Impact of fertilizer application and urban wastes on the quality of groundwater in the Cambrai Chalk aquifer,Northern France

Since 1975, Europe sets up its policy to limit the degradation and the pollution of the aquatic environments through 30 directives and regulations. In the north of France, the nitrate concentrations measured in the groundwater exceed the water drinking limit fixed at 50 mg/L by the European framework directive in the field of water (2000/60/EC). This high concentration is due to intensive agriculture, industrialization and demographic growth. Several programs were launched in order to resolve this situation: “Ferti-better” or the use of fertilizer in moderation and installation and amelioration of wastewater collect and treatment systems. In order to estimate the influence of the anthropic activities on the quality of groundwater in the “Artois-Picardy” basin, a preliminary validation on parcel and district scale were necessary. The impact of these programs in the “Cambrai district” was evaluated using an integrated approach, which is based on the use of four numerical models: AgriFlux, VS2DT, Modflow and MT3D. The results illustrate an improvement due to the “Ferti-Better” program initiated in 1990 and punctual degradation under urbanized areas. Predictions (2015) show a spatial evolution of nitrates concentration varying with the thickness of unsaturated layer. The integrated model constitutes an efficient tool for predicting the evolution of the groundwater quality. This approach is important to control the application of the new European laws in the water field.     

Atmospheric Lead in PM2.5 after Leaded Gasoline Phase‐out in Jeddah City,Saudi Arabia

The objective of the present study is the assessment of Jeddah ambient air quality in terms of PM_2.5, and the associated lead 7 years after phasing out leaded gasoline in Saudi Arabia. Twenty‐four air samples were collected at four locations throughout Jeddah during the period from December 23, 2008 to April 6, 2009. The collected PM_2.5‐samples were analyzed by ICP‐MS for determination of lead. The average atmospheric PM_2.5 concentration was 50.8 µg/m³. Atmospheric PM_2.5‐concentrations were higher than the 24‐h U.S. National Ambient Air Quality Standards (NAAQS) in 14 sample events. The average lead concentration for all samples was 0.07326 µg/m³. Atmospheric lead concentration was dependent on the sampling location. Concentrations at the two southern locations were higher than at the two northern locations. Southern locations had higher lead concentrations due to very high traffic density, in addition to their proximity to industrial zone. In general, the results of this study show a considerable decrease in atmospheric lead concentration 7 years after phasing out leaded gasoline. The study recommends further studies to accurately determine the current sources of atmospheric lead.     

The Waqf as Suwwan crater,Eastern Desert of Jordan: aspects of the deep structure of an oblique impact from reflection seismic and gravity data

The deeply eroded Waqf as Suwwan ring structure was recently discovered to be a large impact, the first identified in the near east. Large-scale reflection seismic structure shows the impact situated high on the northeastern flank of the Jordan Uplift sloping into Wadi Sirhan Basin. If exhumation is linked to the Arabia–Eurasia collision, a likely time window for the impact event may be latest Eocene to Late Oligocene. Impact into a shallow sea seems an optional scenario. Old reflection seismic lines offer limited insight into the deep structure of the rim and part of the central uplift of the complex crater. An important structural clue is provided by a well-resolved seismic horizon of a yet tentative correlation with a Paleozoic black shale. The central gravity high is compatible with a mass surplus by the uplift of denser Paleozoic basement below the central uplift. The gravity model further indicates a ring of dense Paleozoic sediments rising from below into the ring syncline. Seismics show presumably radial synclines in the central uplift which are interpreted by centripetal constrictional flow during crater collapse. Beneath the final crater’s outer boundary, a shallow-dip normal fault zone, subtle seismic structure in uncollapsed footwall segments reveal an asymmetry of strain. The asymmetry is attributed to the cratering flow by an oblique impact directed toward NE. The finding provides independent support to an earlier suggestion of impact obliquity based on vergency of folds exposed on the central uplift.     

Groundwater recharge zones mapping using GIS: a case study in Southern part of Jordan Valley,Jordan

This paper aims at mapping the potential groundwater recharge zones in the southern part of Jordan Valley (JV). This area is considered as the most important part for agricultural production in Jordan. The methodology adopted in this study is based on utilizing the open ended SLUGGER-DQL score model, which was developed by Raymond et al (2009). Geographic information systems were used in this study to build up the different layers of this model and to create the potential groundwater recharge zones. Based on the generated SLUGGER-DQL potential map, it was found that about 70.8 % of the investigated area was categorized as high potential for groundwater recharge, 18.7 % as moderate, and 10.5 % as low potential for groundwater recharge. To validate the model results, sensitivity analysis was carried out to assess the influence of each model parameter on the obtained results. Based on this analysis, it was found that the slope parameter (S) is the most sensitive parameter among SLUGGER-DQL model parameters, followed by water level in summer (L), well density (D), water quality (Q), runoff availability (R), land use/land cover, geology (GE), whereas the lowest sensitive parameter is the geology parameter (GE). Moreover, the parameters R, D, and Q show the lowest effective weights. The effective weight for each parameter was found to differ from the assigned theoretical weight by SLUGGER-DQL index model.     

