Eo-Alpine Metamorphism in the Uppermost Unit of the Cretan Nappe System — Petrology and Geochronology

The uppermost unit of the Cretan nappe system contains a variegated series of high-grade metamorphic rocks. In the Léndas area, amphibolites are present characterized by the assemblage

$$\text{brown}\;\text{hornblende}\;+\;\text{diopside}\;+\;\text{plagioclase}\;\text{(An 50)}$$

while associated metapelitic gneisses consist of

$$\text{garnet}\;+\;\text{cordierite}\;+\;\text{biotite}\;+\;\text{sillimanite (andalusite)}\;\pm\;\text{K-feldspar}\;+\;\text{plagioclase (An 40-50)}\;+\;\text{quartz}.$$

Judging from relevant experimental data for the gneiss assemblage including the Fe/Mg distribution on coexisting garnet and cordierite, the P-T conditions of metamorphism are estimated at about 700° C and 5 kb water vapour pressure.K/Ar determinations on hornblendes from three amphibolites yielded cooling ages of 71.3, 71.2, and 71.1 (±1.7) m.y. respectively; biotites from three paragneisses gave 70.2 ± 1.4, 69.7 ± 1.2, and 67.9 ± 1.4 m.y. respectively. Assuming a sealing temperature against argon diffusion of 300° C, for biotite, and 500° C, for hornblende, a cooling rate of 100–200° C/m.y. is calculated. Thus a late Cretaceous (eo-Alpine) metamorphic event is established in the post-Cretaceous nappes of Crete.     

A regional 8200 cal. yr BP cooling event in northwest Europe,induced by final stages of the Laurentide ice-sheet deglaciation?

The most notable change in δ¹⁸O in Greenland ice cores during the Holocene occurs at 8200 cal. yr BP. Here we present a new high-resolution marine record from the northern North Sea, along with tree-ring data from Germany, which contain evidence of a pronounced temperature drop (>2°C) contemporaneous with that of the Greenland ice-core records. The synchronous timing of the cooling event in the Greenland ice-cores, marine record and tree-ring data from northwest Europe reflects a regional influence on the North Atlantic ocean–atmospheric system, suggesting a prominent role of the North Atlantic thermohaline circulation. The operation of the North Atlantic ocean circulation is sensitive to variation in the freshwater budget, implying that any change in freshwater flux is capable of altering the North Atlantic circulation system. We hypothesise minor but long-term freshwater fluxes in the final stages of the deglaciation of the Laurentide ice-sheet as a forcing mechanism. © 1998 John Wiley & Sons, Ltd.     

Comparing the adaptive Gaussian mixture filter with the ensemble Kalman filter on synthetic reservoir models

Over the last years, the ensemble Kalman filter (EnKF) has become a very popular tool for history matching petroleum reservoirs. EnKF is an alternative to more traditional history matching techniques as it is computationally fast and easy to implement. Instead of seeking one best model estimate, EnKF is a Monte Carlo method that represents the solution with an ensemble of state vectors. Lately, several ensemble-based methods have been proposed to improve upon the solution produced by EnKF. In this paper, we compare EnKF with one of the most recently proposed methods, the adaptive Gaussian mixture filter (AGM), on a 2D synthetic reservoir and the Punq-S3 test case. AGM was introduced to loosen up the requirement of a Gaussian prior distribution as implicitly formulated in EnKF. By combining ideas from particle filters with EnKF, AGM extends the low-rank kernel particle Kalman filter. The simulation study shows that while both methods match the historical data well, AGM is better at preserving the geostatistics of the prior distribution. Further, AGM also produces estimated fields that have a higher empirical correlation with the reference field than the corresponding fields obtained with EnKF.     

The role of intracontinental deformation in supercontinent assembly: insights from the Ribeira Belt,Southeastern Brazil (Neoproterozoic West Gondwana)

In this study, we challenge the multiple collision model for the tectonic evolution of the Neoproterozoic Ribeira Belt in Southeastern Brazil. New U–Pb SHRIMP data reveal Palaeoproterozoic (2153 ± 15 Ma) and Cryogenian (783 ± 6 and 768 ± 8 Ma) granitic rocks in the Embu Domain, and detrital zircon data of metasedimentary units from the Embu and Costeiro domains suggest a coherent tectonic evolution for the whole Ribeira Belt. Rather than by multiple collisions, these data are best explained by a simpler tectonic model involving continent (craton)‐volcanic arc collisions in the Dom Feliciano and Brasilia belts that led to intracontinental crustal thickening of the adjacent thinned hinterland (Ribeira Belt) at ~640–610 Ma, followed by widespread post‐collisional magmatism and rift‐related sedimentation at ~600–540 Ma. We suggest that intracontinental orogeny is a relevant process during supercontinent assembly, as illustrated here by the evolution of significant parts of the Brasiliano orogen.     

Late Devensian ice‐marginal features in the central North Sea – processes and chronology

Palaeoglaciological reconstructions of the North Sea sector of the last British Ice Sheet have, as other shelf areas, suffered from a lack of dates directly related to ice‐front positions. In the present study new high‐resolution TOPAS seismic data, bathymetric records and sediment core data from the Witch Ground Basin, central North Sea, were compiled. This compilation made it possible to map out three ice‐marginal positions, partly through identification of terminal moraines and partly through location of glacial‐fed debrisflows. The interfingering of the distal parts of the glacial‐fed debrisflows with continuous marine sedimentation enabled the development of a chronology for glacial events based on previously published and some new radiocarbon dates on marine molluscs and foraminifera. From these data it is suggested that after the central Witch Ground Basin was deglaciated at c. 27 cal. ka BP, the eastern part was inundated by glacial ice from the east in the Tampen advance at c. 21 cal. ka BP. Subsequently, the basin was inundated by ice from northeast during the Fladen 1 (c. 17.5 cal. ka BP) and the Fladen 2 (16.2 cal. ka BP) events. It should be emphasized that the Fladen 1 and 2 events, individually, may represent dynamics of relatively small lobes of glacial ice at the margin of the British Ice Sheet and that the climatic significance of these may be questioned. However, the Fladen Events probably correlate in time with the Clogher Head and Killard Point re‐advances previously documented from Ireland and the Bremanger event from off western Norway, suggesting that the British and Fennoscandian ice sheets both had major advances in their northwestern parts, close to the northwestern European seaboard, at this time.     

