Initiation of large-volume silicic centers in the Yellowstone hotspot track: insights from H<Subscript>2</Subscript>O- and F-rich quartz-hosted rhyolitic melt inclusions in the Arbon Valley Tuff of the Snake River Plain

During the onset of caldera cluster volcanism at a new location in the Snake River Plain (SRP), there is an increase in basalt fluxing into the crust and diverse silicic volcanic products are generated. The SRP contains abundant and compositionally diverse hot, dry, and often low-δ¹⁸O silicic volcanic rocks produced through time during the formation of individual caldera clusters, but more H₂O-rich eruptive products are rare. We report analyses of quartz-hosted melt inclusions from pumice clasts from the upper and lower Arbon Valley Tuff (AVT) to gain insight into the initiation of caldera cluster volcanism. The AVT, a voluminous, caldera-forming rhyolite, represents the commencement of volcanism (10.44 Ma) at the Picabo volcanic field of the Yellowstone hotspot track. This is a normal δ¹⁸O rhyolite consisting of early and late erupted members (lower and upper AVT, respectively) with extremely radiogenic Sr isotopes and unradiogenic Nd isotopes, requiring that ~50 % of the mass of these elements is derived from melts of Archean upper crust. Our data reveal distinctive features of the early erupted lower AVT melt including: variable F concentrations up to 1.4 wt%, homogenous and low Cl concentrations (~0.08 wt%), H₂O contents ranging from 2.3 to 6.4 wt%, CO₂ contents ranging from 79 to 410 ppm, and enrichment of incompatible elements compared to the late erupted AVT, subsequent Picabo rhyolites, SRP rhyolites, and melt inclusions from other metaluminous rhyolites (e.g., Bishop Tuff, Mesa Falls Tuff). We couple melt inclusion data with Ti measurements and cathodoluminescence (CL) imaging of the host quartz phenocrysts to elucidate the petrogenetic evolution of the AVT rhyolitic magma. We observe complex and multistage CL zoning patterns, the most critical being multiple truncations indicative of several dissolution–reprecipitation episodes with bright CL cores (higher Ti) and occasional bright CL rims (higher Ti). We interpret the high H₂O, F, F/Cl, and incompatible trace element concentrations in the context of a model involving melting of Archean crust and mixing of the crustal melt with basaltic differentiates, followed by multiple stages of fractional crystallization, remelting, and melt extraction. This multistage process, which we refer to as distillation, is further supported by the complex CL zoning patterns in quartz. We interpret new Δ¹⁸O(Qz-Mt) isotope measurements, demonstrating a 0.4 ‰ or ~180 °C temperature difference, and strong Sr isotopic and chemical differences between the upper and lower AVT to represent two separate eruptions. Similarities between the AVT and the first caldera-forming eruptions of other caldera clusters in the SRP (Yellowstone, Heise and Bruneau Jarbidge) suggest that the more evolved, lower-temperature, more H₂O-rich rhyolites of the SRP are important in the initiation of a caldera cluster during the onset of plume impingement.     

Spatially controlled Fe and Si isotope variations: an alternative view on the formation of the Torres del Paine pluton

We present new Fe and Si isotope ratio data for the Torres del Paine igneous complex in southern Chile. The multi-composition pluton consists of an approximately 1 km vertical exposure of homogenous granite overlying a contemporaneous 250-m-thick mafic gabbro suite. This first-of-its-kind spatially dependent Fe and Si isotope investigation of a convergent margin-related pluton aims to understand the nature of granite and silicic igneous rock formation. Results collected by MC-ICP-MS show a trend of increasing δ⁵⁶Fe and δ³⁰Si with increasing silica content as well as a systematic increase in δ⁵⁶Fe away from the mafic base of the pluton. The marginal Torres del Paine granites have heavier Fe isotope signatures (δ⁵⁶Fe = +0.25 ± 0.02 2se) compared to granites found in the interior pluton (δ⁵⁶Fe = +0.17 ± 0.02 2se). Cerro Toro country rock values are isotopically light in both Fe and Si isotopic systems (δ⁵⁶Fe = +0.05 ± 0.02 ‰; δ³⁰Si = ?0.38 ± 0.07 ‰). The variations in the Fe and Si isotopic data cannot be accounted for by local assimilation of the wall rocks, in situ fractional crystallization, late-stage fluid exsolution or some combination of these processes. Instead, we conclude that thermal diffusion or source magma variation is the most likely process producing Fe isotope ratio variations in the Torres del Paine pluton.     