Geotechnical Risk Assessment of Mine Development Intersections with Respect to Mining Sequence

Mine developments such as haulage drifts and their intersections with cross-cuts are the only stope access in sub-level stoping mining system. Thus, they must remain stable during their service life. Haulage drift instability could lead to serious consequences such as: production delay, damage to equipment, loss of reserves and high operational cost. The goal of this paper is the stability of mine developments with respect to mining sequence with focus on the performance of haulage drift intersection during the production plan. A case study, the #1 Shear East orebody at Vale’s Garson Mine in Sudbury Ontario will be examined in this paper. A three-dimensional, elastoplastic, finite difference code (FLAC3D) is used for this study. The extent of strength-to-stress ratio corresponds to Mohr–Coulomb strength-to-stress ratio of 1.4 is used as failure evaluation criterion. The unsatisfactory performance is reached when the extent of strength-to-stress ratio exceeds the anchorage limit of the rockbolt. Stochastic analysis; adopting point-estimate method, is then employed with the numerical modelling to tackle the inherent uncertainty associated with rockmass properties. Then, the probability of instability at various mining steps is estimated for the roof and north wall of the studied intersection. The cost of consequence models is introduced to provide an economical solution if the intersection failed, blocked or damaged. Furthermore, the geotechnical risk associated with the instability of mine development intersection is estimated using risk-indexing tool. The results are presented and categorized in terms of probability, cost of consequence and risk-index at various mining stages.     

On the use of finite‐difference and neural‐network models to evaluate the impact of underground water overexploitation

The purpose of this study is to include expert knowledge as one part of the modelling system and thereby offer the chance to create a productive interactive system between expert, mathematical model, ASM, and artificial neural networks (ANNs). An attempt to determine outflow‐influencing parameters in order to simulate spring flow is presented. The Bouteldja dune aquifer is fed by rains and streaming water on the sandy argillaceous relieves in the Est. The lateral passage to the gravel of the Bouteldja Plain is marked by numerous bogs that correspond to the piezometric level. These bogs have long been an environment for migratory birds and a natural reserve for many species. However, the continued exploitation of about 30 wells has negatively influenced the hydrodynamic equilibrium of the aquifer and has brought a diminution of the sources' capacity. In this study, we tried by using a hydrodynamic model and the neural network to ascertain the state of the resources and to identify the factors responsible for the decreasing flows of the three principal springs of the area (Bougles, Bourdim and Titteri) by using neural networks. The results obtained show a continued exhaustion of the reserve since 1986 with a large cone of depression. The ANNs show that the decrease in flows of the springs is not only due to the unfavourable climatic conditions, but also to the intensive exploitation of the aquifer. These results show that the groundwater reserves are decreasing over time, thus highlighting the need to take some urgent measures to stop this phenomenon. Copyright © 2006 John Wiley & Sons, Ltd.     

Long-term analog of carbonation in travertine from Uleimat Quarries, Central Jordan

Quaternary travertine capping the metamorphic (cement) zones in Uleimat Quarries, central Jordan, has been precipitated from hyperalkaline paleogroundwaters. Such waters are similar to the cement pore water and to the present day hyperalkaline seepages (pH 12.5) in Maqarin, north Jordan. The isotopic depletions observed in Uleimat travertine, with δ¹³C values as low as −25.45‰, suggest that they have been precipitated during CO₂ uptake by highly alkaline calcium hydroxide waters. The travertine in Uleimat Quarries indicates a long-term analog of carbonation and remobilization of silica in cementitious barriers for radioactive waste repositories. The presence of Cr-rich smectites and relatively high levels of Cr (4.1%), V (657 ppm), Ni (163 ppm), Zn (634 ppm) and U (34 ppm) in the green travertine and the associated opaline silica phases suggests the use of the Uleimat travertines as analogs with the repository disturbed zone. Smectites and silica phases are expected to be a sink for alteration products in the late stage evolution of a high pH plume. Co-precipitation of these elements in mineral phases is of great importance to control the concentration of these elements in groundwater.     

Utilization of bituminous limestone ash from EL-LAJJUN area for engineering applications

The following work aims at minimizing the environmental impact of the solid wastes (ash) that is produced after the utilization of the bituminous limestone in thermal power stations and /or retort processes. Limy ash has been prepared from the El-Lajjun bituminous limestone by direct combustion at 1,200, 950, and 525°C respectively. The laboratory tests have been selected with respect to construction needs and possible post construction conditions. Utilization of the various types of ash in the stabilization problematic soils from Jordan as brown soils and the clayey marl has revealed optimum results. The unconfined compressive strength of the parent brown soil and the clayey marl has been raised from 5 kg/cm² to 50 and 25 kg/cm², respectively. The CBR value has been raised from 4.5 to 150% for both problematic soil types. Various mortars and construction elements can be produced at normal room curing temperature without the use of ordinary Portland cement (OPC). Low quality sub-base and base course can be mixed with ash to produce cement treated base (CTB) and roller compacted concrete (RCC) without OPC. Durable pavements, embankments can be constructed with very long life and low cost. CTB and RCC utilizing ash can be used in dam construction instead of normal soil in earth fill dams. The high alkalinity of El-Lajjun ash is considered as a disadvantage to be utilized in normal concrete mixes for structural purposes. Ash only can be mixed with aggregates to produce lean concrete like for blinding purposes to be prepared for foundation activities.     

Origin of water salinity in a lake and coastal aquifer system

The studied area is in the Algerian Northeast. A number of interacting factors at the site are able to modify salinity. The main influences are: (1) The lithology, (2) Fedzara Lake, (3) marine waters, and (4) a prolonged drought. (1) The lithology is very clearly delineated by the outcrop of metamorphic formations (gneiss, marbles, micaschists, and quartzites) and sedimentary formations (limestones, clay, sandstones, and sands). All these formations can influence the chemical composition of waters. (2) Fedzara Lake evacuates its salted waters via the Wadi Meboudja, which connects with the Wadi Seybouse and the phreatic surface. These lake waters might induce changes in salinity. (3) The marine waters represent the third source of salinity change. Over-pumping of water from wells and drillings can cause an imbalance to the fresh–salted water interface. (4) The effects of a local prolonged drought of more than 10 years may increase water salinity. Over-pumping to augment water supply generates a fall in water levels and the drier atmosphere increases evapotranspiration. Both may contribute to increased salinity. Results of water analysis were used to observe the evolution of these various factors.