Chloroaromatics in groundwater: chances of bioremediation

. The potential for biodegrading of mono-, di- and trichlorobenzenes in a contaminated aquifer in Bitterfeld (Saxony-Anhalt) was tested both in the laboratory and using on-site column experiments. Under the prevailing anaerobic conditions, the reductive dechlorination of 1,4-dichlorobenzene (1,4-DCB) takes place very slowly. Under aerobic conditions the indigenous micro-organisms are able to mineralize monochlorobenzene (MCB) and 1,4-DCB. The degradation rates for the other two isomeric dichlorobenzenes and for 1,2,4-trichlorobenzene (1,2,4-TCB) under aerobic conditions are significantly lower. Indications were found that once the oxygen has been consumed, Fe(III) species can be used as alternative electron acceptors.     

Ecological succession, palaeoenvironmental change, and depositional sequences of Barremian–Aptian shallow-water carbonates in northern Oman

Abstract Barremian and Aptian shallow‐water carbonate facies (uppermost Lekhwair, Kharaib and Shuaiba Formations) are described from outcrops in northern Oman. Based on facies analysis and bedding pattern, three orders of depositional sequences are defined (third to fifth order) and correlated between sections. Over the course of three third‐order sequences, covering the Barremian to Lower Aptian, a third‐order depositional pattern is documented that consists of a succession of three distinct faunal assemblages: discoidal orbitolinids and calcareous algae were deposited during early transgression; microbialites and microencrusters dominate the late transgressive to early highstand facies; and a rudist‐ and miliolid‐dominated facies is typical of the highstand. This ecological succession was controlled largely by palaeoenvironmental changes, such as trophic level and clay influx, rather than sedimentological factors controlled by variations in accommodation space. Orbitolinid beds and carbonates formed by microbialites and microencrusters seem to be the shallow‐water carbonate response to global changes affecting Late Barremian to Aptian palaeoclimate and palaeoceanography.     

Longitudinal variability of the equatorial counter electrojet during the solar cycle 24

Studia Geophysica et Geodaetica - Ground and space-based geomagnetic data were used in the investigation of the longitudinal, seasonal and lunar phase dependence of the equatorial counter...     

Boundary condition control of fluvial obstacle mark formation – framework from a geoscientific perspective

Obstacle marks are sedimentary bedforms, typically composed of an upstream local scour hole and a downstream sediment accumulation in the vicinity of an obstruction that is exposed to a current. However, specific morphologies are variable in fluvial, coastal and submarine environments. Although obstacle marks and the phenomenon of local scouring are subject to different scientific disciplines, the objectives of investigations are rather incoherent and no systematic framework for analysing and evaluating boundary condition control exists yet, especially concerning limited knowledge of the cause and effect relationship of obstacle mark formation at instream boulders or vegetation elements in variable environmental conditions. Thus, a parameter framework is developed which identifies a spectrum of extrinsic and intrinsic boundary conditions that control the major process dynamics of obstacle mark formation. The framework is composed of dimensionless control parameters that are separated by a hierarchical order regarding their significance for obstacle mark formation. Primary control parameters determine the geometrical scale of flow field at the obstacle, and therefore control the potential maximum size of the obstacle. Secondary control parameters affect the dynamics of the flow field in geometrical scale and limit the potential maximum size of the emerging sedimentary structure if thresholds are crossed. The framework is supposed to be a foundation for subsequent quantification and determination of thresholds by systematic laboratory studies. To elucidate this, flume-based research is presented, evaluating the influence of different flow levels at boulder-like obstacles of different shapes. The results show that obstacle mark dimensions were maximized at shallow flow depths compared to obstacle dimensions, while deep flows at submerged boulder-like obstructions caused considerably smaller obstacle marks. In interdependency with a rounded and more streamlined obstacle shape, deep flows even cause a deviation of morphology if the flow depth above an obstacle exceeds 1.6 times the obstacle's dimensions. © 2020 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd.     

