The dependence of organohalogen compound concentrations on herring age and size in the Bothnian Sea, northern Baltic

The concentrations and composition profiles of polychlorinated dibenzo-p-dioxins and dibenzofurans, polychlorinated biphenyls, polybrominated diphenyl ethers and polychlorinated naphthalenes were determined in herring individuals collected from the commercial catches of the Bothnian Sea, northern Baltic. The median age of herring was 5.0 years and in the muscle the median toxic equivalent concentration of PCDD/Fs was 5.6 WHO(PCDD/F)-TEQ pg/g fresh weight (fw) and that of PCBs 2.7 WHO(PCB)-TEQ pg/g fw. The median sum concentration of PBDEs was 1.4 ng/g fw and that of PCNs 0.1 ng/g fw. Differences in age-dependent accumulation between the organohalogen groups and individual congeners were major. In the Bothnian Sea the content of organohalogen compounds in herring is obviously elevated due to the availability and large proportion of Mysis crustaceans in their diet. More intensive fishing could reduce the concentrations of organohalogens, including the abundant, accumulative and toxic 2,3,4,7,8-PeCDF congener in the Baltic herring catch.     

Depositional history of peatland pines (Pinus sylvestris L.) in NW Enontekiö, Finnish Lapland: implications for Middle Holocene drought and temperature fluctuations

High altitude and latitude findings of subfossil peatland pine trees were unearthed from the region of NW Finnish Lapland and dated by ¹⁴C and tree-ring methods. The depositional history of the trees illustrated two distinct peatland pine phases dated to Middle Holocene intervals 4900–4400 and 4100–3400 cal. a BC. It seems evident that both thermal and hydroclimatic fluctuations have played roles of varying importance in the establishment of this pine population and its demise. The presence of these pines, from a site ~60 km north of the coniferous timberline and conditions ~1 °C and 100 degree-days colder than those at the present-day timberline, concurs with previous studies demonstrating the association between the high-latitude summer-temperature cooling and circumpolar timberline retreat since the Middle Holocene due to Milankovitch forcing. On the other hand, the peatland pine recruitment was made possible by drier than present surface conditions during the previously reconstructed Middle Holocene drought anomaly (Hyvärinen-Alhonen event). Our data suggest this event was not continuous but reached its two-phase climax during the peatland pine phases, with an interruption of several centuries with moister surface conditions between 4400 and 4100 cal. a BC. The findings highlight the sensitivity of well-dated peatland tree assemblages in terms of recording past climatic evolution and events and the need for new collections from north and south Fennoscandia and the Baltic region, for more detailed analyses over extended time intervals and regions.     

Forthcoming Meetings on Planetary Boundary-layer Theory, Modelling and Applications

In this short communication we highlight the NATO Advanced Research Workshop (ARW) “Atmospheric Boundary Layers: Modelling and Applications for Environmental Security”, to be held in Dubrovnik, Croatia, 18–22 April 2006 (http:// pbl-nato-arw.dmi.dk) and the “Summer School on Air-Sea Interaction” to be held in Helsinki, Finland, 28 August–1 September 2006 (http://www.scasi.fi). These two events are connected to the ongoing Ev Marie Curie Chair Project “Planetary boundary layers – Theory, modelling and role in earth systems” (PBL – TMRES, Contract MEXC-CT-2003-509742, www.atm.helsinki.fi/PBL/).     

‘Observations and Modelling of Cold-air Advection over Arctic Sea Ice’

Aircraft observations of the atmospheric boundary layer (ABL) over Arctic sea ice were made during non-stationary conditions of cold-air advection with a cloud edge retreating through the study region. The sea-ice concentration, roughness, and ABL stratification varied in space. In the ABL heat budget, 80% of the Eulerian change in time was explained by cold-air advection and 20% by diabatic heating. With the cloud cover and inflow potential temperature profile prescribed as a function of time, the air temperature and near-surface fluxes of heat and momentum were well simulated by the applied two-dimensional mesoscale model. Model sensitivity tests demonstrated that several factors can be active in generating unstable stratification in the ABL over the Arctic sea ice in March. In this case, the upward sensible heat flux resulted from the combined effect of clouds, leads, and cold-air advection. These three factors interacted non-linearly with each other. From the point of view of ABL temperatures, the lead effect was far less important than the cloud effect, which influenced the temperature profiles via cloud-top radiative cooling and radiative heating of the snow surface. The steady-state simulations demonstrated that under overcast skies the evolution towards a deep, well-mixed ABL may take place through the merging of two mixed layers one related to mostly shear-driven surface mixing and the other to buoyancy-driven top-down mixing due to cloud-top radiative cooling.     

