Extended Sediment Quality Rating for Trace Elements in Urban Waters – Case Study Klinke,Germany

The European Water Framework Directive (WFD) commits European Union member states to achieving good ecological status in all water bodies by 2015. For sediments the definition of good chemical status is based on numerical sediment quality guidelines. The aqua regia fraction is thus used for the evaluation of heavy metal concentrations in sediments. The chemical constituents in sediments responsible for mobility and toxicity are not considered generally. This article presents the combining of the sequential BCR procedure, for determining the chemical species of relevant elements, with the geoaccumulation index principle a numerical classification method for sediment quality guidelines. Using the BCR method it can be demonstrated that changes in element speciation can lead to more highly mobile species of trace elements which may affect the hazardous potential of sediments despite the “good chemical status” classification for aqua regia digestions. The Klinke stream is an urban surface water body located in Magdeburg, the state capital of Saxony‐Anhalt, Germany. Using this stream as an example it is shown that this additional information helps to describe the dynamics and discharge of the trace elements Al, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, As, Rb, Sr, Mo, Pd, Cd, Sb, Ba, Pb, Bi, and U into the Elbe River from urban water bodies.     

Estimating the Sampling Uncertainty for the Analysis of Solid Refused Fuel

Uncertainty assessment of the parameters used for the reporting in the emissions trading system (ETS) to characterize fuels includes not only the processes in a laboratory but has to be expanded for inclusion of sampling and sample preparation. Analysis of variance was used to allocate the contributing uncertainties to the steps described. Apart from some specific results for sampling methods, it was observed that the uncertainty of sampling was in the same order of magnitude than the analytical and the sample preparation error. Several measures to enhance quality assurance in sampling and sample preparation could be derived from specific results. The results were used in the European Monitoring and Reporting Regulation, which set out the requirements for ETS. Sampling and sample preparation have to be included in uncertainty assessment as well as sampling procedures and sampling plans (including quality assurance) have to be agreed upon by the laboratories, carrying out the analytics of those samples.     

Accumulation of Copper and Zinc in Danish Agricultural Soils in Intensive Pig Production Areas

Geografisk Tidsskrift, Danish Journal of Geography 105(2):15–22, 2005

The change of Cu and Zn concentrations in Danish agricultural soils was studied in areas with intensive pig production. Cu and Zn are found in pig manure as the metals are added to pig feed as growth promoters. The changes in concentrations of total and 0.02 MEDTA extractable Cu and Zn in soils from 1986 to 1998 were determined from samples taken at two depths (0–25 cm and 25–50 cm) from 73 sites. Pig manure and mineral fertilizer was added to 60 sites whereas fertilizer only was used on 13 sites. During the survey period soil Cu concentrations increased in both depths but mostly in the sites where pig manure was added. Furthermore, the results indicated that some plant-available Cu and Zn were transported from the topsoil to the subsoil. No significant change in soil Zn concentration was found although a slight reduction was observed. Comparing soil metal concentrations observed in 1998 to the total pig manure application in a 12-year period, it was observed that application of manure caused an accumulation of Cu and of Zn in the upper 50 cm soil. The accumulation rates correspond to the Cu and Zn concentrations in the pig manure.     

Multivariate analysis of sediment data from the upper and middle Odra River (Poland)

River pollution data are characterized by high variability. Multivariate statistical methods help to determine a complex set of these multidimensional data and to extract latent information (e.g. differently polluted areas, discharges). The chemometric methods can handle interactions between different pollutants and relationships among various sampling locations. This study presents an application of multivariate data analysis in the field of environmental pollution. The dataset consists of As, Cd, Cr, Cu, Fe, Ni, Mn, Pb and Zn contents of sediment samples collected in the upper and middle Odra River (Poland) in three sampling campaigns (November 1998, June 1999, and May 2000). As chemometric tools cluster analysis (CA), multivariate analysis of variance and discriminant analysis (MVDA) and factor analysis (FA) were used to investigate the matrix of 60 sampling points.     

