Radiometric dating of recent lake sediments from a highly eroded area in semiarid Tanzania

Semiarid regions are vulnerable environments with a series of important and often discussed problems such as land degradation, water scarcity and desertification. These regions are dynamic and respond quickly to climatic and environmental changes. Unlike lakes in temperate zones, lakes in semiarid regions are yet poorly utilized as climatic and environmental indicators. In this study aquatic deposits are used to uncover the environmental history of a severely degraded area in central Tanzania. The ²¹⁰Pb and ¹³⁷Cs chronologies date a 360 cm long sediment sequence to 155 years. The sediments show that lake Haubi basin changed from a seasonally waterlogged depression to a lake at the turn of the century. Calculated sedimentation rates show that the catchment of the lake has been subject to varied and enhanced soil erosion during the last 155 years.     

The environment and evolution of an early egyptian urban center: Archaeological and geochemical investigations at hierakonpolis

We describe and summarize the results of new interdisciplinary techniques for recovering and analyzing historical and paleoenvironmental data from mid-Holocene archaeological and geological deposits in the modern Nile floodplain at the site of Hierakonpolis in Upper Egypt. Application of these techniques has produced the first stratigraphic link between historic (Early Dynastic) and late prehistoric (Predynastic) periods in the Nile Valley at a site which played a central role in the evolution of Egyptian civilization.     

Signature of the 27-day variation in hemispheric sunspot activity and asymmetry during 2010-2015

In the present work,we study the time evolution,significance of the N-S asymmetry excesses presented as a function of the solar cycle and prominent rotational p...     

Andean orogenic signature in the Quaternary sandy barriers of Southernmost Brazilian Passive Margin-Paradigm as a source area

Multiple source provenance of sediments and submarine fan formation are herein investigated based on Quaternary sandy barriers of the Brazilian Southernmost Coastal Plain.LA-ICP-MS dating on 1625 detrital zircons from marine and aeolian facies sands of four successive lagoon-barrier systems are analyzed.The characterization of Archean to Pleistocene zircons into a younger Andean(22 ± 4 Ma to 1 ± 1 Ma,48 from 1625),Mesozoic to Paleozoic,and Mesoproterozoic(479 from 1622) populations suggest that the main feeding of sediments to the coastal plain occurred through the La Plata River drainage system.The significant contribution of sediments is transported from the mouth of La Plata River northward by longshore circulation(littoral drift).Minor contributions are also recognized as.a farther source associated with the Patagonia drainage and nearby source related to the Uruguay/Rio Grande do Sul Shield and the Paraná Basin,drained by the Camaqu? and Jacuí rivers.The latter one is recognized by the contribution from Neoproterozoic to Early Paleozoic,and some Paleoproterozoic and Archean zircon grains.The definition of the sources of clastic sediments allows inferences about the origination of Rio Grande Fan where both the cold Falkland and the warm Brazil currents played a major role.     

Three-dimensional hydromechanical modeling of internal erosion in dike-on-foundation

Currently, numerical studies at the real scale of an entire engineering structure considering internal erosion are still rare. This paper presents a three-dimensional (3D) numerical simulation of the effects of internal erosion within a linear dike located on a foundation. A two-dimensional (2D) finite element code has been extended to 3D in order to analyze the impact of internal erosion under more realistic hydromechanical conditions. The saturated soil has been considered as a mixture of four interacting constituents: soil skeleton, erodible fines, fluidized fine particles, and fluid. The detachment and transport of the fine particles have been modeled with a mass exchange model between the solid and the fluid phases. An elastoplastic constitutive model for sand-silt mixtures has been developed to monitor the effect of the evolution of both the porosity and the fines content induced by internal erosion upon the behavior of the soil skeleton. An unsaturated flow condition has been implemented into this coupled hydromechanical model to describe more accurately the seepage within the dike and the foundation. A stabilized finite element method was used to eliminate spurious numerical oscillations in solving the convection-dominated transport of fluidized particles. This numerical tool was then applied to a specific dike-on-foundation case subjected to internal erosion induced by a leakage located at the bottom of the foundation. Different failure modes were observed and analyzed for different boundary conditions, including the significant influence of the leakage cavity size and the elevation of the water level at the upstream and downstream sides of the dike.     