Land-use dominates climate controls on nitrogen and phosphorus export from managed and natural Nordic headwater catchments

Agricultural, forestry-impacted and natural catchments are all vectors of nutrient loading in the Nordic countries. Here, we present concentrations and fluxes of total nitrogen (totN) and phosphorus (totP) from 69 Nordic headwater catchments (Denmark: 12, Finland:18, Norway:17, Sweden:22) between 2000 and 2018. Catchments span the range of Nordic climatic and environmental conditions and include natural sites and sites impacted by agricultural and forest management. Concentrations and fluxes of totN and totP were highest in agricultural catchments, intermediate in forestry-impacted and lowest in natural catchments, and were positively related %agricultural land cover and summer temperature. Summer temperature may be a proxy for terrestrial productivity, while %agricultural land cover might be a proxy for catchment nutrient inputs. A regional trend analysis showed significant declines in N concentrations and export across agricultural (−15 μg totN L⁻¹ year⁻¹) and natural (−0.4 μg NO₃-N L⁻¹ year⁻¹) catchments, but individual sites displayed few long-term trends in concentrations (totN: 22%, totP: 25%) or export (totN: 6%, totP: 9%). Forestry-impacted sites had a significant decline in totP (−0.1 μg P L⁻¹ year⁻¹). A small but significant increase in totP fluxes (+0.4 kg P km⁻² year⁻¹) from agricultural catchments was found, and countries showed contrasting patterns. Trends in annual concentrations and fluxes of totP and totN could not be explained in a straightforward way by changes in runoff or climate. Explanations for the totN decline include national mitigation measures in agriculture international policy to reduced air pollution and, possibly, large-scale increases in forest growth. Mitigation to reduce phosphorus appears to be more challenging than for nitrogen. If the green shift entails intensification of agricultural and forest production, new challenges for protection of water quality will emerge possible exacerbated by climate change. Further analysis of headwater totN and totP export should include seasonal trends, aquatic nutrient species and a focus on catchment nutrient inputs.     

Eemian crustal deformation in the eastern Baltic area in the light of the new sites at Peski, Russia and Põhja-Uhtju, Estonia

Several Eemian (Mikulino) marine deposits are known from the northwestern part of Russia and from Estonia. The best-known deposits are situated at Mga, Russia and at Prangli, Estonia. Two new sites with clayey and silty deposits covered by till were studied for pollen and diatoms at Peski, Russia and Põhja-Uhtju, Estonia. At Peski, the deposit representing the Eemian Interglacial is 3.8 m thick at the depth of 13.4–9.6 m above present sea-level. At Põhja-Uhtju, the deposit representing the Eemian is 3.5 m thick at the depth of 47.9–51.4 m below present sea-level. Although Peski is situated at a higher altitude than Põhja-Uhtju at present, the diatom stratigraphy at these sites indicates deeper and more saline conditions in the Peski area than at Põhja-Uhtju during the Eemian. This result is similar to some previous studies, which indicate, that although the Russian deposits (e.g. Peski, Mga) are now at a higher altitude than those in Estonia (Põhja-Uhtju and Prangli), the diatoms in the Russian deposits are indicative of a considerable depth of water during the time of deposition. These deposits suggest that the Eemian shore levels ascend from Estonia eastwards, while the Late Weichselian and Holocene shorelines tilt downwards in the same general direction. The present material from Estonia and northwestern part of Russia shows marked differences between the Eemian and Late Weichselian/Holocene crustal deformations, which probably resulted from different ice loads during the final glaciation phases and probably also from different deglaciation patterns during the Saalian and Late Weichselian.     