Der petrogenetische Werdegang der Klinopyroxene in den tertiären Vulkaniten der Hocheifel II. Die Klinopyroxene der Basanitoide

The course of crystallization of basalt forming clinopyroxenes in the olivine basalt-hawaiite-mugearite-trachyte series from the Hocheifel area (Western Germany) has been presented by the author in, an earlier paper (Huckenholz 1964, part I). The present paper deals with the evolution of clinopyroxenes from the basanitoid rocks in the same area. The basanitoids are richer in clinopyroxenes than the normal olivine basalts and may be a product of accumulation of clinopyroxenes in an olivine basalt magma.Mineral separation is very troublesome in fine-grained volcanic rocks but special procedures (as outlined in part I) allow chemical, optical and X-ray analyses of three generations of clinopyroxenes and of other basalt forming minerals. The first clinopyroxenes formed in the basanitoids is a greenish chromian salite Ca₄₅Mg₄₃Fe₁₂ which is preserved in the cores of the phenocrysts. Strongly zoned brown titansalite Ca₄₅Mg₄₁Fe₁₄ surrounds the chromian salite or appears in independent microphenocrysts. The groundmass clinopyroxene is a sodian titansalite Ca₄₆Mg₃₇Fe₁₇ with a small optic axial angle. In contrast to the olivine basalt-trachyte series the clinopyroxenes of the basanitoids are richer in titanium and aluminum.Phenocrysts of nickel-rich olivine Fe_14–16, relics of orthopyroxene Fs₁₄ and chrome spinell were formed together with the chromian clinopyroxene. The same minerals have been observed in the olivine basalts and hawaiites. This paragenesis indicates high pressure and high temperature in the alkali basalts of the Hocheifel during an initial stage of magmatic evolution. With the decrease of pressure mineral reactions occurred with the alkali basalt melt. The high pressure clinopyroxenes of the basanitoids were changed to a larger extent than the clinopyroxenes of the olivine basalts and hawaiites because they are in contact with the magma for a longer period of time. This favours the reaction between the solids and the melt, and the high pressure garnet and/or enstatite components in the elinopyroxenes are substituted by Ca-Tschermak's and titanaugite molecule.     

High-Pressure (~2000 MPa) Kyanite- and Glaucophane-bearing Pelitic Schist and Eclogite from Cordillera de la Costa Belt, Venezuela

Cretaceous melange of the Cordillera de la Costa belt, north–centralVenezuela, there are knockers of eclogite, barroisite-bearingeclogite, and pelitic glaucophane schist. These occur in a metamorphicmelange matrix that locally consists of marble, serpentinite,amphibolite, actinolite schist, feldspathic schist and gneiss,graphitic schist, chloritoid schist, and garnet-bearing micaschist. The protoliths for these various rock types exhibita wide age range (Cambrian to Early Cretaceous?). Recently discoveredknockers of pelitic glaucophane schist contain Mg-glaucophane+ paragonite + kyanite + garnet + talc + graphite + rutile +quartz. The coexistence of kyanite and Mg-glaucophane suggestsminimum P 2000 MPa at T > 600°C. Eclogite knockers fromthe same outcrop contain garnet and clinopyroxene which yield500°C for cores, 700°C for rims, and P 1200 MPa. Theassemblage garnet–biotite–phengite–albitewithin schists of the melange matrix of this locality indicatesmetamorphic conditions of T = 450–520°C at P = 1800MPa. Because all lithologies in this outcrop record high-P conditions,this metamorphic melange formed before or during peak metamorphismin a mid-Cretaceous subduction zone. KEY WORDS: geothermobarometry; high-P pelitic schist; eclogite; Puerto Cabello; Venezuela     

Über das Gleitvermögen der Glimmer

Ohne Zusammenfassung     

Monitoring strategies at phreatic wellfields: a 3D travel time approach

Ground water quality networks for monitoring phreatic drinking water wellfields are generally established for two main purposes: (1) the short-term safeguarding of public water supply and (2) signaling and predicting future quality changes in the extracted ground water. Six monitoring configurations with different well locations and different screen depths and lengths were evaluated using a numerical model of the 3D ground water flow toward a partially penetrating pumping well in a phreatic aquifer. Travel times and breakthrough curves for observation and pumping wells were used to judge the effectiveness of different design configurations for three monitoring objectives: (1) early warning; (2) prediction of future quality changes; and (3) evaluation of protection measures inside a protection zone. Effectiveness was tested for scenarios with advective transport, first-order degradation, and linear sorption. It is shown that the location and especially the depth of the observation wells should be carefully chosen, taking into account the residence time from the surface to the observation well, the residual transit times to the extraction well, and the transformation and retardation rates. Shallow monitoring was most functional for a variety of objectives and conditions. The larger the degradation rates or retardation, the shallower should the monitoring be for effective early warning and prediction of future ground water quality. The general approach followed in the current study is applicable for many geohydrological situations, tuning specific monitoring objectives with residence times and residual transit times obtained from a site-specific ground water flow model.