Zur Charakterisierung suspendierter Wasserinhaltsstoffe. Teil 2: Erste Ergebnisse der praktischen Anwendung der Analysenmethoden

Nachdem in Teil 1 (Schultz ) die Bedeutung der Feststoffe für den Betrieb von Wasseraufbereitungsanlagen und Analysenmethoden zur Charakterisierung der Feststoffe diskutiert wurden, enthält Teil 2 die Ergebnisse von Untersuchungen an einem ausgewählten Vorfluter. Verschiedene Analysenmethoden werden getestet, miteinander verglichen und ihre Eignung zur Einschätzung des Leistungsverhaltens der Aufbereitungsanlagen überprüft.     

Allan Hills 77081—an unusual stony meteorite

Allan Hills (ALHA) 77081 is achondritic in texture while the mineral composition and the chemistry are chondritic with the exception of a few elements. An assignment to one specific group of ordinary chondrites is therefore difficult. In many respects this meteorite is similar to the unusual stone meteorite Acapulco. The REE pattern of ALHA 77081 is essentially flat and the distribution ratios of siderophile elements between metal and silicates are high compared to ordinary chondrites.Gas retention ages are 3.5±0.5 AE for U, Th-He and 4.50±0.15 AE for K-Ar. In spite of the high degree of recrystallisation the meteorite contains trapped noble gases in amounts comparable to type 4 chondrites.Cosmic ray tracks and spallogenic noble gases indicate a small preatmospheric radius of about 2–3 cm. Spallogenic nuclides produced by solar cosmic rays or stopped solar flare ions may be present.     

Scaling the Microphysics Equations and Analyzing the Variability of Hydrometeor Production Rates in a Controlled Parameter Space

A set of microphysics equations is scaled based on the convective length and velocity scales.Comparisons are made among the dynamical transport and various microphysical processes.From the scaling analysis,it becomes apparent which parameterized microphysical processes present off-scaled influences in the integration of the set of microphysics equations. The variabilities of the parameterized microphysical processes are also studied using the approach of a controlled parameter space.Given macroscopic dynamic and thermodynamic conditions in different regions of convective storms,it is possible to analyze and compare vertical profiles of these processes.Bulk diabatic heating profiles for a cumulus convective updraft and downdraft are also derived from this analysis. From the two different angles,the scale analysis and the controlled-parameter space approach can both provide an insight into and an understanding of microphysics parameterizations.     

Reflections from a randomly grooved interface: ultrasonic modelling and finite-diff erence calculation1

This study utilizes ultrasonic water tank modelling to examine the complexities which can result when seismic energy is diffracted by even a simple 3D interface structure. Ultrasonic laboratory modelling is carried out in our in-house water tank, using an aluminum block to simulate very simple ocean-bottom topography. The topography consists of parallel depressions which simulate valleys running parallel to a mid-ocean spreading ridge. This study shows that the phase and amplitude of primary ocean-bottom reflections can vary strongly with the azimuth of propagation. The trailing energy coda also varies dramatically as a function of propagation direction, showing the importance of developing a seismic model which includes the full 3D azimuthal distribution of interface structure.     

Radiogenic, fissiogenic and nucleogenic noble gases in zircons

The concentrations and isotopic compositions of argon, krypton and xenon have been determined in a grain size suite of zircons separated from pyroxene syenite of the Botnavatn Igneous Complex, southwestern Norway. The UPb systematics of these zircons has been studied previously.Kr and Xe are mixtures of fissiogenic gas from the spontaneous fission of²³⁸U and a component with atmospheric isotopic composition. From correlation diagrams the fissiogenic component is determined to be:⁸³Kr :⁸⁴Kr :⁸⁶Kr = (4.6 ± 1.3) : (11.0 ± 2.0) : 100 and¹²⁹Xe :¹³¹Xe :¹³²Xe :¹³⁴Xe :¹³⁶Xe = (0.6 ± 0.3) : (8.8 ± 0.2) : (56.8 ± 0.3) : (82.8 ± 0.4) : 100. The fissiogenic¹³⁶Xe/⁸⁶Kr is 6.0 ± 0.4.The Ar isotopic composition shows radiogenic⁴⁰Ar and a small excess of³⁸Ar. The excess³⁸Ar of about 1 × 10⁻¹¹ cm³ STP/g can be explained by reactions of α-particles with chlorine. Asymmetric fission of²³⁸U which has been postulated to cause argon isotope anomalies in U-rich minerals is unnecessary to explain the observed³⁸Ar concentrations.UXe ages are (1.19 ± 0.07) Ga, in agreement with UPb ages. However, if the recoil loss of fissiogenic Xe is considered the UXe ages of these zircons are about 1.53 Ga, which is comparable with the KAr ages and some RbSr ages observed in basement rocks in this region. The uncertainty of the product of fission yield times spontaneous fission decay constant of²³⁸U prevents to decide which age is the true crystallization age.     

Environmental estrogens: dose–response relationships for vitellogenin formation and reproductive toxicity in male rainbow trout

The appearance of the egg-yolk protein vitellogenin (Vg) in plasma of male fish is a sensitive indicator of exposure to estrogenic compounds. We have been studying the kinetics of Vg formation and excretion in rainbow trout with a goal towards developing an integrated pharmacokinetic–pharmcodynamic (PK–PD) model to quantitatively relate cumulative estrogenic exposure of fish to the expression and appearance of Vg in plasma. We administered graded doses of ethynylestradiol (EE2), o,p-DDT, DDD and DDE and octylphenol to male rainbow trout via a dorsal aortic cannula which allowed repetitive blood sampling from individual fish for up to 48 days after injection. The plasma concentrations of the xenobiotics and Vg were simultaneously quantified using ELISA and GC–MS or GC–ECD. In separate experiments, sexually mature trout were exposed to graded water concentrations of EE2 for 3 months and various parameters indicative of the functional status of the male reproductive system determined. These parameters included tissue-somatic indices, histopathological evaluation, spermatocrit, sperm motility (quantified using computer-assisted-motion analysis) and viability of semen based on fertilization assays using eggs harvested from untreated trout. Results from fertilization assays indicated that 12 week exposure to EE2 concentrations of 10 and 100 ng/l caused a 50% reduction in the fertilization rate of semen harvested from exposed trout. PK–PD modeling strategies proved valuable tools for linking chemical exposures to Vg formation.