Ammonium Silicate Stability Relations

A method has been developed to control ammonium fugacity, \(f_{{\text{NH}}_{3}}\), at elevated temperatures and pressures. The method uses an internal nitrogen buffer, the assemblage Cr + CrN, in conjunction with a traditional external hydrogen buffer. In this manner, all gas fugacities in the system N-O-H can be calculated.The Cr + CrN buffer has been applied to study equilibria between buddingtonite (ammonium feldspar), ammonium muscovite, sillimanite, and quartz at a constant gas pressure of 2,000 bars. Two of the five relevant reactions were measured experimentally; from these data, it is possible to calculate isothermal sections at 500, 600, and 700° C.Below 600° C, ammonium muscovite is stable even at extremely low levels of \(f_{{\text{NH}}_{3}}\), while buddingtonite requires \(f_{{\text{NH}}_{3}}\;\geqq\;10^4\) bars. Release of NH₃ during progressive metamorphism can be achieved by three processes: thermal decomposition, dehydration, and cation exchange. Within the crust, \(f_{{\text{NH}}_{3}}\) predominates over \(f_{{\text{N}}_{2}}\) by several orders of magnitude; but on the surface, nitrogen released as NH₃ by metamorphism will be oxidized to N₂. Biological materials provide important intermediate storage for nitrogen compounds during the nitrogen cycle.     

Sampling Fauna in Stream Sediments as well as Groundwater Using One Net Sampler

Groundwater bores act as traps. Net samplers are regularly used for sampling this type of trap for fauna. To enable direct comparisons of faunal communities in groundwater bores and stream sediments, stream sediment tubes were built similar to groundwater bores and were sampled with net samplers for fauna. These stream sediment tubes consisted of a tube anchored in the stream sediment, also called interstitial space. To test the efficacy of this trap method in stream sediments, it was compared to another type of trap, Hahn's trap. Faunal communities sampled by a net in the stream sediment tubes did not differ hugely from fauna in Hahn's trap samples. Physical and chemical factors of sampled water in both the stream sediment tubes, the surrounding interstitial sediments and the second type of traps, Hahn's traps, showed that water in both the tubes and Hahn's traps was closely related to interstitial water. The net sampler is inexpensive and easy to handle. It is suggested that sampling stream tubes with nets may be an appropriate method for long‐term monitoring studies.     

The changing relationship between state and church/religion in the Netherlands

The Netherlands is part of the historic Northwest-Southeast multi-confessional culture belt according to the comparative framework of church-state relations in Europe as recently developed by Madeley on the basis of Rokkan’s conceptual map. The aim of this paper is to describe the development of the church-state relations in the Netherlands within this historic framework of state-formation and nation-building, and to interpret recent challenges of its historic state-church model, such as secularisation, the rise of immigrant religions, and general ‘de- and re-territorialisation’ tendencies. The Netherlands developed from a relatively very tolerant polity dominated by the Calvinist Church to a ‘pillarised’ society, in which the Rome-Reformation divide (which also had a strong geographical dimension) was institutionalised in the political system. After the 1960s, very strong secularisation put this ‘pillarised’ system under severe pressure, but the remnants of this system offered a favourable opportunity structure for religious newcomers (Muslims in particular), who could establish their mosques and Muslim schools relatively easily. However, while the main Protestant churches, and even Catholic and Protestant political parties have merged, failing integration of these newcomers in Dutch society and terrorist attacks at the global level as well as in the Netherlands encouraged a new divide between Muslims and non-Muslims. The metropolitan areas in particular became the scene of this new divide.     

A multiscaling‐based intensity–duration–frequency model for extreme precipitation

Rainfall intensity–duration–frequency (IDF) curves are a standard tool in urban water resources engineering and management. They express how return levels of extreme rainfall intensity vary with duration. The simple scaling property of extreme rainfall intensity, with respect to duration, determines the form of IDF relationships. It is supposed that the annual maximum intensity follows the generalized extreme value (GEV) distribution. As well known, for simple scaling processes, the location parameter and scale parameter of the GEV distribution obey a power law with the same exponent. Although, the simple scaling hypothesis is commonly used as a suitable working assumption, the multiscaling approach provides a more general framework. We present a new IDF relationship that has been formulated on the basis of the multiscaling property. It turns out that the GEV parameters (location and scale) have a different scaling exponent. Next, we apply a Bayesian framework to estimate the multiscaling GEV model and to choose the most appropriate model. It is shown that the model performance increases when using the multiscaling approach. The new model for IDF curves reproduces the data very well and has a reasonable degree of complexity without overfitting on the data.     