An integrated and transferable climate change vulnerability assessment for regional application

While sectoral vulnerability assessments have become common usage in the climate change field, integrated and transferable approaches are still rare. However, comprehensive knowledge is demanded to concretize and prioritize adaptation strategies, which are currently being drafted at national and state levels. We present a multisectoral analysis where sensitivity is quantified by the physical, social, environmental and economic dimension by means of tailor-made approaches for specific sectors. These are directly related to relevant exposure variables defined as relative climatic changes until the end of this century. Aggregation of the sector-specific impacts, comprising both sensitivity and exposure, leads to integrated impact measures. These are then combined with the generic adaptive capacity. We exemplify our methodology for municipalities in the German state North Rhine-Westphalia for two regional climate models. Our approach allows for the integrated assessment, while at the same time enabling a sector-specific perspective. However, various limitations remain, especially regarding the aggregation across sectors. We emphasize the need to consider the aim and methodological advantages and disadvantages before applying any vulnerability assessment.     

Microstructure characteristics during hydrate formation and dissociation revealed by X-ray tomographic microscopy

Despite much progress over the past years in fundamental gas hydrate research, frontiers to the unknown are the early beginning and early decomposition of gas hydrates in their natural, submarine environment: gas bubbles meeting ocean water and forming hydrate, and gas starting to escape from the surface of a hydrate grain. In this paper we report on both of these topics, and present three-dimensional microstructure results obtained by synchrotron radiation X-ray cryo-tomographic microscopy (SRXCTM). Hydrates can precipitate when hydrate-forming molecules such as methane exceed solubility, and combine with water within the gas hydrate stability zone. Here we show hydrate formation on surfaces of bubbles from different gas mixtures and seawater, based on underwater robotic in situ experiments in the deep Monterey Canyon, offshore California. Hydrate begins to form from the surrounding water on the bubble surfaces, and subsequently grows inward into the bubble, evidenced by distinct edges. Over time, the bubbles become smaller while gas is being incorporated into newly formed hydrate. In contrast, current understanding has been that hydrate decomposition starts on the outer surface of hydrate aggregates and grains. It is shown that in an early stage of decomposition, newly found tube structures connect well-preserved gas hydrate patches to areas that are dissociating, demonstrating how dissociating areas in a hydrate grain are linked through hydrate that is still intact and will likely decompose at a later stage.

High resolution sensors in space and time for determination saltation and creep intensity

The measurement of aeolian sand transport rates at high temporal and spatial resolution is crucial for further progress in testing and developing numerical models of sand movement by wind and in the modelling of sand dunes, ripples and so on. This paper reports the development and field testing of two sand transport sensors. The first one, a webcam commonly used with personal computers, is a new device in aeolian research. The webcam frame transfer is triggered by a sonic anemometer every 0·1 second. Consecutive frames are compared and analysed in real‐time by a computer program. Changes in pixel light intensity exceeding a threshold level are recorded and interpreted as grain movements. The second sensor is a small‐sized ‘Saltiphone’‐type device made of simple loudspeakers with a diameter of 15 mm as used in MP3 players. It can be deployed as a 2 × 3 array of six such devices distributed to enable horizontal and vertical spatial sampling of the sand flux. The devices are tested under field conditions. Both signals and the sum of microphone impacts over 15 minutes are compared to data gathered using a Guelph sand trap, and very good agreement is found. Measurements in a wind tunnel using sieved natural sand indicate that the webcam can be used to infer additional information about the grain size. As an application, the fluid and impact thresholds for aeolian sand transport are investigated in field measurements by analysing the onset and breakdown of saltation in gust and lull intervals of rising and falling wind speeds, respectively. In this way, constitutive equations for sand transport in terms of the wind speed can be tested. If viable, they can be employed to infer estimates for the thresholds by minimizing the root‐mean‐square error between measured and calculated transport data. Copyright © 2012 John Wiley & Sons, Ltd.     

