Persistent organic pollutants and stable isotopes in biopsy samples (2004/2006) from Southern Resident killer whales

“Southern Resident” killer whales include three “pods” (J, K and L) that reside primarily in Puget Sound/Georgia Basin during the spring, summer and fall. This population was listed as “endangered” in the US and Canada following a 20% decline between 1996 and 2001. The current study, using blubber/epidermis biopsy samples, contributes contemporary information about potential factors (i.e., levels of pollutants or changes in diet) that could adversely affect Southern Residents. Carbon and nitrogen stable isotopes indicated J- and L-pod consumed prey from similar trophic levels in 2004/2006 and also showed no evidence for a large shift in the trophic level of prey consumed by L-pod between 1996 and 2004/2006. ∑PCBs decreased for Southern Residents biopsied in 2004/2006 compared to 1993–1995. Surprisingly, however, a three-year-old male whale (J39) had the highest concentrations of ∑PBDEs, ∑HCHs and HCB. POP ratio differences between J- and L-pod suggested that they occupy different ranges in winter.     

Chemical studies of copper-organic complexes isolated from estuarine waters using C18 reverse-phase liquid chromatography

Dissolved organic matter (DOM) and dissolved copper-organic complexes were isolated from the estuarine waters of Narragansett Bay, RI, using reverse-phase liquid chromatography employing C₁₈ Sep-Pak cartridges (Waters Associates). The cartridges were found to have a constant retention efficiency for processing ? 1-l volumes of seawater. Fractionation of the isolated material, by sequential elution of the Sep-Pak with water: methanol mixtures of increasing organic solvent concentration, yielded a fraction of the organic matter with a specific copper activity six times greater than the overall activity for the isolated DOM. Analysis of this fraction by high performance liquid chromatography suggested that the organic components are of intermediate polarity and have appreciable aromatic character.An investigation of the protonation characteristics of the isolated complexes indicated that most of the copper is associated with a broad range of acidic sites on the DOM. Analysis by electron paramagnetic resonance spectroscopy confirmed the organic association of the isolated copper and also suggested the presence of several types of binding sites which probably involve oxygen donor ligands.Studies of the exchange of ⁶⁴Cu with these binding sites on the isolated DOM indicated that 70% of the sites undergo rapid exchange with copper in seawater while 20% of these sites did not exchange in a 24-h time period.     

Influence of heterogeneous land surfaces on surface energy and mass fluxes

Summary Land-surface heterogeneity affects surface energy fluxes. The magnitudes of selected land-surface influences are quantified by comparing observations with model simulations of the FIFE (First ISLSCP Field Experiment) domain. Several plausible heterogeneous and homogeneous initial and boundary conditions are examined, although soilmoisture variability is emphasized. It turns out that simple spatial averages of surface variation produced biased flux values. Simulated maximum latent-heat fluxes were approximately 30 to 40 W m^–2 higher, and air temperatures 0.4 °C lower (at noon), when computations were initialized with spatially averaged soil-moisture and leaf-area-index fields. The planetary boundary layer (PBL) height and turbulent exchanges were lower as well. It additionally was observed that (largely due to the nonlinear relationship between initial soil-moisture availability and the evapotranspiration rate), real latent-heat flux can be substantially less than simulated latent-heat flux using models initialized with spatially averaged soil-moisture fields. Differences between real and simulated fluxes also vary with the resolution at which real soil-moisture heterogeneity is discretized.With 8 Figures     

Modeling undertow due to random waves

A numerical model of undertow due to random waves is developed. The model includes three sub-models: (i) a model for multi-directional and multi-frequency random wave transformation, (ii) a surface roller evolution model, and (iii) a model for calculating the vertical distribution and the mean value of the undertow velocity. The calculation of wave trough level is performed based on a theory for the wave asymmetry. The model was successfully validated against small- and large-scale laboratory experiments. Thus, the model is expected to provide reliable input for the modeling of sediment transport and morphological change due to waves and currents.     

Gender,Place, and Social Contacts: Understanding Awareness of Vulnerability to Terrorism

Abstract

Creating resiliency, accomplished in part by individuals preparing for disaster, is the primary strategy outside of law enforcement for responding to the threat of urban terrorism. Individuals prepare when they perceive a need to do so, yet little is known about what shapes a person's awareness of vulnerability to terrorism. Because evidence indicates that social contacts act as conduits of information and affect perception of risk to natural hazards, it is possible that such contacts also affect terrorism vulnerability awareness. Because social contacts are also known to be systematically segmented by gender and location, we hypothesized that conversations about terrorism vary by gender and place, specifically the home and work place. Drawing on data from 93 interviews with householders in Boston, the study demonstrates that: (1) family networks generated discussions of home preparedness, whereas workplace networks engaged a wider variety of topics; (2) women discussed terrorism more frequently and in greater depth than did men; and (3) women heard more preparedness messages for the home than did men, whereas men undertook preparedness activities external to the home. The findings bridge geography and terrorism studies by theorizing emplaced and subjective human experiences that prompt conversations about terrorism. These conversations, in turn, help urban emergency managers and risk-hazards geographers promote rational dialogue and action vis-à-vis terrorism. Hazards researchers have shown that the more people discuss terrorism, the less they seek extreme and unwarranted responses.