Diagenetic crystallization and oxidation of siderite in red bed (Buntsandstein) sediments from the Central Iberian Chain,Spain

Compactional deformation facilitated replacement of dolomite and calcite by siderite and its subsequent oxidation in carbonate cemented red beds of the Triassic Buntsandstein in the Iberian Chain. Locally, the sedimentary clasts were cemented by carbonate that was derived from dissolution of locally exposed dolomite in the basement. Microstructures indicate that during sedimentation of the rocks, oxidizing conditions prevailed in the sediments and the basement was reddened by impregnation of hematite. Reducing conditions prevailed during deformation of the sediments. Ferric iron was reduced to Fe²⁺, that reacted with deformed dolomite and calcite cement to produce fine grained siderite. At a later stage, siderite crystallites were (partly) oxidized to form a secondary phase of brown ferric oxide (goethite). Locally, goethite transformed to fine grained hematite that caused secondary reddening of the sediments. The reactions are associated with a combined volume loss of the solid phases of c. 50% per reaction mol; this was accommodated by the formation of pores. Oxidation of siderite was associated with release of CO₂; localized dissolution took place of feldspar and concurrently growth of kaolinite occurred by acidifying condition during release of CO₂. The relation of redox reactions and deformation is comparable to those in red bed conglomerates in the region. Reductive dissolution occurred at sites of stress concentration, particularly at contact points of pebbles. Late stage precipitation of ferric oxides and pyrolusite took place at oxidizing conditions in association with uplift.     

Heuristic considerations pertaining to hailstone size distributions in the plain of Friuli-Venezia Giulia

In this work, the hailstone size distributions at the ground in the plain of Friuli-Venezia Giulia are presented, as revealed through a network of polystyrene pads (hailpads), managed by volunteers, which has been active since 1988. The aim of this work is to highlight possible differences in the diurnal and seasonal behavior of hail at the ground, both from Friuli-Venezia Giulia and other countries, in order to improve the knowledge of this meteorological phenomenon.In the comparison between different countries, differences are found between the yearly size distributions of Friuli-Venezia Giulia and those of North-East Colorado, measured during the National Hail Research Experiment (NHRE). The size distributions obtained in South West France and in Friuli-Venezia Giulia are quite similar and they are slightly different from those of the Grossversuch experiment.In the comparison between different periods of the year, relevant differences are found between April and May and the other months. In particular, thunderstorms are less efficient in producing big hailstones during the former months. The most prolific month in producing hailstones is June, followed by September. This feature is interpreted as due to a form of synergy between the frequency of the synoptic forcing of storms and the amount of available energy at the ground.Analyzing the size distributions at different times of the day, the greatest differences are found in the intervals [00–06] and [06–12] in local time (respectively, [22–04] and [04–10] in UTC). These differences cannot be ascribed to the melting of the hailstones during their fall.     

The effect of cyclic operation of brittle and ductile deformation on the metamorphic assemblage in cataclasites and mylonites

Cataclasites and mylonites, and the brittle-ductile processes that produce them, were studied at exposures along the northern rim of the Grong culmination, a transverse basement antiform in the central Scandinavian Caledonides. The rock suite studied is composed of gneisses, mylonites, and cataclasites which have a granodioritic composition. The microstructure of the rocks appears to be the result of repeated alternations of brittle faulting (associated with hydrothermal mineral growth) and ductile deformation of the crystallization products. During brittle faulting K-feldspar-chlorite veins are formed, probably by incongruent pressure solution of micas. During plastic deformation of the rocks the mineral association is transformed to white mica and green biotite, according to the reaction. $$5 biotite + 3 white mica + 9 quartz + 4 H_2 O = 8 K - feldspar + 9 chlorite$$ During this reaction plagioclase is overgrown by mica and epidote, and K-feldspar crystals are replaced by albite. The reactions which involve K-feldspars are cyclic: K-feldspar that is generated in cracks tends to be removed by albitization during ductile deformation. It is concluded that the mylonites studied represent a movement zone in the Earth's crust in which seismic and aseismic slip alternated during a large part of the deformation history.     

A multiscale observational case study of an isolated tornadic supercell

This work deals with the analysis of an isolated tornadic supercell thunderstorm that took place on the plain of Friuli Venezia Giulia (Italy) causing several damage. The analysis is performed using different kind of data, looking in the available information for possible signatures that could be helpful in the forecasting and nowcasting procedures. The analysis reveals that rather than a single cause for the tornadic storm development, there is an “interaction” of several effects. In particular, a favorable environment seems to be produced by the interplay between synoptic and mesoscale environments with a fundamental role played by orography. Radar data, in particular Doppler measurements, are fundamental to the recognition and interpretation of the events but in this particular case they could give little useful information for the forecasting and nowcasting procedures. The most robust signals of an environment prone to the onset of severe deep moist convection come from the thermal gradients at the ground and by the vertical profile analysis. The reason why the event took place in that specific place and not in others is still unknown.     

