Characterization of accumulated precipitates during subsurface iron removal

The principle of subsurface iron removal for drinking water supply is that aerated water is periodically injected into the aquifer through a tube well. On its way into the aquifer, the injected O₂-rich water oxidizes adsorbed Fe²⁺, creating a subsurface oxidation zone. When groundwater abstraction is resumed, the soluble Fe²⁺ is adsorbed and water with reduced Fe concentrations is abstracted for multiple volumes of the injection water. In this article, Fe accumulation deposits in the aquifer near subsurface treatment wells were identified and characterized to assess the sustainability of subsurface iron removal regarding clogging of the aquifer and the potential co-accumulation of other groundwater constituents, such as As. Chemical extraction of soil samples, with Acid-Oxalate and HNO₃, showed that Fe had accumulated at specific depths near subsurface iron removal wells after 12 years of operation. Whether it was due to preferred flow paths or geochemical mineralogy conditions; subsurface iron removal clearly favoured certain soil layers. The total Fe content increased between 11.5 and 390.8 mmol/kg ds in the affected soil layers, and the accumulated Fe was found to be 56-100% crystalline. These results suggest that precipitated amorphous Fe hydroxides have transformed to Fe hydroxides of higher crystallinity. These crystalline, compact Fe hydroxides have not noticeably clogged the investigated well and/or aquifer between 1996 and 2008. The subsurface iron removal wells even need less frequent rehabilitation, as drawdown increases more slowly than in normal production wells. Other groundwater constituents, such as Mn, As and Sr were found to co-accumulate with Fe. Acid extraction and ESEM-EDX showed that Ca occurred together with Fe and by X-ray Powder Diffraction it was identified as calcite.     

Determination of chemical weathering rates from U series nuclides in soils and weathering profiles: Principles,applications and limitations

The development of U-series nuclides for investigating weathering processes has been significantly stimulated by the analytical improvement made over the last decades in measuring the ²³⁸U series with intermediate half-lives (i.e., ²³⁴U–²³⁰Th–²²⁶Ra). It is proposed in this paper to present principles and methods that are now being developed to determine weathering rates from the study of U-series nuclides in soils and weathering profiles. Mathematical approaches, developed to calculate such rates, are based on some implicit assumptions that are also presented and must be kept in mind if one wants to correctly interpret the obtained ages.     

Advances towards improved low-frequency tree-ring reconstructions, using an updated Pinus sylvestris L. MXD network from the Scandinavian Mountains

The dendrochronological use of the parameter maximum density (MXD) in Pinus Sylvestris L., at high latitudes, has provided valuable insights into past summer temperature variations. Few long MXD chronologies, from climatically coherent regions, exist today, with the exception being in northern Europe. Five, 500-year-long, Fennoscandian, MXD chronologies were compared with regard to their common variability and climate sensitivity. They were used to test Signal-free standardization techniques, to improve inferences of low-frequency temperature variations. Climate analysis showed that, in accordance with previous studies on MXD in Fennoscandia, the summer temperature signal is robust (R ²?>?50 %) and reliable over this climatically coherent region. A combination of Individual standardization and regional curve standardization is recommended to refine long-term variability from these MXD chronologies and relieve problems arising from low replication and standardization end-effects.     

On the efficiency of horizontal diffusion and numerical filtering in an Arakawa‐type model

Abstract

In a series of 5‐day forecasts with a 3‐layer/2.8° hemispheric model, horizontal diffusion schemes of the second and fourth degree are compared with a numericalfilter technique. The results, which are discussed mainly in terms of spectral energetics in zonal wavenumber space, indicate that fourth‐degree diffusion is more scale selective than second‐degree and equivalent to filtering. The seventh‐order filter applied only intermittently to the prognostic variables is superior to fourth‐degree diffusion from the viewpoint of computational economy. Excessive dissipation of the long waves may inhibit the production of eddy kinetic energy from eddy available potential energy.     

Influence from Surrounding Land on the Turbulence Measurements Above a Lake

Turbulence measurements taken at a Swedish lake are analyzed. Although the measurements took place over a relatively large lake with several km of undisturbed fetch, the turbulence structure was found to be highly influenced by the surrounding land during daytime. Variance spectra of both horizontal velocity and scalars during both unstable and stable stratification displayed a low frequency peak. The energy at lower frequencies showed a daily variation, increasing in the morning and decreasing in the afternoon. This behaviour is explained by spectral lag, where the low frequency energy due to large eddies that originate from the convective boundary layer above the surrounding land. When the air is advected over the lake the small eddies rapidly equilibrate with the new surface forcing. However, the large eddies remain for an appreciable distance and influence the turbulence in the developing lake boundary layer. The variances of the horizontal velocity and scalars are increased by these large eddies, while the turbulent fluxes are mainly unaffected. The drag coefficient, Stanton number and Dalton number used to parametrize the momentum flux, heat flux and latent heat flux respectively all compare well with current parametrizations developed for open sea conditions. The diurnal cycle of the partial pressure of methane, $p\mathrm{CH}_{4}$ , observed at this site is closely related to the diurnal cycle of the lake-air methane flux. An idealized two-dimensional model simulation of the boundary layer at a lake site indicates that the strong response of $p\mathrm{CH}_{4}$ to the surface methane flux is due to the shallow internal boundary layer that develops above the lake, allowing methane to accumulate in a relatively small volume.     