Cover stones on liquefiable soil bed under waves

The paper describes the results of an experimental study on the behavior of cover stones on a liquefiable soil bed exposed to a progressive wave. The soil was silt with d₅₀ = 0.098 mm. Stones, the size of 4 cm, were used as cover material. The effect of packing density of stones, and that of number of stone layers (including the effect of an intermediate filter layer) were investigated. Pore pressure was measured across the soil depth. The experiments show that the soil liquefaction depended mainly on two parameters: the packing density of stones, and the number of stone layers. When the liquefaction occurs, stones sink in the soil. Mechanisms of liquefaction and sinking are described, and practical guidelines are recommended.     

Local effects of blue mussels around turbine foundations in an ecosystem model of Nysted off-shore wind farm, Denmark

The development of off-shore wind farms along the coastline of north-west Europe is rapidly increasing; it is therefore important to study how this will affect the marine environment. The present study modelled the growth and feed-backs of blue mussels in natural beds and on turbine foundations in an off-shore wind farm (OWF) located in a shallow coastal ecosystem by coupling a dynamic energy budget (DEB) model to a small-scale 3D hydrodynamic–biogeochemical model. The model results showed that blue mussels located higher up in the water column on turbine pillars achieved a 7–18 times higher biomass than those located on the scour protection because the former experience an enhanced advective food supply. Secondly, the high biomasses of blue mussels on foundations created local ‘hot spots’ of biological activity and changed ecosystem dynamics due to their feed-backs e.g. ingestion of microplankton and copepods, excretion of ammonium and egestion of faecal pellets. The model results were supported by field measurements around foundations of Chl a concentrations and biomasses of the fauna community. Our study emphasised that OWFs seem to be particularly favourable for blue mussels in the western Baltic Sea and that the functioning of the OWFs as artificial reef ecosystems depends upon how the blue mussels interact with their local pelagic and benthic environment.     

Methane in the southern North Sea: Sources, spatial distribution and budgets

Measurements of methane (CH₄) so far have always shown supersaturation in the entire North Sea relative to the atmospheric partial pressure and the distribution of surface CH₄ reveals a distinct increase towards the shore. Since North Sea sediments presumably are an insignificant source for CH₄ the coastal contribution via rivers and tidal flats gains in importance.In this work, CH₄ data from the River Weser, the back barrier tidal flats of Spiekeroog Island (NW Germany), and the German Bight are presented. Results from the River Weser are compared to other rivers draining into the German Bight. Measurements in the tidal flat area of Spiekeroog Island highlight this ecosystem as an additional contributor to the overall CH₄ budget of the southern North Sea. A tidally driven CH₄ pattern is observed for the water column with maximum values during low tide. Tidal flat sediments turn out to be the dominating source because pore waters discharged during low tide are highly enriched in CH₄. In contrast, the freshwater contribution to the tidal flats by small coastal tributaries has almost no impact on water column CH₄ concentrations. The CH₄ level seems to be disturbed irregularly by wind forcing due to elevated degassing and prevention of advective flow when tidal flats remain covered by water.Based on our data, two model calculations were used to estimate the impact of tidal flats on the CH₄ budget in the German Bight. Our results demonstrate that the back barrier tidal flats of the east Frisian Wadden Sea contribute CH₄ in an order of magnitude between the Wash estuary and River Elbe and thus have to be considered in budget calculations.     

Amplitude of ENSO cycles in the Santa Barbara Basin,off California,during the past 15 000 years

Varve thickness time series from ODP Site 893 in the Santa Barbara Basin (off California) were analysed to determine variation in the strength of El Niño/Southern Oscillation (ENSO) cycles during the past 15 000 yr. Mean varve thickness and variance changed over time, with thicker varves before ～8000 yr BP indicative of wetter than modern climates. A 100‐yr running standardisation was applied to correct for non‐stationarity. The contribution of ENSO‐scale variability was then estimated as the amplitude of 3–8 year bandpassed data. Results show multidecadal‐ to centennial‐scale modulation of the amplitude. On average, however, the amplitude of ENSO scale variability remained constant throughout the past 15 000 yr. We therefore conclude that, although the expression of ENSO cycles may have changed during the Holocene, there is no indication for a significant change in amplitude of interannual variability. Copyright © 2005 John Wiley & Sons, Ltd.