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31.
Anders Moberg Hans Bergström Josefin Ruiz Krigsman Ola Svanered 《Climatic change》2002,53(1-3):171-212
Daily meteorological observations have been made at the old astronomical observatory in Stockholm since 1754. Complete daily mean series of air temperature and sea level pressure are reconstructed from the observational data for 1756–1998. The temperature and pressure series arereconstructed and homogenized with the aid of metadata, statistical tests and comparisons with data from other stations. Comparisons with independently reconstructed daily series for nearby Uppsala (1722–1998) show that the quality of thedaily Stockholm data is good, although the reliability is lower before the mid-19th century. The daily temperature data show that the colder winter mean temperatures of the late 18th to early 19th centuries were connected with a particularly high frequency of very cold winter days. The warmer summers of the same period are more connected with a general shift of the temperature distribution towards higher temperatures than in the late 20th century. 相似文献
32.
Christoph Gaedicke Hans-Ulrich Schlüter Hans Albert Roeser Alexander Prexl Bernd Schreckenberger Heinrich Meyer Christian Reichert Peter Clift Shahid Amjad 《Tectonophysics》2002,355(1-4)
The nature and origin of the sediments and crust of the Murray Ridge System and northern Indus Fan are discussed. The uppermost unit consists of Middle Miocene to recent channel–levee complexes typical of submarine fans. This unit is underlain by a second unit composed of hemipelagic to pelagic sediments deposited during the drift phase after the break-up of India–Seychelles–Africa. A predrift sequence of assumed Mesozoic age occurring only as observed above basement ridges is composed of highly consolidated rocks. Different types of the acoustic basement were detected, which reflection seismic pattern, magnetic anomalies and gravity field modeling indicate to be of continental character. The continental crust is extremely thinned in the northern Indus Fan, lacking a typical block-faulted structure. The Indian continent–ocean transition is marked on single MCS profiles by sequences of seaward-dipping reflectors (SDR). In the northwestern Arabian Sea, the Indian plate margin is characterized by several phases of volcanism and deformation revealed from interpretation of multichannel seismic profiles and magnetic anomalies. From this study, thinned continental crust spreads between the northern Murray Ridge System and India underneath the northern Indus Fan. 相似文献
33.
Geochemistry and sequence stratigraphy of regional Upper Cretaceous limestone units, offshore eastern Canada 总被引:1,自引:0,他引:1
Hydrocarbons occur in two regional, Upper Cretaceous limestone units—the Turonian-Coniacian Petrel Member, and the Santonian-Maastrichtian Wyandot Formation. The units form important seismic markers beneath the Scotian Shelf and the Grand Banks of Eastern Canada. They mainly consist of bioturbated chalk and minor amounts of calcareous mudstone. A search for source rock using the Δ log R technique showed intervals with source potential, but testing of core and cuttings by Rock-Eval analysis showed no source potential. Three issues are the main cause for the inconsistency: (1) unconsolidated shales that likely included organic material were lost during sample washing; (2) severe contamination by mud additives; and (3) presence of gas. The organic matter found on the shelf has been strongly oxidised, but the distal facies of these limestone units and condensed shale units above and below may yet have potential to form source rock, beyond the studied areas. 相似文献
34.
In this paper it is argued that the re-establishment of a metropolitan government in the Greater Copenhagen Area in 2000 (Greater
Copenhagen Authority) is not to be seen as a return to the kind of regional, coordinative authority (Greater Copenhagen Council)
that was abolished in the Thatcherite climate of the 1980s. Throughout the 1980s and 1990s new forms of urban governance,
entrepreneurialism and a higher national priority to the capital region were introduced, which changed the conditions under
which the new metropolitan government is operating. This `contextualization' of the analysis of the two generations of metropolitan
government points to the fact that typologies of metropolitan government, such as the one put forward by Sharpe (1995), often
lacks analytical cogency.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
35.
Water solubility in orthopyroxene 总被引:7,自引:0,他引:7
The solubility of water in pure enstatite was measured on samples synthesized at 1,100 °C and pressures to 100 kbar. Enstatite crystals were grown under water-saturated conditions from a stoichiometric mixture of high-purity SiO2 and Mg(OH)2. Water contents were calculated from polarized FTIR spectra measured on oriented single crystals. The water solubility in orthoenstatite increases with pressure to 867ᆷ ppm H2O by weight at 75 kbar. At 100 kbar, in the stability field of high-clinoenstatite, a water solubility of 714ᆷ ppm was observed. The water solubility in enstatite at 1,100 °C can be described by the equation cH2O=AfH2O exp(-P(V/RT), where fH2O is water fugacity, A=0.0204 ppm/bar and (V=12.3 cm3/mol. The infrared spectra of the hydrous enstatite crystals show a sharp, intense band at 3,363 cm-1 and a broad, weaker band at 3,064 cm-1. Both bands are strongly polarized parallel c. Most likely, pairs of protons attached to non-bridging oxygen atoms substitute for Mg2+. In order to investigate the effect of chemical impurities on water solubility in enstatite, an additional series of experiments was carried out with gels doped with Al, B, or Li as starting material. Whereas, the presence of Li and B had no detectable effect on water solubility, the addition of about 1 wt% Al2O3 increased water solubility in enstatite from 199 to 1,100 ppm at 1,100°C and 15 kbar. In the infrared spectra of these aluminous samples, additional bands occur in the range from 3,450 to 3,650 cm-1. Similar bands are also observed in natural, aluminous orthopyroxenes and are most likely caused by protons coupled with Al according to the substitution of Al3++H+ for Si4+. A series of hydrous annealing experiments on a natural, gem-quality aluminous enstatite from Tanzania yielded water solubilities generally consistent with the results from the synthetic model systems. The results presented here imply that pure enstatite has a similar storage capacity for water as olivine; however, aluminous orthopyroxenes in the mantle may dissolve much larger amounts of water comparable with the entire mass of the present hydrosphere. Moreover, the mechanism of aluminum substitution in orthopyroxenes, i.e., the distribution of Al between tetrahedral and octahedral sites, may be a potential probe of water fugacity. 相似文献
36.
