Further studies on the chordal-hop theory of ionospheric long-range propagation

Summary This paper presents new results of the author's investigations on ionospheric propagation in Australia from 1952 to 1957. Considerations on path attenuation are followed by a discussion on the propagation paths to North America and Western Europe. Conclusions are in agreement with the author's previous publications in this field.

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Zusammenfassung In dieser Arbeit behandelt der Verfasser neue Ergebnisse seiner Untersuchungen über ionosphärische Ausbreitung in Australien von 1952 bis 1957. Auf eine Betrachtung über die Signalschwächung folgt eine Diskussion über die Ausbreitungswege nach Nordamerika und Westeuropa. Die Folgerungen stimmen mit den früheren Veröffentlichungen des Verfassers auf diesem Gebiet überein.

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Résumé L'auteur expose les nouveaux résultats de ses recherches sur la propagation ionosphérique en Australie de 1952 à 1957; il considère l'affaiblissement de la propagation des signaux et les chemins suivis par les ondes vers l'Amérique du Nord et vers l'Europe occidentale. Ces résultats concordent avec ceux qu'il a publiés précédemment.

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Chemical Mechanism Development: Laboratory Studies and Model Applications

Within the German Tropospheric Research Programme (TFS) numerous kinetic and mechanistic studies on the tropospheric reaction/degradation of the following reactants were carried out: oxygenated VOC, aromatic VOC, biogenic VOC, short-lived intermediates, such as alkoxy and alkylperoxy radicals.At the conception of the projects these selected groups were classes of VOC or intermediates for which the atmospheric oxidation mechanisms were either poorly characterised or totally unknown. The motivation for these studies was the attainment of significant improvements in our understanding of the atmospheric chemical oxidation processes of these compounds, particularly with respect to their involvement in photooxidant formation in the troposphere. In the present paper the types of experimental investigations performed and the results obtained within the various projects are briefly summarised. The major achievements are highlighted and discussed in terms of their contribution to improving our understanding of the chemical processes controlling photosmog formation in the troposphere.     

Chemical structural units of macromolecular coal components

Chemical degradations of coal resins, coal asphaltenes and coal residues have been performed with selective, non-oxidative reagents. The coal comprise samples a rank interval 0.30–1.21 %R_m. Degraded low-molecular-weight compounds were analyzed by GC-MS. The distributions of pentacyclic terpanes, isoprenoids, n-alkanes, acids and alcohols obtained as degradation products illustrate a considerable variability between the macromolecular coal fractions. A structural study on the molecular level of the degraded compounds from coal resins and coal asphaltenes show their potential to generate hydrocarbons during coalification process.     

Improving a tree-ring reconstruction from west-central Scandinavia: 900?years of warm-season temperatures

Dendroclimatological sampling of Scots pine (Pinus sylvestris L.) has been made in the province of J?mtland, in the west-central Scandinavian mountains, since the 1970s. The tree-ring width (TRW) chronology spans several thousand years and has been used to reconstruct June?CAugust temperatures back to 1632 bc. A maximum latewood density (MXD) dataset, covering the period ad 1107?C1827 (with gap 1292?C1315) was presented in the 1980s by Fritz Schweingruber. Here we combine these historical MXD data with recently collected MXD data covering ad 1292?C2006 into a single reconstruction of April?CSeptember temperatures for the period ad 1107?C2006. Regional curve standardization (RCS) provides more low-frequency variability than ??non-RCS?? and stronger correlation with local seasonal temperatures (51% variance explained). The MXD chronology shows a stronger relationship with temperatures than the TRW data, but the two chronologies show similar multi-decadal variations back to ad 1500. According to the MXD chronology, the period since ad 1930 and around ad 1150?C1200 were the warmest during the last 900?years. Due to large uncertainties in the early part of the combined MXD chronology, it is not possible to conclude which period was the warmest. More sampling of trees growing near the tree-line is needed to further improve the MXD chronology.     