Soil-water dynamics and tree water uptake in the Sacramento Mountains of New Mexico (USA): a stable isotope study

In the southwestern United States, precipitation in the high mountains is a primary source of groundwater recharge. Precipitation patterns, soil properties and vegetation largely control the rate and timing of groundwater recharge. The interactions between climate, soil and mountain vegetation thus have important implications for the groundwater supply. This study took place in the Sacramento Mountains, which is the recharge area for multiple regional aquifers in southern New Mexico. The stable isotopes of oxygen and hydrogen were used to determine whether infiltration of precipitation is homogeneously distributed in the soil or whether it is partitioned among soil-water ‘compartments’, from which trees extract water for transpiration as a function of the season. The results indicate that “immobile” or “slow” soil water, which is derived primarily from snowmelt, infiltrates soils in a relatively uniform fashion, filling small pores in the shallow soils. “Mobile” or “fast” soil water, which is mostly associated with summer thunderstorms, infiltrates very quickly through macropores and along preferential flow paths, evading evaporative loss. It was found that throughout the entire year, trees principally use immobile water derived from snowmelt mixed to differing degrees with seasonally available mobile-water sources. The replenishment of these different water pools in soils appears to depend on initial soil-water content, the manner in which the water was introduced to the soil (snowmelt versus intense thunderstorms), and the seasonal variability of the precipitation and evapotranspiration. These results have important implications for the effect of climate change on recharge mechanisms in the Sacramento Mountains.     

Forecasting rock slope failure: how reliable and effective are warning systems?

Warning systems are increasingly applied to reduce damage caused by different magnitudes of rockslides and rockfalls. In an integrated risk-management approach, the optimal risk mitigation strategy is identified by comparing the achieved effectiveness and cost; estimating the reliability of the warning system is the basis for such considerations. Here, we calculate the reliability and effectiveness of the warning system installed in Preonzo prior to a major rockfall in May 2012. “Reliability” is defined as the ability of the warning system to forecast the hazard event and to prevent damage. To be cost-effective, the warning system should forecast an event with a limited number of false alarms to avoid unnecessary costs for intervention measures. The analysis shows that to be reliable, warning systems should be designed as fail-safe constructions. They should incorporate components with low failure probabilities, high redundancy, have low warning thresholds, and additional control systems. In addition, the experts operating the warning system should have limited risk tolerance. In an additional hypothetical probabilistic analysis, we investigate the effect of the risk attitude of the decision makers and of the number of sensors on the probability of detecting the event and initiating a timely evacuation, as well as on the related intervention cost. The analysis demonstrates that quantitative assessments can support the identification of optimal warning system designs and decision criteria.     

Stability analysis of an ancient landslide considering shear strength reduction behavior of slip zone soil

In this paper, the stability of an ancient landslide during the first impounding of a nearby reservoir is investigated through the analyses of the shear strength reduction behavior of slip zone soil. In view of the experimental observations, an empirical strain-dependent soil model is established and is then incorporated in finite element analyses. The numerical analysis results show that the failing sections progressively develop due to the soil strength declines from peak toward residual, and the shear zone propagates within the front slope. It is demonstrated in the numerical results that the toe weighting measure has a significant effect on restraining the shear displacements of the soils and preventing the progressive failure of the landslide. The field observations further confirmed the stability condition of the reinforced landslide.     