Wave velocities and attenuation of shaley sandstones as a function of pore pressure and partial saturation 总被引:3,自引:0,他引:3
Nam H. Pham † José M. Carcione Hans B. Helle Bjørn Ursin 《Geophysical Prospecting》2002,50(6):615-627
We obtain the wave velocities and quality factors of clay‐bearing sandstones as a function of pore pressure, frequency and partial saturation. The model is based on a Biot‐type three‐phase theory that considers the coexistence of two solids (sand grains and clay particles) and a fluid mixture. Additional attenuation is described with the constant‐Q model and viscodynamic functions to model the high‐frequency behaviour. We apply a uniform gas/fluid mixing law that satisfies the Wood and Voigt averages at low and high frequencies, respectively. Pressure effects are accounted for by using an effective stress law. By fitting a permeability model of the Kozeny– Carman type to core data, the model is able to predict wave velocity and attenuation from seismic to ultrasonic frequencies, including the effects of partial saturation. Testing of the model with laboratory data shows good agreement between predictions and measurements. 相似文献
37.
Thomas K. Nielsen Hans Christian Larsen John R. Hopper 《Earth and Planetary Science Letters》2002,200(3-4):271-286
We present new and reprocessed seismic reflection data from the area where the southeast and southwest Greenland margins intersected to form a triple junction south of Greenland in the early Tertiary. During breakup at 56 Ma, thick igneous crust was accreted along the entire 1300-km-long southeast Greenland margin from the Greenland Iceland Ridge to, and possibly 100 km beyond, the triple junction into the Labrador Sea. However, highly extended and thin crust 250 km to the west of the triple junction suggests that magmatically starved crustal formation occurred on the southwest Greenland margin at the same time. Thus, a transition from a volcanic to a non-volcanic margin over only 100–200 km is observed. Magmatism related to the impact of the Iceland plume below the North Atlantic around 61 Ma is known from central-west and southeast Greenland. The new seismic data also suggest the presence of a small volcanic plateau of similar age close to the triple junction. The extent of initial plume-related volcanism inferred from these observations is explained by a model of lateral flow of plume material that is guided by relief at the base of the lithosphere. Plume mantle is channelled to great distances provided that significant melting does not take place. Melting causes cooling and dehydration of the plume mantle. The associated viscosity increase acts against lateral flow and restricts plume material to its point of entry into an actively spreading rift. We further suggest that thick Archaean lithosphere blocked direct flow of plume material into the magma-starved southwest Greenland margin while the plume was free to flow into the central west and east Greenland margins. The model is consistent with a plume layer that is only moderately hotter, 100–200°C, than ambient mantle temperature, and has a thickness comparable to lithospheric thickness variations, 50–100 km. Lithospheric architecture, the timing of continental rifting and viscosity changes due to melting of the plume material are therefore critical parameters for understanding the distribution of magmatism. 相似文献
38.
Methodology for construction, calibration and validation of a national hydrological model for Denmark 总被引:13,自引:0,他引:13
Hans Jrgen Henriksen Lars Troldborg Per Nyegaard Torben Obel Sonnenborg Jens Christian Refsgaard Bjarne Madsen 《Journal of Hydrology》2003,280(1-4):52-71
An integrated groundwater/surface water hydrological model with a 1 km2 grid has been constructed for Denmark covering 43,000 km2. The model is composed of a relatively simple root zone component for estimating the net precipitation, a comprehensive three-dimensional groundwater component for estimating recharge to and hydraulic heads in different geological layers, and a river component for streamflow routing and calculating stream–aquifer interaction. The model was constructed on the basis of the MIKE SHE code and by utilising comprehensive national databases on geology, soil, topography, river systems, climate and hydrology. The present paper describes the modelling process for the 7330 km2 island of Sjælland with emphasis on the problems experienced in combining the classical paradigms of groundwater modelling, such as inverse modelling of steady-state conditions, and catchment modelling, focussing on dynamic conditions and discharge simulation. Three model versions with different assumptions on input data and parameter values were required until the performance of the final, according to pre-defined accuracy criteria, model was evaluated as being satisfactory. The paper highlights the methodological issues related to establishment of performance criteria, parameterisation and assessment of parameter values from field data, calibration and validation test schemes. Most of the parameter values were assessed directly from field data, while about 10 ‘free’ parameters were subject to calibration using a combination of inverse steady-state groundwater modelling and manual trial-and-error dynamic groundwater/surface water modelling. Emphasising the importance of tests against independent data, the validation schemes included combinations of split-sample tests (another period) and proxy-basin tests (another area). 相似文献
39.
