Water source characterization through spatiotemporal patterns of major,minor and trace element stream concentrations in a complex,mesoscale German catchment

The link between spatiotemporal patterns of stream water chemistry and catchment characteristics for the mesoscale Dill catchment (692 km²) in Germany is explored to assess the catchment scale controls on water quality and to characterize water sources. In order to record the spatiotemporal pattern, ‘snapshot sampling’ was applied during low, mean and high flow, including 73 nested sites throughout the catchment. Water samples were analysed for the elements Li, B, Na, Mg, Al, K, Ca, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Rb, Sr, Mo, Ba, Pb and U using inductively‐coupled‐plasma mass spectrometry, and for electric conductivity and pH. Principle component analysis and hierarchical cluster analysis were used to find typical element associations and to group water samples according to their hydrochemical fingerprints. This revealed regional hydrochemical patterns of water quality which were subsequently related to catchment attributes to draw conclusions about the controls on stream chemistry. It was found that various lithologic signals and anthropogenic point source inputs controlled the base flow hydrochemistry. During increased flows, stream waters were diluted causing additional hydrochemical variability in response to heterogeneous precipitation inputs and differences in aquifer storage capacities. The hydrochemical patterns further displayed in‐stream mixing of waters. This implied, that stream waters could be apportioned to the identified water sources throughout the catchment. The basin‐wide hydrochemical variability has the potential to outrange the tracer signatures typically inferred in studies at the hillslope scale and is able to strongly influence the complexity of the catchment output. Both have to be considered for further catchment scale tracer and modelling work. Despite the likelihood of non‐conservative behaviour, the minor and trace elements enhanced the rather qualitative discrimination of the various groundwater types, as the major cations were strongly masked by point source inputs. Copyright © 2007 John Wiley & Sons, Ltd.     

δ13C signature of early graphite and subsequently formed microdiamond from the Saxonian Erzgebirge,Germany

Microdiamond and graphite occur in quartzofeldspathic rocks (saidenbachites) of the central Erzgebirge in Saxony. Zircon from such rocks contains not only relatively high but also variable amounts of early formed graphite and later crystallized diamond, however no carbonate. Six purified zircon concentrates were analysed by mass spectrometry for δ₁₃C(PDB) values which were between −24 and −33‰. The carbon inclusions resulted in C contents of the concentrates as high as 0.5 wt%. It is hypothesized that the observed δ₁₃C signature results from organic material in the sedimentary protoliths of the saidenbachites probably deposited not earlier than Mid‐Devonian. This material was transformed to graphite during early metamorphism and subsequently to diamond after an anatectic event at great depths (>150 km). During these processes, the δ₁₃C signature of the carbon did not (significantly) change.     

U-series disequilibria in suspended river sediments and implication for sediment transfer time in alluvial plains: The case of the Himalayan rivers

²³⁸U-²³⁴U-²³⁰Th radioactive disequilibria were analyzed in suspended sediments (collected at different depths) from the Ganges River and one of its main tributaries: the Narayani-Gandak River. Results associated with bedload sediment data suggest that uranium-series (U-series) disequilibria in river sediments of the Ganges basin vary with grain size and sampling location. The range of observed U-series disequilibria is explained by a mixing model between a coarse-grained sediment end-member, represented by bedload and bank sediments, and a fine-grained end-member that both originate from Himalaya but undergo different transfer histories within the plain. The coarse-grained sediment end-member transits slowly (i.e. >several 100’s ky) in the plain whereas the fine-grained sediment end-member is transferred much faster (<20-25 ky), as indicated by the absence of significant variations in Th isotope composition of the fine-grained sediment end-members. These results show that U-series isotopes can be used to quantify the various transfer times of river sediments of different sizes and infer that there can be an order of magnitude of difference, or more, between the transfer time of suspended and bedload sediments. This underlines that a good knowledge of the proportion of suspended vs. bedload sediments transported in the river is required to accurately assess how fast erosion products are transferred in a catchment and how fast a catchment is likely to respond to external forcing factors.     