Arsenite sorption at the magnetite-water interface during aqueous precipitation of magnetite: EXAFS evidence for a new arsenite surface complex

The interaction of aqueous As(III) with magnetite during its precipitation from aqueous solution at neutral pH has been studied as a function of initial As/Fe ratio. Arsenite is sequestered via surface adsorption and surface precipitation reactions, which in turn influence the crystal growth of magnetite. Sorption samples were characterized using EXAFS spectroscopy at the As K-edge in combination with HRTEM observations, energy dispersive X-ray analysis at the nanoscale, electron energy loss spectroscopy at the Fe L₃-edge, and XRD-Rietveld analyses of reaction products. Our results show that As(III) forms predominantly tridentate hexanuclear As(III)O₃ complexes (³C), where the As(III)O₃ pyramids occupy vacant tetrahedral sites on {1 1 1} surfaces of magnetite particles. This is the first time such a tridentate surface complex has been observed for arsenic. This complex, with a dominant As-Fe distance of 3.53 ± 0.02 Å, occurs in all samples examined except the one with the highest As/Fe ratio (0.33). In addition, at the two highest As/Fe ratios (0.133 and 0.333) arsenite tends to form mononuclear edge-sharing As(III)O₃ species (²E) within a highly soluble amorphous As(III)-Fe(III,II)-containing precipitate. At the two lowest As/Fe ratios (0.007 and 0.033), our results indicate the presence of additional As(III) species with a dominant As-Fe distance of 3.30 ± 0.02 Å, for which a possible structural model is proposed. The tridentate ³C As(III)O₃ complexes on the {1 1 1} magnetite surface, together with this additional As(III) species, dramatically lower the solubility of arsenite in the anoxic model systems studied. They may thus play an important role in lowering arsenite solubility in putative magnetite-based water treatment processes, as well as in natural iron-rich anoxic media, especially during the reductive dissolution-precipitation of iron minerals in anoxic environments.     

Interplay between urban communities and human‐crowd mobility: A study using contributed geospatial data sources

An intense process of urbanization, witnessed particularly in the last decade, has stressed the need to comprehend human mobility behavior in urban settings. Although the emergence of contributed geospatial data (i.e., pervasive activity‐based data) has contributed to substantial progress toward understanding human activity, the relationship between human‐crowd mobility and the functional structure of a city is not yet well understood. In this context, the present research focuses on the intra‐urban origin–destination matrix modeling founded on a combination of two major crowdsourced datasets as well as the inclusion of urban communities’ structure. Specifically, the well‐known “radiation” and “PWO” models were modified through first, identifying the communities embedded in the cyberspace network then employing the identified hierarchical structure of the spatial‐interaction network for the formulation of the users’ movement network and second, imposing proper input variables including the telecommunication activity volume and check‐in frequency. The results obtained by various empirical analyses suggest that the modified community‐constrained origin–destination flow estimation models exhibit better performance levels than those of alternative conventional mobility models.     

Temporal Changes in Seawater Carbonate Chemistry and Carbon Export from a Southern California Estuary

Estuaries are important subcomponents of the coastal ocean, but knowledge about the temporal and spatial variability of their carbonate chemistry, as well as their contribution to coastal and global carbon fluxes, are limited. In the present study, we measured the temporal and spatial variability of biogeochemical parameters in a saltmarsh estuary in Southern California, the San Dieguito Lagoon (SDL). We also estimated the flux of dissolved inorganic carbon (DIC) and total organic carbon (TOC) to the adjacent coastal ocean over diel and seasonal timescales. The combined net flux of DIC and TOC (F_DIC?+?TOC) to the ocean during outgoing tides ranged from ??1.8±0.5?×?10³ to 9.5±0.7?×?10³?mol C h^?1 during baseline conditions. Based on these fluxes, a rough estimate of the net annual export of DIC and TOC totaled 10±4?×?10⁶?mol C year^?1. Following a major rain event (36 mm rain in 3 days), F_DIC?+?TOC increased and reached values as high as 29.0 ±?0.7?×?10³?mol C h^?1. Assuming a hypothetical scenario of three similar storm events in a year, our annual net flux estimate more than doubled to 25 ±?4?×?10⁶?mol C year^?1. These findings highlight the importance of assessing coastal carbon fluxes on different timescales and incorporating event scale variations in these assessments. Furthermore, for most of the observations elevated levels of total alkalinity (TA) and pH were observed at the estuary mouth relative to the coastal ocean. This suggests that SDL partly buffers against acidification of adjacent coastal surface waters, although the spatial extent of this buffering is likely small.     

Flood prediction and mitigation in coastal tourism areas,a case study: Hurghada,Egypt

Flood mitigation involves the management and control of floodwater movement, such as redirecting flood runoff through the use of floodwalls and flood gates, rather than trying to prevent floods altogether. The prevention and mitigation of flooding can be studied on three levels: on individual properties, small communities, and whole towns or cities. The current study area is located in Hurghada on the Red Sea, which is considered an important area for coastal tourism. The study area is located at distance 7.50 km from El Gouna city along the Red Sea and east of Hurghada–Al Ismaileya road. The aim of this research is to derive the runoff flow paths across the study area and their flow magnitudes under different rainfall events of 10, 25, 50, and 100 year return periods in order to design the flood mitigation measures to protect such important areas. Field data (e.g., topographic data and rainfall intensities) were collected for the study area. The results indicated that the site is exposed to high flash flood risk and protection work is required. In order to protect the area from flood risks, locations of number of drainage channels and dams were selected and designed based on flood quantity and direction. The proposed mitigation system is capable of protecting this crucial area from flood risks and increases the national income from tourism. This study can be applied in different areas of Egypt and the world.