Spectral Characteristics and Correction of Long-Term Eddy-Covariance Measurements Over Two Mixed Hardwood Forests in Non-Flat Terrain

We present turbulence spectra and cospectra derived from long-term eddy-covariancemeasurements (nearly 40,000 hourly data over three to four years) and the transferfunctions of closed-path infrared gas analyzers over two mixed hardwood forests inthe mid-western U.S.A. The measurement heights ranged from 1.3 to 2.1 times themean tree height, and peak vegetation area index (VAI) was 3.5 to 4.7; the topographyat both sites deviates from ideal flat terrain. The analysis follows the approach ofKaimal et al. (Quart. J. Roy. Meteorol. Soc. 98, 563–589, 1972) whose results were based upon 15 hours of measurements atthree heights in the Kansas experiment over flatter and smoother terrain. Both thespectral and cospectral constants and stability functions for normalizing and collapsingspectra and cospectra in the inertial subrange were found to be different from those ofKaimal et al. In unstable conditions, we found that an appropriate stabilityfunction for the non-dimensional dissipation of turbulent kinetic energy is of the form ₍₎ = (1 - b^-)^-1/4 - c^-, where representsthe non-dimensional stability parameter. In stable conditions, a non-linear functionG_xy() = 1 + b_xy^c _xy (c_xy < 1) was found to benecessary to collapse cospectra in the inertial subrange. The empirical cospectralmodels of Kaimal et al. were modified to fit the somewhat more (neutraland unstable) or less (stable) sharply peaked scalar cospectra observed over forestsusing the appropriate cospectral constants and non-linear stability functions. Theempirical coefficients in the stability functions and in the cospectral models varywith measurement height and seasonal changes in VAI. The seasonal differencesare generally larger at the Morgan Monroe State Forest site (greater peak VAI) andcloser to the canopy.The characteristics of transfer functions of the closed-path infrared gas analysersthrough long-tubes for CO₂ and water vapour fluxes were studied empirically. This was done by fitting the ratio between normalized cospectra of CO₂ or watervapour fluxes and those of sensible heat to the transfer function of a first-order sensor.The characteristic time constant for CO₂ is much smaller than that for water vapour. The time constant for water vapour increases greatly with aging tubes. Three methods were used to estimate the flux attenuations and corrections; from June through August, the attenuations of CO₂ fluxes are about 3–4% during the daytime and 6–10% at night on average. For the daytime latent heat flux (Q_E), the attenuations are foundto vary from less than 10% for newer tubes to over 20% for aged tubes. Correctionsto Q_E led to increases in the ratio (Q_H + Q_E)/(Q^* - Q_G) by about 0.05 to0.19 (Q_H is sensible heat flux, Q^* is net radiation and Q_G is soil heat flux),and thus are expected to have an important impact on the assessment of energy balanceclosure.     

Frequency of Boundary-Layer-Top Fluctuations in Convective and Stable Conditions Using Laser Remote Sensing

The planetary boundary-layer (PBL) height is determined with high temporal and altitude resolution from lidar backscatter profiles. Then, the frequencies of daytime thermal updrafts and downdrafts and of nighttime gravity waves are obtained applying a fast Fourier transform on the temporal fluctuation of the PBL height. The principal frequency components of each spectrum are related to the dominant processes occurring at the daytime and nighttime PBL top. Two groups of cases are selected for the study: one group combines daytime cases, measured in weak horizontal wind conditions and dominated by convection. The cases show higher updraft and downdraft frequencies for the shallow, convective boundary layer and lower frequencies for a deep PBL. For cases characterized by strong horizontal winds, the frequencies directly depend on the wind speed. The temporal variation of the PBL height is determined also in the likely presence of lee waves. For nighttime cases, the main frequency components in the spectra do not show a real correlation with the nocturnal PBL height. Altitude fluctuations of the top of the nocturnal boundary layer are observed even though the boundary layer is statically stable. These oscillations are associated with the wind shear effect and with buoyancy waves at the PBL top.     

