. Bias currents tailored for each plasma parameter regime (i.e., variable bias current) would o1q1improve the double-probe response to gradient effects considerably.     

Spatial characterization of environmental gradients in a coastal lagoon, Chincoteague Bay

Spatial patterns of environmental processes are intrinsic yet complex components of estuaries. Spatial characterization of environmental gradients is a necessary step to better understand and classify estuarine environments. A geographic information system is developed to analyze the major abiotic environmental processes, to evaluate accuracy and spatial uncertainty, and to analyze potential zonation within the choked coastal lagoon of Chincoteague Bay in Maryland and Virginia, USA. Spatially extensive grid-based models of environmental gradients are constructed from existing geospatial and environmental databases, including tidal prism, bathymetry, salinity, wave exposure, and Secchi disk depth. Integration of wetland boundaries and bathymetric data provide for full basin analysis of flushing and tidal prism. Multivariate Principal Components Analysis demonstrates the covariation among gradients and provides an empirical approach to mapping multidimensional zones within the lagoon. The project documents the development of an estuarine geographic information system that can be used to analyze and compare estuarine environments and provide data for environmental decision making.     

Cordierite III: the site occupation and concentration of Fe3+

Cordierite has the ideal formula (Mg,Fe)₂Al₄Si₅O₁₈ ^.x(H₂O,CO₂), but it must contain some Fe³⁺ to account for its blue color and strong pleochroism. The site occupation and concentration of Fe³⁺ in two Mg-rich natural cordierites have been investigated by EPR and ⁵⁷Fe Mössbauer spectroscopy. In addition, powder IR spectroscopy, X-ray diffraction, and TEM examination were used to characterize the samples. Single-crystal and powder EPR spectra indicate that Fe³⁺ is located on T₁1 in natural cordierites and not in the channels. The amount in Mg-rich cordierites is very small with an upper limit set by Mössbauer spectroscopy giving less than 0.004 cations per formula unit (pfu). Fe³⁺ in cordierite can, therefore, be considered insignificant for most petrologic calculations. Heat-treating cordierite in air at 1,000?°C for 2?days causes an oxidation and/or loss of Fe²⁺ on T₁1, together with an expulsion of Na⁺ from the channels, whereas heating at the Fe–FeO buffer produces little Fe³⁺ in cordierite. Heating at 1,000?°C removes all class I H₂O, but small amounts of class II H₂O remain as shown by the IR measurements. No evidence for channel Fe²⁺ or Fe³⁺ in the heat-treated samples was found. The blue color in cordierite arises from a broad absorption band (E//b and weaker with E//a) around 18,000?cm^?1 originating from charge-transfer between Fe²⁺ in the octahedron and Fe³⁺ in the edge-shared T₁1 tetrahedron. It therefore appears that all natural cordierites contain some tetrahedral Fe³⁺. The brown color of samples heated in air may be due to the formation of very small amounts of submicroscopic magnetite and possibly hematite. These inclusions in cordierite can only be identified through TEM study.