A Compilation of Silicon,Rare Earth Element and Twenty‐One other Trace Element Concentrations in the Natural River Water Reference Material SLRS‐5 (NRC‐CNRC)

The natural river water certified reference material SLRS‐5 (NRC‐CNRC) was routinely analysed in this study for major and trace elements by ten French laboratories. Most of the measurements were made using ICP‐MS. Because no certified values are assigned by NRC‐CNRC for silicon and 35 trace element concentrations (rare earth elements, Ag, B, Bi, Cs, Ga, Ge, Li, Nb, P, Rb, Rh, Re, S, Sc, Sn, Th, Ti, Tl, W, Y and Zr), or for isotopic ratios, we provide a compilation of the concentrations and related uncertainties obtained by the participating laboratories. Strontium isotopic ratios are also given.     

Fracture mechanics analysis of multiple cracks in anisotropic media

This paper presents a single‐domain boundary element method (BEM) for linear elastic fracture mechanics analysis in the two‐dimensional anisotropic material. In this formulation, the displacement integral equation is collocated on the un‐cracked boundary only, and the traction integral equation is collocated on one side of the crack surface only. A special crack‐tip element was introduced to capture exactly the crack‐tip behavior. A computer program with the FORTRAN language has been developed to effectively calculate the stress intensity factors of an anisotropic material. This BEM program has been verified having a good accuracy with the previous researches. Furthermore, by analyzing the different anisotropic degree cracks in a finite plate, we found that the stress intensity factors of crack tips had apparent influence by the geometry forms of cracks and media with different anisotropic degrees. Copyright © 2010 John Wiley & Sons, Ltd.     

Fossil wood

Plants have been making wood (secondary xylem) for more than 370 million years. This familiar material is one of the keys to their massive success. Wood allows plants to attain breathtaking heights and maximize the capture of sunlight for growth. By creating complex, multi‐layered forests, the evolution of wood, has done more to shape life on land than almost any other innovation. Wood is one of the most common terrestrial fossils encountered in the geological record. Whether preserved as huge petrified logs or as minute chunks of charcoal, fossil wood is abundant in rocks of Late Devonian age and younger. It is of enormous scientific importance, shedding light on the identity and stature of ancient trees. As a record of growth over a sustained period, it also tells us much about the climates and environments in which those trees lived. In this article, I explain some aspects of the origin, evolution, preservation, and identification of fossil wood, and emphasise its great significance for geology.     

The lateglacial Quercus expansion in the southern European Alps: rapid vegetation response to a late Allerød climate warming?

A pollen‐inferred vegetation shift, from pioneer birch–pine woodland to mixed pine–summergreen oak forests, in the southern Alpine forelands, is commonly attributed to a centennial‐scale warming that occurred between the Gerzensee Oscillation (GO) and the Younger Dryas. Two microtephra layers bracketing the Younger Dryas onset (the Laacher See Tephra and the Vedde Ash) improve the chronology at Lago Piccolo di Avigliana (northern Italy) and allowed accurate correlation with Central European records where the GO is clearly detected. We used pollen percentages, pollen accumulation rates (PARs) and plant macrofossils to assess the population dynamics of Quercus, and leaf‐cuticle analysis for a better taxonomic identification of Quercus. Our results indicate that the species that was locally present was probably Quercus robur. PARs suggest that the population expansion started as early as the Bølling and followed an exponential increase through time. We attribute this gradual shift to increasing summer temperatures and longer growing seasons which contrast with a gradually decreasing temperature trend as recorded in Greenland ice cores and in Central Europe. Breaks or set‐backs in the PAR record may indicate the biotic response to minor Lateglacial cooling events of different life‐history stages in the Quercus population. Copyright © 2011 John Wiley & Sons, Ltd.     