Two‐dimensional and three‐dimensional computational models in hydrodynamic and morphodynamic reconstructions of a river bend: sensitivity and functionality

This study assesses hydrodynamic and morphodynamic model sensitivity and functionality in a curved channel. The sensitivity of a depth‐averaged model to user‐defined parameters (grain size, roughness, transverse bed slope effect, transport relations and secondary flow) is tested. According to the sensitivity analysis, grain size, transverse bed slope effect and sediment transport relations are critical to simulated meander bend morphodynamics. The parametrization of grain size has the most remarkable effect: field‐based grain size parametrization is necessary in a successful morphodynamic reconstruction of a meander bend. The roughness parametrization method affects the distribution of flow velocities and therefore also morphodynamics. The combined effect of various parameters needs further research. Two‐dimensional (2D) and three‐dimensional (3D) reconstructions of a natural meander bend during a flood event are assessed against field measurements of acoustic Doppler current profiler and multi‐temporal mobile laser scanning data. The depth‐averaged velocities are simulated satisfactorily (differences from acoustic Doppler current profiler velocities 5–14%) in both 2D and 3D simulations, but the advantage of the 3D hydrodynamic model is unquestionable because of its ability to model vertical and near‐bed flows. The measured and modelled near‐bed flow, however, differed notably from each other's, the reason of which was left open for future research. It was challenging to model flow direction beyond the apex. The 3D flow features, which also affected the distribution of the bed shear stress, seem not to have much effect on the predicted morphodynamics: the 2D and 3D morphodynamic reconstructions over the point bar resembled each other closely. Although common features between the modelled and measured morphological changes were also found, some specific changes that occurred were not evident in the simulation results. Our results show that short‐term, sub‐bend scale morphodynamic processes of a natural meander bend are challenging to model, which implies that they are affected by factors that have been neglected in the simulations. The modelling of short‐term morphodynamics in natural curved channel is a challenge that requires further study. Copyright © 2014 John Wiley & Sons, Ltd.     

Outokumpu revisited: New mineral deposit model for the mantle peridotite-associated Cu–Co–Zn–Ni–Ag–Au sulphide deposits

The metaturbidites of the Palaeoproterozoic Jormua–Outokumpu thrust belt in eastern Finland enclose m- to km-scale ultramafic massifs that are distributed over an area of more than 5000 km². These bodies, which almost entirely consist of highly depleted mantle peridotites (now metaserpentinites and metaperidotites), are intimately associated with massive to semimassive, polymetallic Cu–Co–Zn–Ni–Ag–Au sulphide deposits that sustained mining in the region between 1913 and 1988. Currently, one deposit (Kylylahti) is proceeding into a definitive feasibility study emphasising the renewed economic interest for Outokumpu-type deposits.The origin of these Outokumpu-type Cu–Co–Zn–Ni–Ag–Au deposits is now re-interpreted to be polygenetic. First, their formation requires deposition of a Cu-rich proto-ore within peridotitic sea floor at  1950 Ma. Close modern analogues to the proto-ore setting include, for example, the Logatchev and Rainbow fields at the Mid-Atlantic Ridge, where venting of high-T–low-pH hydrothermal fluid resulted in accumulations of Cu–Zn–Co–Ag–Au sulphides on serpentinised ultramafic seafloor. Second, the Ni-rich composition of Outokumpu sulphide ores calls for a separate source for nickel: Some 40 Ma after the deposition of the Cu-rich proto-ore – concomitant with the obduction of the ultramafic massifs – disseminated Ni sulphides formed through chemical interaction between obducting peridotite massifs and adjacent black schists. This process was related to listwaenite–birbirite type carbonate–silica alteration at margins of the ultramafic massifs. Due to this alteration, silicate nickel was released from the primary Fe–Mg silicates and redeposited as Ni sulphides in the alteration fringes of the massifs.We propose that syntectonic mixing of these two “end-member” sulphides, i.e., the primary Cu-rich proto-ore and the secondary Ni-sulphide disseminations, resulted in the uncommon metal combination of the Outokumpu-type sulphides. Late tectonic solid-state re-mobilisation, related to the duplexing of the ore by isoclinal folding, upgraded the sulphides into economic deposits.