A first Holocene leaf wax isotope-based paleoclimate record from the semi-humid to semi-arid south-eastern Caucasian lowlands

The Holocene paleoclimate of the Caucasus region is rather complex and not yet well understood: while existing studies are mainly based on pollen records from high-altitude and humid lowland regions, no records are available from the semi-humid to semi-arid south-eastern Caucasian lowlands. Therefore, this study investigated compound-specific δ²H and δ¹³C isotopes of leaf wax biomarkers from Holocene floodplain soils in eastern Georgia. Our results show that the leaf wax δ²H signal from the paleosols mostly reflects changes in the moisture source and its isotopic composition. Depleted δ²H values before ~8 cal ka bp change towards enriched values after ~5 cal ka bp and become again depleted after ~1.6 cal ka bp. This trend could be caused by Holocene changes of the isotopic compositions of the Black and eastern Mediterranean Sea, and/or by varying contribution of both moisture sources linked with the North Atlantic Oscillation. The leaf wax δ¹³C signal from the paleosols directly indicates varying local water availability and drought stress. Depleted δ¹³C values before ~8 and after ~5 cal ka bp indicate wetter local conditions with higher water availability, whereas more enriched values during the middle Holocene (~8 until at least 5 cal ka bp ) indicate drier conditions with increased drought stress.     

Correction to: New insights into the rainfall variability in the tropical Andes on seasonal and interannual time scales

Climate Dynamics - The original version of the article contained errors in Fig.     

The influence of central black holes on gravitational lenses

Recent observations indicate that many if not all galaxies host massive central black holes. In this paper we explore the influence of black holes on the lensing properties. We model the lens as an isothermal ellipsoid with a finite core radius plus a central black hole. We show that the presence of the black hole substantially changes the critical curves and caustics. If the black hole mass is above a critical value, then it will completely suppress the central images for all source positions. Realistic central black holes are likely to have masses below this critical value. Even in such subcritical cases, the black hole can suppress the central image when the source is inside a zone of influence, which depends on the core radius and black hole mass. In the subcritical cases, an additional image may be created by the black hole in some regions, which for some radio lenses may be detectable with high-resolution and large dynamic range VLBI maps. The presence of central black holes should also be taken into account when one constrains the core radius from the lack of central images in gravitational lenses.     

An on Orbit Determination of Point Spread Functions for the <Emphasis Type="Italic">Interface Region Imaging Spectrograph</Emphasis>

Using the 2016 Mercury transit of the Sun, we characterize on orbit spatial point spread functions (PSFs) for the Near- (NUV) and Far- (FUV) Ultra-Violet spectrograph channels of NASA’s Interface Region Imaging Spectrograph (IRIS). A semi-blind Richardson–Lucy deconvolution method is used to estimate PSFs for each channel. Corresponding estimates of Modulation Transfer Functions (MTFs) indicate resolution of 2.47 cycles/arcsec in the NUV channel near 2796 Å and 2.55 cycles/arcsec near 2814 Å. In the short (\({\approx}\,1336~\mathring{\mathrm{A}}\)) and long (\({\approx}\,1394~\mathring{\mathrm{A}}\)) wavelength FUV channels, our MTFs show pixel-limited resolution (3.0 cycles/arcsec). The PSF estimates perform well under deconvolution, removing or significantly reducing instrument artifacts in the Mercury transit spectra. The usefulness of the PSFs is demonstrated in a case study of an isolated explosive event. PSF estimates and deconvolution routines are provided through a SolarSoft module.     