Fingerprinting the 8.2 ka event climate response in a coupled climate model

Using results from coupled climate model simulations of the 8.2 ka climate event that produced a cold period over Greenland in agreement with the reconstructed cooling from ice cores, we investigate the typical pattern of climate anomalies (fingerprint) to provide a framework for the interpretation of global proxy data for the 8.2 ka climate event. For this purpose we developed an analysis method that isolates the forced temperature response and provides information on spatial variations in magnitude, timing and duration that characterise the detectable climate event in proxy archives. Our analysis shows that delays in the temperature response to the freshwater forcing are present, mostly in the order of decades (30 a over central Greenland). The North Atlantic Ocean initially cools in response to the freshwater perturbation, followed in certain parts by a warm response. This delay, occurring more than 200 a after the freshwater pulse, hints at an overshoot in the recovery from the freshwater perturbation. The South Atlantic and the Southern Ocean show a warm response reflecting the bipolar seesaw effect. The duration of the simulated event varies for different areas, and the highest probability of recording the event in proxy archives is in the North Atlantic Ocean area north of 40° N. Our results may facilitate the interpretation of proxy archives recording the 8.2 ka event, as they show that timing and duration cannot be assumed to correspond with the timing and duration of the event as recorded in Greenland ice cores. Copyright © 2011 John Wiley & Sons, Ltd.     

Midge‐inferred Holocene effective moisture fluctuations in a subarctic lake,northern Lapland

Luoto, T. P. & Sarmaja‐Korjonen, K. 2011: Midge‐inferred Holocene effective moisture fluctuations in a subarctic lake, northern Lapland. Boreas, 10.1111/j.1502‐3885.2011.00217.x. ISSN 0300‐9483. We examined fossil midge (Diptera: Chironomidae) assemblages from Lake Várddoaijávri, northern Finland to track Holocene effective moisture variability. Application of a midge‐based water‐depth calibration model showed that the early Holocene was characterized by a high water level compared with the Holocene average, but the inferred values decreased at c. 8000 cal. a BP and increased again towards c. 6000 cal. a BP. The inferred water level decreased at c. 5500 cal. a BP, but increased again towards c. 4000 cal. a BP. Between 4000 and 3000 cal. a BP the lake experienced two rapid events of lower water level. A relatively high water level detected at c. 3000 cal. a BP was followed by a lowering towards c. 2000 cal. a BP. The time period from c. 2000 cal. a BP onwards was characterized by a general rise in lake level towards the present. Overall, the present reconstruction shows a close correspondence in its trends to previous lake‐level records in the region. Two common core taxa, Paratanytarsus and Corynocera ambigua, did not correlate significantly with water depth in the calibration data, creating a potential error source for the present lake‐level reconstruction. However, statistical analysis showed a clear community response to long‐term lake‐level changes, and therefore the major trends in Holocene effective moisture patterns were revealed. The present palaeoclimatic information can also serve as valuable background data when assessing the effects of the present climate change.     

Oxygen‐18 dynamics in precipitation and streamflow in a semi‐arid agricultural watershed,Eastern Washington,USA

Understanding flow pathways and mechanisms that generate streamflow is important to understanding agrochemical contamination in surface waters in agricultural watersheds. Two environmental tracers, δ¹⁸O and electrical conductivity (EC), were monitored in tile drainage (draining 12 ha) and stream water (draining nested catchments of 6‐5700 ha) from 2000 to 2008 in the semi‐arid agricultural Missouri Flat Creek (MFC) watershed, near Pullman Washington, USA. Tile drainage and streamflow generated in the watershed were found to have baseline δ¹⁸O value of ?14·7‰ (VSMOW) year round. Winter precipitation accounted for 67% of total annual precipitation and was found to dominate streamflow, tile drainage, and groundwater recharge. ‘Old’ and ‘new’ water partitioning in streamflow were not identifiable using δ¹⁸O, but seasonal shifts of nitrate‐corrected EC suggest that deep soil pathways primarily generated summer streamflow (mean EC 250 µS/cm) while shallow soil pathways dominated streamflow generation during winter (EC declining as low as 100 µS/cm). Using summer isotopic and EC excursions from tile drainage in larger catchment (4700‐5700 ha) stream waters, summer in‐stream evaporation fractions were estimated to be from 20% to 40%, with the greatest evaporation occurring from August to October. Seasonal watershed and environmental tracer dynamics in the MFC watershed appeared to be similar to those at larger watershed scales in the Palouse River basin. A 0·9‰ enrichment, in shallow groundwater drained to streams (tile drainage and soil seepage), of δ¹⁸O values from 2000 to 2008 may be evidence of altered precipitation conditions due to the Pacific Decadal Oscillation (PDO) in the Inland Northwest. Copyright © 2009 John Wiley & Sons, Ltd.     