Optimization and Parametrical Investigation to Assess the Reconstitution of Different Types of Indian Sand Using Portable Travelling Pluviator

By using the air pluviation technique, it is aimed to achieve the desired relative density with uniform void ratio throughout the specimen in order to maintain the homogeneity and to avoid the spatial variability. Further, in order to achieve the maximum deposition intensity, a systematic optimization study has been carried out rigorously in a test tank to determine the diameter of the orifice to be employed for the sieve plates of different porosity and the number of sieve plates to be installed in the diffuser sieve sets. The study has been conducted with four different patterns of sieves with different porosity to achieve a wide range of relative densities for four different uniformly graded Indian sands. The dynamic penetrometer which is considered to be one of the cost effective instruments has been efficiently used to determine the soil resistance at various locations of the test tank for every given height of fall in order to check the uniformity of placement density throughout the sand bed. The study reveals that the sand beds of different relative densities could be achieved using different patterns of diffuser sieves at optimum sand flow rate without compromising the uniformity. The effect of height of fall as well as porosity of diffuser sieves on the relative density of different sands has been studied in detail. The deposition intensity and the relative density obtained from the present study are compared with the values available in the literature.     

Assessment and Prediction of Liquefaction Potential Using Different Artificial Neural Network Models: A Case Study

Soil liquefaction as a transformation of granular material from solid to liquid state is a type of ground failure commonly associated with moderate to large earthquakes and refers to the loss of strength in saturated, cohesionless soils due to the build-up of pore water pressures and reduction of the effective stress during dynamic loading. In this paper, assessment and prediction of liquefaction potential of soils subjected to earthquake using two different artificial neural network models based on mechanical and geotechnical related parameters (model A) and earthquake related parameters (model B) have been proposed. In model A the depth, unit weight, SPT-N value, shear wave velocity, soil type and fine contents and in model B the depth, stress reduction factor, cyclic stress ratio, cyclic resistance ratio, pore pressure, total and effective vertical stress were considered as network inputs. Among the numerous tested models, the 6-4-4-2-1 structure correspond to model A and 7-5-4-6-1 for model B due to minimum network root mean square errors were selected as optimized network architecture models in this study. The performance of the network models were controlled approved and evaluated using several statistical criteria, regression analysis as well as detailed comparison with known accepted procedures. The results represented that the model A satisfied almost all the employed criteria and showed better performance than model B. The sensitivity analysis in this study showed that depth, shear wave velocity and SPT-N value for model A and cyclic resistance ratio, cyclic stress ratio and effective vertical stress for model B are the three most effective parameters on liquefaction potential analysis. Moreover, the calculated absolute error for model A represented better performance than model B. The reasonable agreement of network output in comparison with the results from previously accepted methods indicate satisfactory network performance for prediction of liquefaction potential analysis.     

Contemporary Deposition and Long-Term Accumulation of Sediment and Nutrients by Tidal Freshwater Forested Wetlands Impacted by Sea Level Rise

Contemporary deposition (artificial marker horizon, 3.5 years) and long-term accumulation rates (²¹⁰Pb profiles, ~150 years) of sediment and associated carbon (C), nitrogen (N), and phosphorus (P) were measured in wetlands along the tidal Savannah and Waccamaw rivers in the southeastern USA. Four sites along each river spanned an upstream-to-downstream salinification gradient, from upriver tidal freshwater forested wetland (TFFW), through moderately and highly salt-impacted forested wetlands, to oligohaline marsh downriver. Contemporary deposition rates (sediment, C, N, and P) were greatest in oligohaline marsh and lowest in TFFW along both rivers. Greater rates of deposition in oligohaline and salt-stressed forested wetlands were associated with a shift to greater clay and metal content that is likely associated with a change from low availability of watershed-derived sediment to TFFW and to greater availability of a coastal sediment source to oligohaline wetlands. Long-term accumulation rates along the Waccamaw River had the opposite spatial pattern compared to contemporary deposition, with greater rates in TFFW that declined to oligohaline marsh. Long-term sediment and elemental mass accumulation rates also were 3–9× lower than contemporary deposition rates. In comparison to other studies, sediment and associated nutrient accumulation in TFFW are lower than downriver/estuarine freshwater, oligohaline, and salt marshes, suggesting a reduced capacity for surface sedimentation (short-term) as well as shallow soil processes (long-term sedimentation) to offset sea level rise in TFFW. Nonetheless, their potentially large spatial extent suggests that TFFW have a large impact on the transport and fate of sediment and nutrients in tidal rivers and estuaries.     