Role of Shear and the Inversion Strength During Sunset Turbulence Over Land: Characteristic Length Scales

The role of shear and inversion strength on the decay of convective turbulence during sunset over land is systematically studied by means of large-eddy simulations. Different decay rates have been found for the vertical and horizontal velocity fluctuations, resulting in an increase of the anisotropy for all the studied cases. Entrainment, which persists during the decay process, favours the appearance of vertical upward movements associated with a conversion from kinetic to potential energy. Particular attention is paid to the evolution of the characteristic length scale of the various turbulent variables during this process. The length scale evolution is found to depend on the wind shear characteristics, but not on the strength of the inversion. In general the length scales of the variables grow during decay because small-scale fluctuations dissipate faster than large-scale fluctuations. Only the length scale of the vertical velocity component remains nearly constant during decay. Spectral analysis of the variance budgets shows that pressure correlations are responsible for fixing this length scale, effectively compensating the strong but oscillating influence of buoyancy. In the shear cases, after an initial period of growth, the length scales start to decrease once the buoyancy-generated variance has sufficiently subsided. Also here the effect of pressure redistribution is crucial, as it transfers the spectral influence of shear to the other velocity components.     

Unsaturated hydraulic properties of xerophilous mosses: towards implementation of moss covered soils in hydrological models

Evaporation from mosses and lichens can form a major component of the water balance, especially in ecosystems where mosses and lichens often grow abundantly, such as tundra, deserts and bogs. To facilitate moss representation in hydrological models, we parameterized the unsaturated hydraulic properties of mosses and lichens such that the capillary water flow through moss and lichen material during evaporation could be assessed. We derived the Mualem‐van Genuchten parameters of the drying retention and the hydraulic conductivity functions of four xerophilous moss species and one lichen species. The shape parameters of the retention functions (2.17 < n < 2.35 and 0.08 < α < 0.13 cm^?1) ranged between values that are typical for sandy loam and loamy sand. The shapes of the hydraulic conductivity functions of moss and lichen species diverged from those of mineral soils, because of strong negative pore‐connectivity parameters (?2.840 < l < ?2.175) and low hydraulic conductivities at slightly negative pressure heads (0.016 < K₀ < 0.280 cm/d). These K₀ values are surprisingly low, considering that mosses are very porous. However, during evaporation, large pores and voids were air filled and did not participate in capillary water flow. Small K₀ values cause mosses and lichens to be conservative with water during wet conditions, thus tempering evaporation compared to mineral soils. On the other hand, under dry conditions, mosses and lichens are able to maintain a moisture supply from the soil, leading to a higher evaporation rate than mineral soils. Hence, the modulating effect of mosses on evaporation possibly differs between wet and dry climates. Copyright © 2013 John Wiley & Sons, Ltd.     

The climatology of tornadoes and waterspouts in Italy

In this work 10 years of reports collected by weather amateurs are used to define a preliminary climatology of tornadoes and waterspouts in Italy. The results show behaviors different from those observed in other countries. Generally, tornadoes and waterspouts are more frequent in late summer and autumn than in the other seasons. The seasonality of tornadoes and waterspouts appears different for different Italian zones, in particular in the Po Valley and Friulian plain and coast (south to the Alps) tornadoes and waterspouts are more frequent in spring and early summer while in the Tirrenian and Ionian coasts (western and southern Italy), tornadoes and waterspouts are more frequent in late summer and autumn. As observed in other studies (Brooks, H., E. and Doswell, C. A. III, 2001. Some aspects of the international climatology of tornadoes by damage classification. Atmos. Res., 56, 191–201.) Italian tornadoes and waterspouts are statistically weaker than in other countries but this difference cannot be completely ascribed to the presence of waterspouts. The “CAPE Storm-Relative-Helicity diagrams” and “Shear Magnitude diagrams” obtained for Italian tornadoes and waterspouts show different characteristics than those obtained for US. The cause of these differences is still unknown, it can rely in the sample selection (problems with the concept of proximity sounding) or in a real climatic effect.     

Periglacial microjointing and faulting in Weichselian fluvio-aeolian deposits

A Weichselian Late Pleniglacial fluvio-aeolian deposit has been investigated in the southern Netherlands. Three main structural lineaments have been distinguished: (1) very small, vertical platy structures (microjoints), in a parallel and a columnar configuration; (2) large joints and normal faults with minor displacement (‘Grubbenvorst type’), arranged in a conjugate fault-system; (3) large joints and normal faults (‘wedge-type’), located adjacent to ice-wedge casts. Since clay is absent, the occurrence of the vertical platy structures cannot be attributed to desiccation cracking. The vertical platy structures are interpreted as the result of thermal contraction cracking of a relatively thin layer, due to a sudden temperature drop. The large joints and normal faults of the Grubbenvorst type are the result of failure of the sediment due to the melting of the permafrost in the Late Pleniglacial, just before the formation of the Beuningen Gravel Bed. In other areas large periglacial convolutions have been formed during the same period. The normal faults and joints of the wedge type are more generally known. They are the result of failure of the sediment adjacent to a melting ice wedge.