Weichselian interstadials at Riipiharju,northern Sweden – interpretation of vegetation and climate from fossil and modern pollen records

Hättestrand, M. & Robertsson, A.‐M. 2010: Weichselian interstadials at Riipiharju, northern Sweden – interpretation of vegetation and climate from fossil and modern pollen records. Boreas, 10.1111/j.1502‐3885.2009.00129.x. ISSN 0300‐9483. The most complete records of Weichselian ice‐free conditions in northern Sweden have been retrieved from kettleholes in the Riipiharju esker. In an earlier study, the Riipiharju I core was described as containing two Weichselian interstadials and Riipiharju was chosen as type site for the second Weichselian interstadial in northern Sweden. Here, we present a palynological investigation of two new sediment cores (Riipiharju II and III) retrieved from Riipiharju. Together, the new cores comprise a late cold part of the first Weichselian interstadial recorded in northeastern Sweden (Tärendö I, earlier correlated with Peräpohjola in Finland) as well as a long sequence of the second Weichselian interstadial (Tärendö II, earlier named Tärendö). The results indicate that the climate during deposition of the Tärendö II sequence was more variable than earlier suggested. According to the present interpretation it was relatively warm in the early part of Tärendö II; thereafter a long cold phase persisted, and finally the climate was warmer again in the late part of Tärendö II. The warm phases are characterized by Betula‐dominant pollen assemblages, while the cold phase is characterized by high percentages of Artemisia and Gramineae pollen. Since there is still no firm chronology established of the interstadials in northeastern Sweden, two possible correlations are discussed; either Tärendö I and II are correlated with Brörup (MIS 5c) and Odderade (MIS 5a), or, perhaps more likely, they are correlated with Odderade and early Middle Weichselian (MIS 3) time.     

The data‐driven approach as an operational real‐time flood forecasting model

Accurate water level forecasts are essential for flood warning. This study adopts a data‐driven approach based on the adaptive network–based fuzzy inference system (ANFIS) to forecast the daily water levels of the Lower Mekong River at Pakse, Lao People's Democratic Republic. ANFIS is a hybrid system combining fuzzy inference system and artificial neural networks. Five ANFIS models were developed to provide water level forecasts from 1 to 5 days ahead, respectively. The results show that although ANFIS forecasts of water levels up to three lead days satisfied the benchmark, four‐ and five‐lead‐day forecasts were only slightly better in performance compared with the currently adopted operational model. This limitation is imposed by the auto‐ and cross‐correlations of the water level time series. Output updating procedures based on the autoregressive (AR) and recursive AR (RAR) models were used to enhance ANFIS model outputs. The RAR model performed better than the AR model. In addition, a partial recursive procedure that reduced the number of recursive steps when applying the AR or the RAR model for multi‐step‐ahead error prediction was superior to the fully recursive procedure. The RAR‐based partial recursive updating procedure significantly improved three‐, four‐ and five‐lead‐day forecasts. Our study further shows that for long lead times, ANFIS model errors are dominated by lag time errors. Although the ANFIS model with the RAR‐based partial recursive updating procedure provided the best results, this method was able to reduce the lag time errors significantly for the falling limbs only. Improvements for the rising limbs were modest. Copyright © 2011 John Wiley & Sons, Ltd.