Eo-alpine metamorphism in the uppermost unit of the Cretan nappe system — Petrology and geochronology

The uppermost unit of the Cretan nappe system consists of ophiolites on the top, and an ophiolitic mélange at the base.Among the various constituents of the mélange, there are slices of low-P/high-T metamorphics. They form a variegated series consisting of tholeiitic ortho-amphibolites, para-amphibolites, andalusite and sillimanite-cordierite-garnet bearing mica schists, calcsilicate rocks, and marbles. The metamorphic sequence is locally intruded by early tectonic magmatites of gabbroic, dioritic and granitic composition. Critical mineral assemblages lead to a maximum temperature of about 700° C reached during metamorphism, at a total pressure of 4–5 kilobars. K — Ar dating on 6 hornblendes, 7 biotites and 1 muscovite yielded cooling ages of 75–66 m.y. and confirmed earlier results according to which the metamorphism and related magmatism took place in Late Cretaceous times.In order to evaluate the age relationships between the hightemperature metamorphics within the ophiolitic mélange and the ophiolites, hornblendes from ultramafic and mafic rocks of the ophiolite complex were dated by the K — Ar method. Hornblende from one schistose hornblendite forming a constituent of the ophiolites proper yielded 156 m.y. and thus provides a middle Jurassic minimum age for the formation of this piece of oceanic lithosphere. Four hornblendes of calc-alkaline gabbrodiorite dikes within the ophiolite complex gave distinctly lower K — Ar dates of about 140 m.y.. The dikes probably intruded after the detachment of the ophiolites in an island-arc or continental-margin environment.As a consequence, the high-temperature metamorphics and related intrusives in the ophiolitic mélange of Crete are genetically unrelated to the overlying ophiolites. The paleogeographic position of the crystalline terrane, slices of which are now incorporated into the ophiolitic mélange is still open to discussion.     

The “Boscobel Landslip” of October 1st, 1901—the largest historic landslide in Barbados,West Indies

Barbados is a small Caribbean island located on the crest of an accretionary prism about 125 km east of the Lesser Antilles volcanic island arc. The oldest strata, Eocene sandstones and shales, are overlain by Oligocene–Miocene chalks and marls, in turn overlain by Pleistocene reef and lagoonal limestones that cover about 85 % of the island. The Eocene sediments, which crop out in the Scotland District of Barbados, are prone to soil creep and landslides covering tens to hundreds of hectares. The largest historic landslide, the “Boscobel Landslip,” occurred on 01 October 1901. We used nineteenth-century and more modern topographic and geologic maps, air photographs, and various archival and petrophysical data, to supplement reconnaissance of the landslide in the field. We identified about ten million cubic meters of the displaced material of the landslide, as well as the meteorological and geological conditions that contributed to the Boscobel Landslip. Similar landslides would pose a presently unquantified hazard to inhabitation and future development in the Scotland District.     

Effects of groundwater flow on mineral diagenesis, with emphasis on carbonate aquifers

 This article provides a critical synopsis of the effects of groundwater flow on mineral diagenesis. Emphasis is placed on those aspects and processes that change porosity and permeability in carbonate aquifers, because they are of particular importance to human societies as sources of supplies of water for human consumption (drinking, irrigation) and of crude oil and natural gas. Diagenetic settings in carbonates as well as clastics are generally ill defined. This paper proposes a new comprehensive classification of diagenetic settings into near-surface, shallow-, intermediate-, and deep-burial diagenetic settings; hydrocarbon-contaminated plumes; and fractures. These settings are defined on the basis of mineralogy, petroleum, hydrogeochemistry, and hydrogeology. This classification is applicable to all sedimentary basins. Diagenesis is governed by various intrinsic and extrinsic factors that include thermodynamic and kinetic constraints, as well as microstructural factors that may override the others. These factors govern diagenetic processes, such as dissolution, compaction, recrystallization, replacement, and sulfate–hydrocarbon redox-reactions. Processes such as cementation, dissolution, and dolomitization require significant flow of groundwater driven by an externally imposed hydraulic gradient. Other processes, such as stylolitization and thermochemical sulfate reduction, commonly take place without significant groundwater flow in hydrologically nearly or completely stagnant systems that are geochemically "closed." Two major effects of groundwater flow on mineral diagenesis are enhancement and reduction of porosity and permeability, although groundwater flow can also leave these rock properties essentially unchanged. In extreme cases, an aquifer or hydrocarbon reservoir rock can have highly enhanced porosity and permeability due to extensive mineral dissolution, or it can be plugged up due to extensive mineral precipitation. Received, April 1998 · Revised, July 1998 · Accepted, September 1998