Social and ecological constraints on decision making by transhumant pastoralists: a case study from the Moroccan Atlas Mountains

Transhumant pastoralism is an important activity in southern Morocco. Migration pattern of transhumant pastoralists can be affected by physical factors (e.g. droughts and diseases) or socioeconomic factors (e.g. schooling options for children and migration costs). We studied the spatio-temporal rangeland usage of the three tribes Ait Mgoun, Ait Zekri, and Ait Toumert in the south-central Atlas region with a two-fold approach. First, we tracked the migration movements of one representative transhumant herd using the Advanced Research and Global Observation Satellite (ARGOS) collars, which record coordinates from satellite signals. Second, we interviewed herders to obtain information about general grazing practices of the respective tribe and to gain more direct information on motivations underlying decisions. For each tribe we observed small-, medium- and large-scale movements. We found that the most important drivers of migration decisions were seasonal fodder availability and weather conditions in combination with herd-specific risk and cost assessment, as well as personal factors. In conclusion, general migration patterns vary in time, both between and within the tribes, but according to a regulatory framework. Moreover, it appears that both the customary rules and its flexible adaptation to physical constraints are generally beneficial in terms of conservation of the arid and semiarid rangeland resources.     

New insights into slide processes and seafloor geology revealed by side-scan imagery of the massive Hinlopen Slide, Arctic Ocean margin

The submarine Hinlopen Slide, located along the Arctic Ocean margin, is one of the largest known mass movements on Earth. The slide scar has several unusual morphometric characteristics, including headwalls up to 1,500 m high and spectacularly large, steep-sided rafted megablocks. The slide processes and continental margin properties that produced these features are not well known. A new high-resolution TOBI (towed ocean bottom instrument) side-scan sonar dataset reveals information about the detailed seafloor morphology and, therefore, slide dynamics during the final stages of sliding. First, the headwall area was efficiently and almost completely evacuated of slide debris, which is unusual for large submarine slides. Second, features relating to the propagation of extension to the shelf behind the headwall are absent, suggesting “strong” cohesive shelf material here or that a very stable shelf configuration was reached, possibly defined by NE-SW-trending faults. Third, there is little evidence for the translation of shelf material, again uncommon for submarine slides. Taken together with the occurrence of massive megablocks in the slide debris, Hinlopen Slide is distinct because of the juxtaposition of apparently “stronger” shelf material that has remained intact (headwalls, megablocks), and “weaker” shelf material that disaggregated fully during slope failure. Nevertheless, there is sonograph evidence of variable post-slide disintegration of the megablocks. Contrary to previous interpretations, this suggests that the blocks comprise sedimentary lithologies that are prone to failure, a key aspect awaiting confirmation.     

Suppression of Periodic Disturbances in Seismic Aftershock Recordings for Better Localisation of Underground Explosions

For precise localisation of a potential underground nuclear explosion, the Comprehensive Nuclear-Test-Ban Treaty Organization, during an on-site inspection, can set up seismic sensors to find the very small signals from aftershocks. These signals can be masked by periodic disturbances from, for example, helicopters. We present a new method to characterise every such disturbance by the amplitude, frequency and phase of the underlying sine in the time domain using a mathematical expression for its Hann-windowed discrete Fourier transform. The contributions of these sines are computed and subtracted from the complex spectrum sequentially. Two examples show the performance of the procedure: (1) synthetic sines superposed to a coal-mine induced event, orders of magnitude stronger than the latter, can be removed successfully, (2) removal of periodic content from the signals of a helicopter overflight reduces the amplitude by a factor 3.3 when the frequencies are approximately constant. The procedure cannot yet cope with peaks that change frequency too fast, for example by the Doppler effect when passing, and with peaks that lie too close to each other. Improvement to solve these problems seems possible.