Main Species Characteristics of Phytoplankton Spring Blooms in NE Atlantic and Arctic Waters (68–80° N)

A compilation of phytoplankton species abundance data from the spring bloom along the northern Norwegian coast and in the Barents Sea shows that the quantitatively most important species are the prymnesiophyte Phaeocystis pouchetii and the common cold water to temperate diatoms Chaetoceros socialis, Skeletonema costatum sensu lato, Fragilariopsis oceanica, Thalassiosira spp., Chaetoceros furcellatus, Chaetoceros compressus, Chaetoceros debilis and Bacterosira bathyomphala. The relative abundance of diatoms and Phaeocystis varied highly and apparently stochastically between years. P. pouchetii occurred during all stages of the spring bloom and sometimes completely dominated the phytoplankton community. Along the Norwegian coast, the importance of P. pouchetii increased northwards. The species composition in coastal fjords at 70° N is surprisingly similar to that of shelf waters in the Barents Sea (up to 80° N). An exception is S. costatum sensu lato which was seldom observed in Arctic waters. Small flagellates (<10 μm) other than dinoflagellates and P. pouchetii are also important among the Barents Sea spring phytoplankton. Associations of species seem rigid over time and are dominated by C. socialis and P. pouchetii in northern waters. Biogeographical categories of spring bloom species in relation to environmental conditions are discussed.     

The “Boscobel Landslip” of October 1st, 1901—the largest historic landslide in Barbados,West Indies

Barbados is a small Caribbean island located on the crest of an accretionary prism about 125 km east of the Lesser Antilles volcanic island arc. The oldest strata, Eocene sandstones and shales, are overlain by Oligocene–Miocene chalks and marls, in turn overlain by Pleistocene reef and lagoonal limestones that cover about 85 % of the island. The Eocene sediments, which crop out in the Scotland District of Barbados, are prone to soil creep and landslides covering tens to hundreds of hectares. The largest historic landslide, the “Boscobel Landslip,” occurred on 01 October 1901. We used nineteenth-century and more modern topographic and geologic maps, air photographs, and various archival and petrophysical data, to supplement reconnaissance of the landslide in the field. We identified about ten million cubic meters of the displaced material of the landslide, as well as the meteorological and geological conditions that contributed to the Boscobel Landslip. Similar landslides would pose a presently unquantified hazard to inhabitation and future development in the Scotland District.     

Efficient block preconditioners for the coupled equations of pressure and deformation in highly discontinuous media

Large‐scale simulations of flow in deformable porous media require efficient iterative methods for solving the involved systems of linear algebraic equations. Construction of efficient iterative methods is particularly challenging in problems with large jumps in material properties, which is often the case in geological applications, such as basin evolution at regional scales. The success of iterative methods for this type of problems depends strongly on finding effective preconditioners. This paper investigates how the block‐structured matrix system arising from single‐phase flow in elastic porous media should be preconditioned, in particular for highly discontinuous permeability and significant jumps in elastic properties. The most promising preconditioner combines algebraic multigrid with a Schur complement‐based exact block decomposition. The paper compares numerous block preconditioners with the aim of providing guidelines on how to formulate efficient preconditioners. Copyright © 2010 John Wiley & Sons, Ltd.     

Simulating stochastically excited oscillations: The mode lifetime of ξ Hya

The discovery of solar-like oscillations in the giant star ξ Hya (G7 III) was reported by Frandsen et al. (2002). Their frequency analysis was very limited due to alias problems in the data set (caused by single-site observations). The extent to which the aliasing affected their analysis was unclear due to the unknown damping time of the stellar oscillation modes. In this paper we describe a simulator created to generate time series of stochastically excited oscillations, which takes as input an arbitrary window function and includes both white and non-white noise. We also outline a new method to compare a large number of simulated time series with an observed time series to determine the damping time, amplitude, and limited information on the degree of the stochastically excited modes. For ξ Hya we find the most likely amplitude to be ∼ 2 m s⁻¹, in good agreement with theory (Houdek and Gough, 2002), and the most likely damping time to be ∼ 2 days, which is much shorter than the theoretical value of 15–20 days calculated by Houdek and Gough (2002).     

The influence of central black holes on gravitational lenses

Recent observations indicate that many if not all galaxies host massive central black holes. In this paper we explore the influence of black holes on the lensing properties. We model the lens as an isothermal ellipsoid with a finite core radius plus a central black hole. We show that the presence of the black hole substantially changes the critical curves and caustics. If the black hole mass is above a critical value, then it will completely suppress the central images for all source positions. Realistic central black holes are likely to have masses below this critical value. Even in such subcritical cases, the black hole can suppress the central image when the source is inside a zone of influence, which depends on the core radius and black hole mass. In the subcritical cases, an additional image may be created by the black hole in some regions, which for some radio lenses may be detectable with high-resolution and large dynamic range VLBI maps. The presence of central black holes should also be taken into account when one constrains the core radius from the lack of central images in gravitational lenses.