Comment on “Trends and low frequency variability of extra-tropical cyclone activity in the ensemble of twentieth century reanalysis” by Xiaolan L. Wang,Y. Feng,G. P. Compo,V. R. Swail,F. W. Zwiers,R. J. Allan,and P. D. Sardeshmukh,Climate Dynamics, 2012

The main subject of this article is to comment on the issue of storminess trends derived from the twentieth century reanalysis (20CR) and from observations in the North Atlantic region written about in Wang et al. (Clim Dyn 40(11–12):2775–2800, 2012). The statement that the 20CR estimates would be consistent with storminess derived from pressure-based proxies does not hold for the time prior to 1950.     

Weibull-k Revisited: “Tall” Profiles and Height Variation of Wind Statistics

The Weibull distribution is commonly used to describe climatological wind-speed distributions in the atmospheric boundary layer. While vertical profiles of mean wind speed in the atmospheric boundary layer have received significant attention, the variation of the shape of the wind distribution with height is less understood. Previously we derived a probabilistic model based on similarity theory for calculating the effects of stability and planetary boundary-layer depth upon long-term mean wind profiles. However, some applications (e.g. wind energy estimation) require the Weibull shape parameter (k), as well as mean wind speed. Towards the aim of improving predictions of the Weibull- \(k\) profile, we develop expressions for the profile of long-term variance of wind speed, including a method extending our probabilistic wind-profile theory; together these two profiles lead to a profile of Weibull-shape parameter. Further, an alternate model for the vertical profile of Weibull shape parameter is made, improving upon a basis set forth by Wieringa (Boundary-Layer Meteorol, 1989, Vol. 47, 85–110), and connecting with a newly-corrected corollary of the perturbed geostrophic-drag theory of Troen and Petersen (European Wind Atlas, 1989, Risø National Laboratory, Roskilde). Comparing the models for Weibull-k profiles, a new interpretation and explanation is given for the vertical variation of the shape of wind-speed distributions. Results of the modelling are shown for a number of sites, with a discussion of the models’ efficacy and applicability. The latter includes a comparative evaluation of Wieringa-type empirical models and perturbed-geostrophic forms with regard to surface-layer behaviour, as well as for heights where climatological wind-speed variability is not dominated by surface effects.     

Innovating the IPCC review process—the potential of young talent

There is significant potential in young talent for enhancing the credibility of the scientific assessments such as the IPCC’s by contributing to quality assurance and quality control. In this essay, we reflect on an experiment that was done by the Dutch government as part of its government review of a contribution to the IPCC’s Fifth Assessment Report (AR5). In an effort to review the entire Working Group II contribution to the AR5 within the official review period for the Second Order Draft (SOD), the PBL Netherlands Environmental Assessment Agency turned to PhD students. This article shows that a systematic review focusing on transparency and errors of a large scientific assessment document using young talented scientists can be successful if certain conditions are met. The reviewers need to have intrinsic motivation to conduct the review. There needs to be a communication plan that fosters engagement and a clear methodology to guide the reviewers through their task. Based on this experiment in review, we reflect on the wider potential for openness and crowdsourcing in scientific assessment processes such as the IPCC’s.     

Early Last Interglacial Greenland Ice Sheet melting and a sustained period of meridional overturning weakening: a model analysis of the uncertainties

Proxy-data suggest that the Last Interglacial (LIG; ~130–116 ka BP) climate was characterized by higher temperatures, a partially melted Greenland Ice Sheet (GIS) and a changed Atlantic meridional overturning circulation (AMOC). Notwithstanding the uncertainties in LIG palaeoclimatic reconstructions, this setting potentially provides an opportunity to evaluate the relation between GIS melt and the AMOC as simulated by climate models. However, first we need to assess the extent to which a causal relation between early LIG GIS melt and the weakened AMOC is plausible. With a series of transient LIG climate simulations with the LOVECLIM earth system model, we quantify the importance of the major known uncertainties involved in early LIG GIS melt scenarios. Based on this we construct a specific scenario that is within the parameter space of uncertainties and show that it is physically consistent that early LIG GIS melting kept the AMOC weakened. Notwithstanding, this scenario is at the extreme end of the parameter space. Assuming that proxy-based reconstructions of early LIG AMOC weakening offer a realistic representation of its past state, this indicates that either (1) the AMOC weakening was caused by other forcings than early LIG GIS melt or (2) the early LIG AMOC was less stable than indicated by our simulations and a small amount of GIS melt was sufficient to keep the AMOC in the weak state of a bi-stable regime. We argue that more intensive research is required because of the high potential of the early LIG to evaluate model performance in relation to the AMOC response to GIS melt.     

A double slip non-coaxial flow rule for viscous-plastic Cosserat materials

We propose a double slip non-coaxial plastic model within the framework of a Cosserat continuum theory. In a Cosserat continuum, a material point possesses the degrees of freedom of an infinitesimal rigid body: two translations and one rotation in 2D. We formulate the plastic model into viscous-plastic constitutive relationships and illustrate the viscous-plastic behaviour of the model by means of numerical solution of a simple shear problem.