陕西关中及周边地区近500a来初夏旱涝事件初步分析

基于华山树轮宽度差值年表重建的陕西关中及周边地区近500a来的初夏干燥指数序列,对该地区初夏极端旱涝事件及其连续旱涝变化特征进行了初步分析.区域干燥指数与Palmer指数在变化上极为相似,可用于反映该地区的旱涝变化.结果表明:该地区近500a来初夏共发生18次极端干旱事件和11次极端洪涝事件,除公元1521年与历史文献记录的旱涝事件相反,公元1513年、1574年、1675年和1945年未发现历史记录外,其余年份均能找到相应记录;近500a来初夏存在9个显著的连续偏旱期和10个显著的连续偏涝期,并以16和19世纪发生的连续旱涝事件最为频繁,而17和18世纪发生的旱涝事件相对较少,20世纪发生的干旱事件明显多于洪涝事件.     

Evaluation of the Weather Research and Forecasting Mesoscale Model for GABLS3: Impact of Boundary-Layer Schemes,Boundary Conditions and Spin-Up

We evaluated the performance of the three-dimensional Weather Research and Forecasting (WRF) mesoscale model, specifically the performance of the planetary boundary-layer (PBL) parametrizations. For this purpose, Cabauw tower observations were used, with the study extending beyond the third GEWEX Atmospheric Boundary-Layer Study (GABLS3) one-dimensional model intercomparison. The WRF model (version 3.4.1) contains 12 different PBL parametrizations, most of which have been only partially evaluated. The GABLS3 case offers a clear opportunity to evaluate model performance, focusing on time series of near-surface weather variables, radiation and surface flux budgets, vertical structure and the nighttime inertial oscillation. The model results revealed substantial differences between the PBL schemes. Generally, non-local schemes tend to produce higher temperatures and higher wind speeds than local schemes, in particular, for nighttime. The WRF model underestimates the 2-m temperature during daytime (about \(2\) K) and substantially underestimates it at night (about \(4\) K), in contrast to the previous studies where modelled 2-m temperature was overestimated. Considering the 10-m wind speed, during the night turbulent kinetic energy based schemes tend to produce lower wind speeds than other schemes. In all simulations the sensible and latent heat fluxes were well reproduced. For the net radiation and the soil heat flux we found good agreement with daytime observations but underestimations at night. Concerning the vertical profiles, the selected non-local PBL schemes underestimate the PBL depth and the low-level jet altitude at night by about 50 m, although with the correct wind speed. The latter contradicts most previous studies and can be attributed to the revised stability function in the Yonsei University PBL scheme. The local, turbulent kinetic energy based PBL schemes estimated the low-level jet altitude and strength more accurately. Compared to the observations, all model simulations show a similar structure for the potential temperature, with a consistent cold bias ( \(\approx \) 2 K) in the upper PBL. In addition to the sensitivity to the PBL schemes, we studied the sensitivity to technical features such as horizontal resolution and domain size. We found a substantial difference in the model performance for a range of 12, 18 and 24 h spin-up times, longer spin-up time decreased the modelled wind speed bias, but it strengthened the negative temperature bias. The sensitivity of the model to the vertical resolution of the input and boundary conditions on the model performance is confirmed, and its influence appeared most significant for the non-local PBL parametrizations.     

A novel ozone sensor for direct eddy flux measurements

A small, lightweight (1.5 kg) and fast-response ozone sensor for direct eddy flux measurements has been built. The basis for detection is the chemiluminescence of an organic dye adsorbed on dry silica gel in the reaction with ozone. The chemiluminescence is monitored with a cheap and small blue-sensitive photomultiplier. At a flow rate of 100 l min^-1 the ozone sensor has a 90% response time of significantly better than 0.1 s with a detection limit lower than 50 ppt at S/N=3. There are no interferences from other atmospheric trace gases like NO_x, H₂O₂ and PAN. Water vapour and SO₂ enhance the chemiluminescence efficiency of the ozone sensor. Since their response times are 22 seconds and 30 minutes, respectively, no correlation between rapid ozone fluctuations and those of these two trace gases is noticed by the ozone sensor when operating at a frequency of 10 Hz.The ozone sensor was tested for several weeks in continuous measurements of ozone fluxes and deposition velocities over different croplands using the eddy correlation technique. Good agreement was found between ozone dry deposition velocities derived from profile measurements and by eddy correlation.