Thomas Backhaus Rolf Altenburger sa Arrhenius Hans Blanck Michael Faust Antonio Finizio Paola Gramatica Matthias Grote Marion Junghans Wiebke Meyer Manuela Pavan Tobias Porsbring Martin Scholze Roberto Todeschini Marco Vighi Helge Walter L. Horst Grimme 《Continental Shelf Research》2003,23(17-19):1757
Freshwater and marine ecosystems are exposed to various multi-component mixtures of pollutants. Nevertheless, most ecotoxicological research and chemicals regulation focus on hazard and exposure assessment of individual substances only, the problem of chemical mixtures in the environment is ignored to a large extent. In contrast, the assessment of combination effects has a long tradition in pharmacology, where mixtures of chemicals are specifically designed to develop new products, e.g. human and veterinary drugs or agricultural and non-agricultural pesticides. In this area, two concepts are frequently used and are thought to describe fundamental relationships between single substance and mixture effects: Independent Action (Response Addition) and Concentration Addition. The question, to what extent these concepts may also be applied in an ecotoxicological and regulatory context may be considered a research topic of major importance, as the concepts would allow to make use of already existing single substance toxicity data for the predictive assessment of mixture toxicities. Two critical knowledge gaps are identified: (a) There is a lack of environmental realism, as a huge part of our current knowledge about the applicability of the concepts is restricted to artificial situations with respect to mixture composition or biological effect assessment. (b) The knowledge on what exactly is needed for using the concepts as tools for the predictive mixture toxicity assessment is insufficient. Both gaps seriously hamper the necessary, scientifically sound consideration of mixture toxicities in a regulatory context.In this paper, the two concepts will be briefly introduced, the necessity of considering the toxicities of chemical mixtures in the environment will be demonstrated and the applicability of Independent Action and Concentration Addition as tools for the prediction and assessment of mixture toxicities will be discussed. An overview of the specific aims and approaches of the BEAM project to fill in the identified knowledge gaps is given and first results are outlined. 相似文献
40.
Emil V. Stanev Jörg-Olaf Wolff Hans Burchard Karsten Bolding Götz Flöser 《Ocean Dynamics》2003,53(1):27-51
In this paper we use a combination of numerical modeling and data analysis to gain a better understanding of the major characteristics
of the circulation in the East Frisian Wadden Sea. In particular, we concentrate on the asymmetry of the tidal wave and its
modulation in the coastal area, which results in a complex pattern of responses to the sea-level forcing from the North Sea.
The numerical simulations are based on the 3-D primitive equation General Estuarine Transport Model (GETM) with a horizontal
resolution of 200 m and terrain-following vertical coordinates. The model is forced at its open boundaries with sea-level
data from an operational model for the German Bight (German Hydrographic Office). The validation data for our model simulations
include time series of tidal gauge data and surface currents measured at a pile in the back-barrier basin of the Island Langeoog,
as well as several ADCP transects in the Accumer Ee tidal inlet.
Circulation and turbulence characteristics are investigated for typical situations driven by spring and neap tides, and the
analysis is focused on dominating temporal and spatial patterns. By investigating the response of five back-barrier basins
with rather different morphologies to external forcing, an attempt is made to elucidate the dominating physical balances controlling
the circulation in the individual sub-basins. It is demonstrated that the friction at the seabed tends to slow down the tidal
signal in the shallow water. This leads to the establishment of flood dominance in the shallow sea north of the barrier islands.
South of the islands, where the water volume of the channels at low tide is smaller than the tidal prism, the asymmetry of
the tidal signal is shifted towards ebb dominance, a feature which is particularly pronounced at spring tide.
At the northern open boundary, the tidal wave propagating from west to east generates a sea-level difference of ∼1 m along
the boundary, and thereby triggers vigorous alongshore currents. The frictional control in the model is located in the inlets,
as well as along the northern boundary. The correlation between velocity and turbulent kinetic energy tends to the establishment
of a net southward transport, giving theoretical support to the observed accumulation of sediments on the intertidal flats.
Weak turbulence along the northern shores of the barrier islands and the small magnitude of the residual currents there promote
accumulation of suspended matter in these areas, although wave action will generally counteract this effect.
Received: 29 May 2002 / Accepted: 26 September 2002
Responsible Editor: Jean-Marie Beckers
Acknowledgements We are indebted to S. Dick for providing the data from the operational model of BSH and to B. Flemming for the useful discussions.
The topography data and Fig. 1 have been prepared in cooperation with F. Meyer. Figure 2 has been prepared by G. Brink-Spalink.
We also thank for the comments from an anonymous reviewer which helped to improve our paper. 相似文献