ON THE DETERMINATION OF THE ROUGHNESS COEFFICIENT IN NATURAL AND ARTIFICIAL WATERWAYS

SYNOPSIS

It has always been a problem for the hydraulic engineer to obtain reasonable values for the roughness in a waterway. The writer feels that the idea put forward in this essay could help the parcticing engineer to obtain a roughness value without complicated procedure.     

Comparison of abstraction scenarios simulated by SWAT and SWAT-MODFLOW

In hydrological modelling of catchments, wherein streams are groundwater-fed, an accurate representation of groundwater processes and their interaction with surface water is crucial. With this purpose, a coupled model was recently developed linking SWAT (Soil and Water Assessment Tool) with the fully-distributed groundwater model MODFLOW (Modular Groundwater Flow). In this study, SWAT and SWAT-MODFLOW were applied to a Danish groundwater-dominant catchment, simulating groundwater abstraction scenarios and assessing the benefits and drawbacks of SWAT-MODFLOW. Both models demonstrated good performance. However, SWAT-MODFLOW provided more realistic outputs when simulating abstraction: the decrease in streamflow was similar to the volume of water abstracted, while in SWAT the impact was negligible. SWAT also showed impacts on streamflow only when abstractions were taken from the shallow aquifer, not from the deep aquifer. Overall, SWAT-MODFLOW demonstrated wider possibilities for groundwater analysis, providing more insights than SWAT in supporting decision making in relation to environmental assessment.     

Spectra of poorly resolved ocean data

Standard temperature and pressure sensors on Aanderaa RCM8 current meters have a resolution of 0.024 °C and 0.6 bar, each equal to 1 digital number (value) over a range of 1024. It is shown that an 11-month deep-ocean temperature record using only four values can contain useful spectral information on internal wave motions. This is partially due to the modulation of high-frequency data by non-zero low-frequency (subinertial) variations. This result follows from the comparison of this record with artificial three- and four-value data constructed from temperature records observed in stronger stratified waters nearby. These artificial records show main features of the internal wave band similar to those observed in the original data spectra. Peaks at tidal harmonic frequencies and enhancements at sum-tidal-inertial interaction frequencies are preserved in the artificial data, but overall noise level (and thus the continuum spectral slope) is enhanced with respect to the properly resolved records (using 15 and 100 values). As a demonstration of the stable accuracy of the temperature sensors, the poorly resolved records provided an estimate of mean stratification to within 5% of the estimate using Seabird CTD data.Responsible Editor: Hans Burchard     

Holocene peatland development and hydrological variability inferred from bog‐pine dendrochronology and peat stratigraphy – a case study from southern Sweden

Dendrochronological analysis was applied to subfossil remains of Scots pine (Pinus sylvestris L.) buried in a South Swedish peat deposit. In combination with peat stratigraphy, this approach was explored for its potential to provide information on the local hydrological and depositional history at the site, forming the basis for a regional palaeohydrological analysis. A 726‐year ring‐width chronology was developed and assigned an absolute age of 7233–6508 cal a BP (5284–4559 BC) through cross‐dating with German bog‐pine chronologies, whereas two short additional records of older ages were radiocarbon dated. Registration of growth positions of individual trees allowed assessment of the spatial dynamics of the pine population in response to hydrological changes and peatland ontogeny. Annually resolved growth variability patterns in the pine population reveal several establishment and degeneration phases, probably reflecting fluctuations in bog‐surface wetness. A major establishment phase at 7200–6900 cal a BP reflects the onset of a period of lowered groundwater level, also indicated by increased peat humification, and a development consistent with regional temperature and lake level reconstructions revealed from other proxies. This study demonstrates that subfossil bog‐pine populations may provide annually to decadally resolved reconstructions of local groundwater variability, which are highly relevant in a long‐term palaeoclimatic context. Copyright © 2012 John Wiley & Sons, Ltd.