Iron Reduction Along an Inundation Gradient in a Tidal Sedge (<Emphasis Type="Italic">Cyperus malaccensis</Emphasis>) Marsh: the Rates,Pathways, and Contributions to Anaerobic Organic Matter Mineralization

Incubation experiments were adopted to characterize the rates and pathways of iron reduction and the contributions to anaerobic organic matter mineralization in the upper 0–5 cm of sediments along a landscape-scale inundation gradient in tidal marsh sediments in the Min River Estuary, Southeast China. Similar sediment characteristics, single-species vegetation, varied biomass and bioturbation, distinct porewater pH, redox potential, and electrical conductivity values have resulted in a unique ecogeochemical zonation along the inundation gradient. Decreases in solid-phase Fe(III) and increases in nonsulfidic Fe(II) and iron sulfide were observed in a seaward direction. Porewater Fe²⁺ was only detected in the upland area. High rates of iron reduction were observed in incubation jars, with significant accumulations of nonsulfidic Fe(II), moderate accumulations of iron sulfides, and negligible accumulations of porewater Fe²⁺. Most of the iron reduction was microbially mediated rather than coupled to reduced sulfides. Microbial iron reduction accounted for 20–89 % of the anaerobic organic matter mineralization along the inundation gradient. The rate and dominance of microbial iron reduction generally decreased in a seaward direction. The contributions of microbial iron reduction to anaerobic organic matter mineralization depended on the concentrations of bioavailable Fe(III), the spatial distribution of which was significantly related to tidal inundation. Our results clearly showed that microbial iron reduction in the upper sediments along the gradient is highly dependent on spatial scales controlled primarily by tidal inundation.     

Characterization of the Tertiary reservoir in Khabbaz Oil Field,Kirkuk area,Northern Iraq

Tertiary reservoir represented by Jeribe, Anah, Azkand, and Azkand/Ibrahim formations has been studied from reservoir characterization point of view in Khabbaz Oil Field/Northern Iraq. Examined thin sections prepared from core rock samples which are selected from the wells Kz-8 and Kz-9 revealed the existence of different microfacies in which are varies types of porosity such as interparticle, intraparticle, moldic, vuggy, and fractures have been noticed. In addition to these different types of diagenetic features are represented mainly by cementation, dolomitization, recrystallization, and dissolution. The available log data for the wells Kz-11, Kz-14, and Kz-16 have been used in characterizing the reservoir properties of the studied formations. The detected lithologies from porosity logs showed domination of limestone, dolomitic limestone, and dolomites in addition to few thin beds of anhydrites in Jeribe Formation and thin beds of sand dominated lithologies in Azkand Formation. Clay content has been calculated from gamma ray log along the studied sections and appeared to be mostly of dispersed clay type as shown from density-neutron porosity crossplot of Thomas-Stieber. Correction from the effect of clay content has been done for all the measured sonic, density, and neutron porosities. The available porosity and permeability values which are measured from core tests in the well Kz-9 for the formations of Jeribe, Anah, and Azkand have been adapted to formalize the best equation for calculating permeability in the other studied wells which have no core test measurements but only log data (Kz-11, Kz-14, and Kz-16 wells). Depending on porosity, permeability, and shale content, the studied sections have been subdivided into seven reservoir units in the wells Kz-11 and Kz-16, and for eight reservoir units in the well Kz-14.