Water solubility in orthopyroxene

The solubility of water in pure enstatite was measured on samples synthesized at 1,100 °C and pressures to 100 kbar. Enstatite crystals were grown under water-saturated conditions from a stoichiometric mixture of high-purity SiO₂ and Mg(OH)₂. Water contents were calculated from polarized FTIR spectra measured on oriented single crystals. The water solubility in orthoenstatite increases with pressure to 867ᆷ ppm H₂O by weight at 75 kbar. At 100 kbar, in the stability field of high-clinoenstatite, a water solubility of 714ᆷ ppm was observed. The water solubility in enstatite at 1,100 °C can be described by the equation c_H2O=Af_H2O exp(-P(V/RT), where f_H2O is water fugacity, A=0.0204 ppm/bar and (V=12.3 cm³/mol. The infrared spectra of the hydrous enstatite crystals show a sharp, intense band at 3,363 cm^-1 and a broad, weaker band at 3,064 cm^-1. Both bands are strongly polarized parallel c. Most likely, pairs of protons attached to non-bridging oxygen atoms substitute for Mg²⁺. In order to investigate the effect of chemical impurities on water solubility in enstatite, an additional series of experiments was carried out with gels doped with Al, B, or Li as starting material. Whereas, the presence of Li and B had no detectable effect on water solubility, the addition of about 1 wt% Al₂O₃ increased water solubility in enstatite from 199 to 1,100 ppm at 1,100°C and 15 kbar. In the infrared spectra of these aluminous samples, additional bands occur in the range from 3,450 to 3,650 cm^-1. Similar bands are also observed in natural, aluminous orthopyroxenes and are most likely caused by protons coupled with Al according to the substitution of Al³⁺+H⁺ for Si⁴⁺. A series of hydrous annealing experiments on a natural, gem-quality aluminous enstatite from Tanzania yielded water solubilities generally consistent with the results from the synthetic model systems. The results presented here imply that pure enstatite has a similar storage capacity for water as olivine; however, aluminous orthopyroxenes in the mantle may dissolve much larger amounts of water comparable with the entire mass of the present hydrosphere. Moreover, the mechanism of aluminum substitution in orthopyroxenes, i.e., the distribution of Al between tetrahedral and octahedral sites, may be a potential probe of water fugacity.     

Chemical characteristics (REE,etc.) of Paleozoic and Mesozoic graywackes and sandstones from Central Europe

During the Variscan orogeny in Central Europe, partial melting in the lower continental crust formed granitic magmas, which intruded into the upper crust and left compounds of Ca (plus Eu²⁺), Mg, etc. in the lower crust. From the late Paleozoic decomposition of the tonalitic upper crust, sedimentary graywackes were produced reflecting the composition of this crust. The repeated reworking of the sedimentary cover caused the formation of sands. Sandstones as their products of consolidation contain increasing fractions of quartz and decreasing feldspar from Carboniferous and Triassic to Cretaceous age. A distinct negative Eu anomaly characterizes the majority of these rocks. The latter is imprinted by the Variscan magmatism. Quartz as used for numerous Medieval wood ash glasses is marked for its Central European origin by a distinct negative Eu anomaly in contrast to many soda glasses produced outside Germany mostly with a small or none Eu anomaly.     

A candidate of the Induan-Olenekian boundary stratotype in the Tethyan region

The Olenekian Stage was proposed by Kiparisova and Popov[1] based on the type section along the lower reaches of the Olenek River, Siberia. Later research showed that this section con-tains only the Olenikites spiniplicatus Zone of the Upper Olenekian Sta…     

In Memoriam

Ohne Zusammenfassung     

The GW-Fauna-Index: A first approach to a quantitative ecological assessment of groundwater habitats

Between June 2001 and December 2002, 18 hyporheic and groundwater bores were sampled for fauna and environmental data using phreatic traps. The bores were situated in three different natural geographic regions in Palatinate, Southwestern Germany.Faunal data correlated with the relative amount of detritus, bacterial abundances and the standard deviation of temperature, while very few and weak correlations were found with physical–chemical variables. Dissolved oxygen was assumed to be a limiting factor for most metazoans with a critical concentration at around 0.5–1 mg l⁻¹.To quantify the strength of the hydrological exchange with surface water and its effects on fauna, a so-called GW-Fauna-Index was developed and calculated using the relative amount of detritus, standard deviation of temperature, and oxygen concentration. From all environmental data and on all spatial scales, this index best explained the total faunal abundance and taxonomic richness.To describe the availability of organic aliments in the groundwater, the terms of “alimonic” and “alimony” [from lat. alimonium=(food) supply] were proposed.Although stygofauna was different in the geographic regions investigated, the GW-Fauna-Index was independent from these regional particularities. Using the GW-Fauna-Index, three groups of groundwater habitats could be classified according to the alimonic conditions. From oligo-alimonic group I samples, fauna was mostly absent, while meso-alimonic group II samples were prevailingly populated by stygobites, and eu-alimonic group III samples by ubiquists and stygoxenes. Total abundances and taxonomic richness increased significantly from group I to group III. Group I samples were characterized by low index values, group II samples by intermediate and group III samples by high values.The GW-Fauna-Index provides promising perspectives for application, but needs some improvement. First of all, detritus should be analysed quantitatively and qualitatively, rather than semi-quantitatively. Also, a standard protocol for sampling has to be developed.